• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.215-216
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• 2000

대기 중에 존재하는 입자의 생성 및 변화를 모델링 하는데 있어서 가장 중요한 요소는 응축/휘발 (condensation/evaporation)과 같은 기체/입자간의 상호 과정을 어떻게 모사 하느냐 하는 것이다. 일반적으로 지금까지의 연구는 입자와 가스상의 농도가 순간적으로 평형을 이룬다고 가정해 왔으나 실제 대기상의 입자는 비 평형(non-equilibrium)상태의 응축/휘발 과정을 따르는 것으로 알려져 왔다. (중략)

• Proceedings of the Membrane Society of Korea Conference
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• 1996.03a
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• pp.1-23
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• 1996

투과증발(Pervaporation)이란 어원적으로 "permeation"과 "evaporation"의 합성어인데 액체혼합물이 치밀한 비다공질막을 통해 이동하는 동안 증기화되면서 분리되는 막분리 공정이다. 이 공정에서 막 한쪽면은 액체공급액과 접하고 있고 다른 한쪽면은 낮은 투과물의 증기압과 접하고 있는데 낮은 증기압은 진공(vacuum pervaporation)을 가하거나 혹은 불활성의 담체가스(sweep gas pervaporation)를 흐르게 하므로써 얻을 수 있다. 이때 막 내부에 트과증발막공정의 추진력인 화학 포텐셜(chemical potential) 구배가 발생하여 막을 통한 물질투과가 이루어지는데 각 투과성분의 투과속도는 투과성분과 막재료간의 물리화학적 인력에 의해 결정된다.의 물리화학적 인력에 의해 결정된다.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1686-1691
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• 2004

The effect of recirculated exhaust gas on performance and exhaust emissions with FGR rate are investigated by using a natural circulation, pressurized draft and water tube boiler with FGR system operating at several boiler loads and over fire air(OFA) damper openings. The purpose of this study is to apply the FGR system to a power plant boiler for reducing $NO_{x}$ emissions. To activate the combustion, the suction damper of two stage combustion system installed in the upper side of wind box is opened by handling the lever between $0^{\circ}$ and $90^{\circ}$ , and the OFA with 0 to 20% into the flame is supplied, as the combustion air supplied to burner is reduced. It is found that the fuel consumption rate divided by evaporation rate does not show an obvious tendency to increase or decrease with rising the FOR rate, and $NO_{x}$ emissions are decreased, at the same OF A damper opening, as FOR rates are elevated and boiler loads are dropped.

• Environmental Analysis Health and Toxicology
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• v.16 no.4
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• pp.181-188
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• 2001

A gas chromatographic method was established for the simultaneous determination of urinary nicotine and cotinine. The analytes in basified urine containing a sufficient amount of Na$_2$S0$_4$were extracted into dichloromethane by vigorous shaking. Into the transferred organic phase was added a small amount of acidified methanol (0.5 N HCI in methanol), followed by concentrating the mixture to dryness using a mild stream of nitrogen gas. The concentrate was reconstituted with methanol and the final solution analyzed using the gas chromatograph equipped with the nitrogen-phosphorus detector. The reproducibility tests showed coefficients of variation less than 11％ for both compounds. The percent recovery for both analytes ranged from 88 to 103％. The estimated method detection limits for nicotine and cotinine were 0.60 and 5.1 ng/mL, respectively. Extraction efficiencies for both nicotine and cotinine apparently declined without the addition of Na$_2$S0$_4$into the urine. Moreover, the absence of methanolic HCI in the extract resulted in almost complete evaporation of nicotine and partial loss of cotinine during the concentration process, indicating that the formation of nicotine-HCI and cotinine-HCI species is prerequisite to the suppression of the loss of both compounds.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.11
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• pp.2159-2168
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• 1992

Coal-water slurry is considered to have the potential for displacing petroleum used in the existing oil-fired industrial and utility boilers. The combustion of coal-water slurry(CWS) is a complex process and little is known about the detailed mechanism. In this paper the combustion behavior of a single suspended droplet of CWS in hot gas stream was investigated. The effect of coal particle size, water content in droplet, initial droplet size, ambient temperature and oxygen fraction in ambient gas were studied. The results are as follows; (1) Increasing the oxygen fraction in ambient gas considerably reduced the char combustion time. (2) The variation of water content and coal particle size in droplet showed little effect on the combustion behavior. (3) In the relatively high temperature ambient gas, the water evaporation time became shorter and the combustion process was stable.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.315.2-315.2
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• 2014

Pt-functionalized ZnS nanowires were synthesized on Au-deposited c-plane sapphire substrates by thermal evaporation of ZnS powders followed by wet Pt coating and annealing. The $NO_2$ gas sensing properties of multiple-networked Pt-functionalized ZnS nanowire sensors were examined. Scanning electron microscopy showed the nanowires with diameters of 20-80 nm. Transmission electron microscopy and X-ray diffraction showed that the nanowires were wurtzite-structured ZnS single crystals. The Pt-functionalized ZnS nanowire sensors showed enhanced sensing performance to $NO_2$ gas at $150^{\circ}C$ compared to pristine ZnS nanowire sensors. Pristine and Pt-functionalized ZnS nanowire sensors showed responses of 140-211% and 207-488%, respectively, to 1-5 ppm $NO_2$, which are better than or comparable to those of many oxide semiconductor sensors. In addition, the underlying mechanism of the enhancement of the sensing properties of ZnS nanowires by Pt functionalization is discussed.

• Journal of Electrical Engineering and Technology
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• v.2 no.2
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• pp.257-262
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• 2007

In this paper the experiments of breakdown characteristics by temperature change of $SF_6$ gas($GSF_6$), and $SF_6$ liquid ($LSF_6$) in model GIS (Gas Insulated Switchgear) are described. From the experiment's results, the breakdown characteristics classify the vapor stage of $SF_6$ according to Paschen's law, in which the gas & liquid coexisted stage of voltage value increases, resulting in much deviation and the breakdown of voltage ($V_B$) low stage as the interior of the chamber gets filled with a mixture of $SF_6$ that is not liquefacted and remaining air that cannot be ventilated. The ability of $LSF_6$ insulation is higher than the high-pressurized $SF_6$ gas. The breakdown characteristics of $LSF_6$ were produced by bubble formed evaporation of $LSF_6$ and bubbles caused by high electric emission. It is considered in this paper that the results are fundamental data for electric insulation design of superconductor and cryogenic equipments machinery that will be studied and developed in the future.

• YAKHAK HOEJI
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• v.44 no.5
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• pp.384-390
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• 2000

Metabolism study of the dye, benzidine, was performed by gas chromatography-mass selective detector (GC/MSD) in the urine of rats orally administered 100 mg/kg benzidine. Urine samples were collected in metabolic cages for 0-24, 24-48, and 48-72 hrs. Ten ml of the urine was extracted with XAD-2 resin and the XAD-2 column was eluted with methanol. After evaporation, benzidine and its metabolites were extracted with diethyl ether (for non-conjugated fraction). For conjugated metabolites, $\beta$-glucu-ronidase was added to the aqueous layer that was incubated for 1 hr at 5$0^{\circ}C$ and the aqueous layer was extracted as in non-conjugated fraction. Aliquot of trimethylsilylated derivatives was applied to the GC/MSD. The mutagenicity of benzidine and its acetylated metabolites was tested by histidine/reversion assay. Five metabolites observed and confirmed either by electron impact and chemical ionization modes of the GC/MSD, or authentic compounds were monoacetyl-, diacetyl-, hydroxyacetyl-, hydroxydiacetyl-, and hydroxy-benzidine. Monoacetyl-benzidine was more potent than benzidine in histidine/reversion assay. This data indicates that monoacetylation of benzidine may be one of the metabolites produced in metabolic activation process.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.66-66
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• 2011

Anodic titanium dioxide (TiO2) nanotubes are very attractive materials for gas sensors due to its large surface to volume ratios. The most widely known method for fabrication of TiO2 nanotubes is anodic oxidation of metallic Ti foil. Since the remaining Ti substrate is a metallic conductor, TiO2 nanotube arrays on Ti are not appropriate for gas sensor applications. Detachment of the TiO2 nanotube arrays from the Ti Substrate or the formation of electrodes onto the TiO2 nanotube arrays have been used to demonstrate gas sensors based on TiO2 nanotubes. But the sensitivity was much lower than those of TiO2 gas sensors based on conventional TiO2 nanoparticle films. In this study, Ti thin films were deposited onto a SiO2/Si substrate by electron beam evaporation. Samples were anodized in ethylene glycol solution and ammonium fluoride (NH4F) with 0.1wt%, 0.2wt%, 0.3wt% and potentials ranging from 30 to 60V respectively. After anodization, the samples were annealed at $600^{\circ}C$ in air for 1 hours, leading to porous TiO2 films with TiO2 nanotubes. With changing temperature and CO concentration, gas sensor performance of the TiO2 nanotube gas sensors were measured, demonstrating the potential advantages of the porous TiO2 films for gas sensor applications. The details on the fabrication and gas sensing performance of TiO2 nanotube sensors will be presented.

• Journal of Mechanical Science and Technology
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• v.16 no.11
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• pp.1457-1469
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• 2002

This paper is the first of several companion papers, which investigate axial stratification process and its effects in an Sl engine. The axial stratification is very sophisticate phenomenon, which results from combination of fuel injection, port and in-cylinder flow and mixing. Because of the inherent unsteady condition in the reciprocating engine, it Is impossible to understand the mechanism through the analytical method. In this paper, the ports were characterized by swir and tumble number in steady flow bench test. After this, lean misfire limit of the engines, which had different port characteristic, were investigated as a function of swirl ratio and injection timing for confirming the existence of stratification. In addition, gas fuel was used for verifying whether this phenomenon depends on bulk air motion of cylinder or on evaporation of fuel. High-speed gas sampling and analysis was also performed to estimate stratification charging effect. The results show that the AFR at the spark plug and LML are very closely related and the AFR is the results of bulk air motion.