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Effects of ZrO2 Addition on Mechanical Strength and Thermal Shock Resistance of Cordierite-Mullite Ceramics (ZrO2가 코디어라이트-뮬라이트 세라믹스의 기계적 강도 및 내열충격성에 미치는 영향)

  • Lim, Jin-Hyeon;Kim, Shi Yeon;Yeo, Dong-Hun;Shin, Hyo-Soon;Jeong, Dae-yong
    • Korean Journal of Materials Research
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    • v.28 no.12
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    • pp.719-724
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    • 2018
  • Cordierite composed of an alumina-silica-magnesia compound has a low coefficient of thermal expansion(CTE) and excellent thermal shock resistance. It also has a low dielectric constant and high electrical insulation. However, due to low mechanical strength, it is limited for use in a ceramic heater. In this study, $ZrO_2$ is added to an 80 wt% cordierite-20 wt% mullite composition, and the effect of $ZrO_2$ addition on the mechanical strength and thermal shock resistance is investigated. With an increasing addition of $ZrO_2$, cordierite-mullite formed $ZrO_2$, $ZrSiO_4$ and spinel phases. With sintering conducted at $1400^{\circ}C$ with the addition of 5 wt% $ZrO_2$ to 80 wt% cordierite-20 wt% mullite, the most dense microstructure forms along with an excellent mechanical strength with a 3-point flexural strength of 238MPa. When this composition is quenched in water at ${\Delta}T=400^{\circ}C$, the 3-point flexural strength is maintained. Moreover, when this composition is cooled from $800^{\circ}C$ to air, the 3-point flexural strength is maintained even after 100 cycles. In addition, the CTE is measured as $3.00{\times}10^{-6}{\cdot}K^{-1}$ at $1000^{\circ}C$. Therefore, 80 wt% cordierite-20 wt% mullite with 5 wt% $ZrO_2$ is considered to be appropriate as material for a ceramic heater.

Printability of Thermally and Chemically Stable Silica-Titanium Dioxide Composite Coating Layer (실리카-이산화티탄 복합 코팅층의 열적, 화학적 안정성 및 인쇄적성 평가)

  • Kim, Hye Jin;Han, Kyu Sung;Hwang, Kwang Taek;Nahm, Sahn;Kim, Jin Ho
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.631-638
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    • 2019
  • As automation systems become more common, there is growing interest in functional labeling systems using organic and inorganic hybrid materials. Especially, the demand for thermally and chemically stable labeling paper that can be used in a high temperature environment above $300^{\circ}C$ and a strong acid and base atmosphere is increasing. In this study, a composite coating solution for the development of labeling paper with excellent thermal and chemical stability is prepared by mixing a silica inorganic binder and titanium dioxide. The silica inorganic binder is synthesized using a sol-gel process and mixed with titanium dioxide to improve whiteness at high-temperature. Adhesion between the polyimide substrate and the coating layer is secured and the surface properties of the coating layer, including the thermal and chemical stability, are investigated in detail. The effects of the coating solution dispersion on the surface properties of the coating layer are also analyzed. Finally, it is confirmed that the developed functional labeling paper showed excellent printability.

Molecular Analysis of Rice Plants Harboring an Ac/Ds Transposable Element-Mediated Gene Trapping System

  • Hang Gyeong;Mi Sook Choe;Sung-Ho Lee;Sung Han Park;Hyuk Kim;Ja Choon Koo;No Youl Kim;Su Hyun Park;Jeung Joo Lee
    • Proceedings of the Botanical Society of Korea Conference
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    • 1999.07a
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    • pp.17-20
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    • 1999
  • In rice, limited efforts have been made to identify genes by the use of insertional mutagens, especially heterologous transposons such as the maize Ac/Ds. We constructed Ac and gene trap Ds vectors and introduced them into the rice genome by Agrobacterium-mediated transformation. In this report, rice plants that contained single and simple insertions of T-DNA were analyzed in order to evaluate the gene-tagging efficiency. The 3'end of Ds was examined for putative splicing donor sites. As observed in maize, three splice donor sites were identified at the 3'end of the Ds in rice. Nearly 80% of Ds elements wered excised from the original T-DNA sites, when Ac cDNA was expressed under a CaMV 35S promoter. Repetitive ratoon culturing was performed to induce new transpositions of Ds in new plants derived from cuttings. About 30% of the plants carried at least one Ds that underwent secondary transposition in the later cultures. 8% of transposed Ds elements expressed GUS in various tissues of rice panicles. With cloned DNA adjacent to Ds, the genomic complexities of the insertion sites were examined by Southern hybridization. Half of the Ds insertion sites showed simple hybriodization patterns which could be easily utilized to locate the Ds. Our data demonstrate that the Ac/Ds mediated gene trap system could prove an excellent tool for the analysis of functions of genes in rice. We discuss genetic strategies that could be employed in a largee scale mutagenesis using a heterologous Ac/Ds family in rice.

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Multi-channel analyzer based on a novel pulse fitting analysis method

  • Wang, Qingshan;Zhang, Xiongjie;Meng, Xiangting;Wang, Bao;Wang, Dongyang;Zhou, Pengfei;Wang, Renbo;Tang, Bin
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2023-2030
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    • 2022
  • A novel pulse fitting analysis (PFA) method is presented for the acquisition of nuclear spectra. The charging process of the feedback capacitor in the resistive feedback charge-sensitive preamplifier is equivalent to the impulsive pulse, and its impulse response function (IRF) can be obtained by non-linear fitting of the falling edge of the nuclear pulse. The integral of the IRF excluding the baseline represents the energy deposition of the particles in the detector. In addition, since the non-linear fitting process in PFA method is difficult to achieve in the conventional architecture of spectroscopy system, a new multi-channel analyzer (MCA) based on Zynq SoC is proposed, which transmits all the data of nuclear pulses from the programmable logic (PL) to the processing system (PS) by high-speed AXI-Stream in order to implement PFA method with precision. The linearity of new MCA has been tested. The spectrum of 137Cs was obtained using LaBr3(Ce) scintillator detector, and was compared with commercial MCA by ORTEC. The results of tests indicate that the MCA based on PFA method has the same performance as the commercial MCA based on pulse height analysis (PHA) method and excellent linearity for γ-rays with different energies, which infers that PFA method is an effective and promising method for the acquisition of spectra. Furthermore, it provides a new solution for nuclear pulse processing algorithms involving regression and iterative processes.

Gradient Microstructure and Mechanical Properties of Fe-6%Mn Alloy by Different Sized Powder Stacking (다른 크기의 분말 적층을 통해 얻은 Fe-6%Mn합금의 경사 미세조직과 기계적 특성)

  • Seo, Namhyuk;Lee, Junho;Shin, Woocheol;Jeon, Junhyub;Park, Jungbin;Son, Seung Bae;Jung, Jae-Gil;Lee, Seok-Jae
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.382-389
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    • 2022
  • A typical trade-off relationship exists between strength and elongation in face-centered cubic metals. Studies have recently been conducted to enhance strength without ductility reduction through surface-treatment-based ultrasonic nanocrystalline surface modification (UNSM), which creates a gradient microstructure in which grains become smaller from the inside to the surface. The transformation-induced plasticity effect in Fe-Mn alloys results in excellent strength and ductility due to their high work-hardening rate. This rate is achieved through strain-induced martensitic transformation when an alloy is plastically deformed. In this study, Fe-6%Mn powders with different sizes were prepared by high-energy ball milling and sintered through spark plasma sintering to produce Fe-6%Mn samples. A gradient microstructure was obtained by stacking the different-sized powders to achieve similar effects as those derived from UNSM. A compressive test was performed to investigate the mechanical properties, including the yielding behavior. The deformed microstructure was observed through electron backscatter diffraction to determine the effects of gradient plastic deformation.

A Study on the Wear Properties of Cu-free Ecofriendly Vehicle Brake Pad (구리를 함유하지 않은 친환경 자동차 브레이크 패드의 마모 특성에 관한 연구)

  • Kim, Ki-Bong;Yang, Sangsun;Lee, Seong-Ju;Hwang, Suk-Hun;Kim, Sin-Wook;Kim, Yong-Jin
    • Journal of Powder Materials
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    • v.25 no.1
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    • pp.30-35
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    • 2018
  • The friction characteristics of Al-Fe alloy powders are investigated in order to develop an eco-friendly friction material to replace Cu fiber, a constituent of brake-pad friction materials. Irregularly shaped Al-Fe alloy powders, prepared by gas atomization, are more uniformly dispersed than conventional Cu fiber on the brake pad matrix. The wear rate of the friction material using Al-8Fe alloy powder is lower than that of the Cu fiber material. The change in friction coefficient according to the friction lap times is 7.2% for the Cu fiber, but within 3.8% for the Al-Fe alloy material, which also shows excellent judder characteristics. The Al-Fe alloy powders are uniformly distributed in the brake pad matrix and oxide films of Al and Fe are homogeneously formed at the friction interface between the disc and pad, thus exhibiting excellent friction and lubrication characteristics. The brake pad containing Al-Fe powders avoids contamination by Cu dust, which is generated during braking, by replacing the Cu fiber while maintaining the friction and lubrication performance.

Antifungal Activities Against Plasmodiophora brassicae Causing Club Root

  • Kim, Bum-Joon;Choi, Gyung-Ja;Cho, Kwang-Yun;Yang, Hee-Jung;Shin, Choon-Shik;Lee, Chul-Hoon;Lim, Yoong-Ho
    • Journal of Microbiology and Biotechnology
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    • v.12 no.6
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    • pp.1022-1025
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    • 2002
  • Club root is one of the major diseases that occur in crucifers. It is caused by Plasmodiophora brassicae. In order to discover microbial biopesticides against P. brassicae, forty-eight Streptomyces isolated from soil were screened. Among these, three strains showed excellent pesticidal activities. We report results on in vivo screening with fermentation broths of these strains and identification of the strain taxa.

Semiconductor Flow Sensor To Detect Air flow (유속감지를 위한 반도체 유량센서)

  • Yee, young-Joo;Chun, Kuk-Jin
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.188-191
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    • 1993
  • Silicon flow sensor which can detect the magnitude and direction of two dimensional air flow was designed and fabricated by CMOS process and bulk micromachining technique. The flow sensor consists of three-layered dielectric diaphragm a heater at the center of the diaphragm and four thermopiles surrounding the heater at each side of diaphragm as sensing elements. This diaphragm structure contributes to improve the sensitivity due to excellent thermal isolation property of dielectric materials and its tiny thickness. The flow sensor has good axial symmetry to sense 2-D air flow with the optimized sensing position in the given structure. Measured sensitivity of our sensor is $18.7mV/(m/s)^{1/2}$.

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Empirical Capacity Degradation Model for a Lithium-Ion Battery Based on Various C-Rate Charging Conditions

  • Dong Hyun Kim;Juhyung Lee;Kyungseop Shin;Kwang-Bum Kim;Kyung Yoon Chung
    • Journal of Electrochemical Science and Technology
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    • v.15 no.3
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    • pp.414-420
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    • 2024
  • Lithium-ion batteries are widely used in many applications due to their high energy density, high efficiency, and excellent cycle ability. Once an unknown Li-ion battery is reusable, it is important to measure its lifetime and state of health. The most favorable measurement method is the cycle test, which is accurate but time- and capacity-consuming. In this study, instead of a cycle test, we present an empirical model based on the C-rate test to understand the state of health of the battery in a short time. As a result, we show that the partially accelerated charge/discharge condition of the Li-ion battery is highly effective for the degradation of battery capacity, even when half of the charge/discharge conditions are the same. This observation provides a measurable method for predicting battery reuse and future capacity degradation.

Research trends and Efficacy Analysis of Surface Characteristics of Bone Grafts (골이식재의 표면 특성 연구 동향과 유효성 분석)

  • Yong-Hoon Jeong;Gye-Wook Lee;Tae-Gon Jung
    • Journal of Surface Science and Engineering
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    • v.57 no.4
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    • pp.234-253
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    • 2024
  • As the population ages, the importance of effective bone disease treatments is increasing, highlighting the role of bone grafts. Bone grafts are categorized into natural (autografts, allografts, xenografts) and synthetic (ceramics, polymers). Natural grafts have excellent regenerative abilities but pose biological risks, while synthetic grafts are biocompatible but less effective in regeneration. Various studies aim to enhance the safety and efficacy of bone grafts, significantly altering their surface properties. This review examines these studies and the resulting surface changes, aiming to guide future research and clinical applications.