• Bulletin of the Korean Chemical Society
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• v.30 no.4
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• pp.829-836
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• 2009

The catalytic enantioselective electrophilic fluorinations of active methine compounds promoted chiral palladium complexes have been developed. Treatment of $\beta$-keto phosphonates and $\beta$-ketoesters with N-fluorobenzenesulfonimide as the fluorine source under mild reaction conditions afforded the corresponding $\alpha$-fluorinated adducts in high yields with excellent enantiomeric excesses (up to 99% ee). These reactions can be conducted in alcoholic solvents without any precaution to exclude water and moisture.

• Journal of the Korean earth science society
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• v.34 no.5
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• pp.415-427
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• 2013

We performed a BVR photometric survey for the entire Small Magellanic Cloud (~26 deg 2 ) with a mosaic system, Wide Field Imager (WFI), covering three seasons: September and October 2001 and November 2002. Through the usual data reduction procedures, we present ~0.73 million catalogue stars brighter than 19 magnitude in B amongst a total of ~1.3 million and compare them with published astrometry and photometry results. We found that the average differences between our and the published data are ~0.7 arcsec in astrometry and 0.065, 0.054, and 0.163 in B, V, and R, respectively, in photometry. In addition, using the 2dF spectroscopic data from Evans et al. (2004), we determined the color excesses in (B-V) and (V-R) to be $0.086{\pm}0.156$, and $0.065{\pm}0.112$, respectively, while for the distance modulus, we obtained $18.55{\pm}1.05$.

• IE interfaces
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• v.19 no.4
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• pp.291-299
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• 2006

In order to enhance sustainable war fighting capabilities, it is important to maintain a good ammunition support system. In this paper, we evaluate the performance of ammunition companies using Imprecise Data Envelopment Analysis (IDEA)-BCC and IDEA-Additive model, which can deal with imprecise data in DEA. The input variables of IDEA models were selected by stepwise multiple regression analysis. With the regression model, we could choose the number of soldiers, officers, and ammunition warehouses as input variables that have significant effects on the output performance. Then, we applied the IDEA-BCC model with the concept of potential efficiency. The results of the model indicate that 8 out of 16 ammunition companies are efficient, 7 are inefficient, and 1 is potentially efficient. We could also identify the possible input excesses and output shortfalls to reach the efficient frontier using the IDEA-Additive model.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.195-197
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• 2003

Soil moisture is a crucial variable in research works of hydrology, meteorology and plant sciences. Adequate soil moisture is essential for plant growth; excesses and deficits of soil moisture must be considered in agricultural practices. There are already several remote sensing methods used for monitoring soil moisture, such as thermal inertia, vegetation water-supplying index, crop water stress index and multi-factor regression. In this paper, an improved method has been discussed which is based on the thermal inertia. We analyzed the problems of monitoring soil moisture using satellites at first, and then put forward an simplified method which directly uses land surface temperature differences to measure soil moisture. Also we have taken the influence of vegetation into account, and import NDVI into the model. The method was used in the study of soil moisture in Heilongjiang Province, China, and we draw the conclusion by the experiments that the model can evidently increase the precision of monitoring soil moisture.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.77-80
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• 1988

A suituable choice of supporting electrolyte medium for trace level determinations of chromium(VI) by differential pulse polarography is described. A comparative study suggests that sodium borate buffer is superior to ammonium acetate, ammonium tartrate, and especially to NaF which was recently known to be one of the most proper medium for the purpose. With 0.01 M borate, the best combination of high sensitivity, well-defined base line, and freedom from common interferents was attained. With $5.0{\times}10^{-7}$M Cr(VI), tenfold excesses of Cu(II) and Fe(III), and a five hundred-fold excess of $Cl^-$ do not change the peak current by more than about 1%. And the detection limit was $5.0{\times}10^{-8}$M Cr(VI).

• The Bulletin of The Korean Astronomical Society
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• v.45 no.1
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• pp.58.1-58.1
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• 2020

The Multipupose InfraRed Imaging System (MIRIS) Paα Galactic Plane Survey (MIPAPS) covers the whole Galactic plane with the latitude range of -3° < b < +3°. Next to the first result in l = 96°-116° (Cepheus), we present the results in l = 276°-296° (Carina). This region with the direction toward the inner Galaxy, has much higher extinction but much more Paα-emitting sources than Cepheus. We list up the detected Paα sources, and compare them with the WISE H II region catalog (there are 308 H II regions and candidates in this region) and VPHAS+ Hα image. By detecting the Paα and Hα recombination lines, 71 H II region candidates are newly confirmed as definite H II regions, out of which 53 H II regions are detected at Paα. For the Paα-detected sources, we measure the Paα and Hα fluxes and estimate the E(B-V) color excesses for the extended sources.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2004.05a
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• pp.85-90
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• 2004

We divided the planting bale into waterproof layer, drainage layer and soil layer so at to investigate changes of live load according to species of wood and composition of the base to make rooftops green. The results are follows, 1. As concerning construction and live load for green roof, sheet waterproofing is superior. 2. When materials of drainage are changed crushed gravel into artificial lightweight graval or ferrite, live load of planting bale is decreased about 22% and 25% in order. 3. When ingredients of soil are chased normal sand into volcanic sand, live load of base is decreased about 28%. Especially, when it is changed into ferrite, 54% of live load is decreased. 4. In this study, all live load we concerned excesses the standard about roof live load of office, school and house. Hence, structure has to be concerned thoroughly when making rooftops green. But, we judge that various methods for making rooftops green can be applied if we consider roof garden when we plan new buildings.

• Korean Journal of Materials Research
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• v.11 no.12
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• pp.1047-1051
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• 2001

Purity tantalum powder has been produced by sodium reduction of potassium tantalum fluoride($K_2TaF_7$)in a stainless steel bomb. The influence of experimental variable, such as excess of reductant and temperature of reduction on the yield and quality of the Ta powder has been studied. The excesses of reductant were varied from -20%, -10%, 0%, 5%, 10%, 20%. When -20% excess of sodium was used, the un-reacted sodium remained in the reacted product. The yield of 81% of Ta powder has been achieved by reducing 50g of$K_TaF_7$with 5% sodium in excess of stoichiometric amount in presence of 16.8g of sodium chloride in the charge at a reduction temperature of$905{\circ}C$. The proportion of fine fraction(~325mesh) decreased appreciably with the increase of sodium excess, and the yield of tantalum powder improved from 65% to 94%. The average particle size of Ta Powder is improved from 3 microns to 4 microns in the 5% excess sodium.

• The Bulletin of The Korean Astronomical Society
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• v.40 no.2
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• pp.53.3-53.3
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• 2015

We analyzed both HCN J=1-0 and HNC J=1-0 line profiles to study the inflow motions in different evolutionary stages of massive star formation; infrared dark clouds (IRDCs), high-mass protostellar object (HMPOs), and ultra-compact HII regions (UCHIIs). The infall asymmetry in HCN spectra seems to be prevalent throughout all the three evolutionary phases, with IRDCs showing the largest excess in blue profile. In the case of HNC spectra, the prevalence of blue sources does not appear, excepting for IRDCs. We suggest that this line is not appropriate to trace infall motion in evolved stages of massive star formation because of an astrochemical effect. This result spotlights the importance of considering chemistry in dynamical study in star-forming regions. The fact that the IRDCs show the highest blue excess in both infall tracers indicates that the most active infall occurs in the early phase of star formation, i.e., the IRDC phase rather than in the later phases. However, the UCHIIs is likely still accreting matters. We also found that the absorption dips of the HNC spectra in all blue sources are red--shifted relative to their central velocities. These red-shifted absorption dips may indicate the observational signature of overall collapse although observations with better resolutions are needed to examine this feature more in detail.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.543-550
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• 2000

Rock slopes along the road or railroad are affected by temperature and therefore experienced iterative freezing-thawing process between winter and early spring. The purpose of this study is to analyze the stability of rock slopes which are influenced by the deterioration due to the freezing-thawing. The analysis is the homogenization method which evaluates the strength property of discontinuous rock mass, and as a strength failure criterion, Drucker-Prager failure criterion is used. The deterioration property of real rock is obtained by a freezing-thawing laboratory test of tuff and this property of deterioration is quantitated and used as a basic data of stability analysis for rock mass. To evaluate the deterioration depth due to the freezing-thawing in situ rock slope, one dimensional heat conductivity equation is used and as the result I can find that the depth of which is affected by a temperature. After the freezing-thawing depth of model slope is determined, we analyze the pattern of rock mass stength value of rock slope model which excesses the limit of self-load.