• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.4
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• pp.399-405
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• 1994

Beacuse of the energy resources exhaustion, the aggravating environmental air pollution and the smoke phenomena etc., the importance of clean gas fuel compared with liquid fuel is highly considered in recent years. The combustion system which consists of porous media is actively studied as a new method for solving above problems. Therefore, excess enthalpy combustion using porous media was interested by many researchers and investigated through numerical and experimental analysis. In this study, the simplified combustor has the unique combustion characteristics of mixture gas preheated effect using radiative and convective heat energy by changing the flow passage of unburned gas with solenoid valves and has the intensive excess enthalpy phenomena As the result of according to reduce equivalence ratio, flame temperature was remarkably higher than adiabatic flame temperature. This show the ability of super-lean combustion.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.660-667
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• 2017

Equilibrium data of the mixture is essential in the design and operation of separation equipment such as distillation or extraction in chemical processes. These equilibrium data can be obtained through experiments or by calculations using the known binary parameters and the thermodynamic models. Generally, to obtain these parameters, phase equilibrium experimental data such as gas-liquid and liquid-liquid are used. In this study, the excess enthalpy of the mixture was measured using the flow type microcalorimeter which is a simpler method than phase equilibria experiments, and the parameters of various theories were obtained by using this data. In order to investigate the relationship between carbon chain length, enthalpy and binary parameters in the alkane system, excess enthalpies for the n-hexane + alkane (n-pentane, n-heptane, n-octane and n-dodecane) were measured at 298.15 K and the banary interaction parameters of Wilson, NRTL, and UNIQUAC were obtained from the experimental data. In addition, we wanted to obtain basic information on the interaction and association phenomena of the system including electrolyte applicable to various fields by using the excess enthalpy experimental data and the existing theory. First, we investigated the excess enthalpy for the NaOH / Water / Ethanol system as a basic experiment and examined the applicability using the electrolyte-NRTL (eNRTL) theory.