• Title/Summary/Keyword: Ethanol-water solution

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Characteristics and Dyeability of Juniperus Chinensis Extracts (향나무 추출 색소의 특성 및 염색성)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Korean Journal of Human Ecology
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    • v.21 no.5
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    • pp.989-1004
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    • 2012
  • The purpose of this study was to investigate the characteristics of the pigment and the dyeability of juniperus chinensis needles, berry, bark and heartwood extracts using distilled water, methanol, normal butanol and ethyl acetate as a solvent. Ultraviolet-visible absorption spectrum bands of the extracts were measured at around 280nm to 320nm in all the solvent extracts. The maximum absorption wavelength was able to determine tannin. All the solvent extracts except for distilled water extracts were able to confirm the presence of chlorophyll. Infrared absorption spectra (FT-IR) of all parts of the extracts showed broad absorption bands of OH due to phenolic-OH, benzene CH peak of phenol chemical structure, ether-based stretching vibration peak and the peak of flavonoid compounds that appeared in all the solvent extracts. The yield of juniper needles and heartwood in distilled water and methanol extraction were effective. Extraction of berry yields in distilled water was also effective. The yield of ethanol extraction from the bark showed better efficiency. As a result of using distilled water for the dye solution, the color of the fabrics dyed with all extracts of the needles and Y series berries generally showed light Y progression with a strong red tinge. By using a mixture of 20% ethanol and 80% distilled water for the dye solution, the color of the fabrics dyed with needles and berry extracts showed Y series dominantly. The color of the fabrics dyed with Bark and heartwood extracts were dominantly R series.

Reaction Conditions and Mechanism of Electrolytic Reduction of Dibenzoylmethane$^\dag$

  • Kang, Sung-Chul;Chon, Jung-Kyoon
    • Bulletin of the Korean Chemical Society
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    • v.8 no.5
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    • pp.414-418
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    • 1987
  • Electrochemical reduction of dibenzoylmethane was studied on mercury electrode by means of cyclic voltammetry, polarography and potentiostatic measurements in ethanol-water system. In acidic solutions monomeric pinacol was produced by irreversible two-electron process while monomeric and dimeric pinacol were competitively produced by the same process in neutral solution. However, in basic solution the dimeric pinacol was mostly produced through radical by irreversible one-electron transfer process. Mechanisms of the reduction of dibenzoylmethane are deduced from Tafel slope, pH dependance and reaction order with respect to the concentration of dibenzoylmethane in the solution of various pH.

The Dissociation Constant of Phenol Red Indicator in Mixed Solvents (혼합용매중의 지시약 Phenol Red의 해리정수)

  • 김양배
    • YAKHAK HOEJI
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    • v.20 no.1
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    • pp.41-43
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    • 1976
  • The dissociation constant of phenol red indicator in mixed solvents was studied. Methanol and ethanol were employed as solvents and studied the changes of pK values of indicator according to the kind and concentration of organic solvent which is mixed into water solution. The effect of methanol solvent on pK is negligible at 40%, 60% and 80% mixing. While in the case of ethanol, the effect of above 40% mixing is not negligible.

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Antigastritic and Antiulcerative Activities of Water Extracts Derived from Scutellaria baicalensis

  • Cho, So-Yean;Lim, Duk-Yun;Kang, Min-Hee;Yoon, Hye-Ran;Kim, Gun-Hee;Lee, Yong-Soo;Jeong, Choon-Sik
    • Biomolecules & Therapeutics
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    • v.14 no.3
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    • pp.171-177
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    • 2006
  • Gastritis and gastric ulcer were known to be induced by gastic acid, stress, ethanol, Helicobacter pylori and free radical, etc. This study was performed for the development of a new drug or nutraceutical from medicinal plants or natural products with anti-gastritis, anti-ulcerative and gastroprotective activities. The water extract of Scutellaria baicalensis was exhibited potent inhibition in HCl ethanol-induced gastric lesion, acetic acid-induced and Shay ulcers, indicating the effects on gastric lesion and ulcer in rats. The water extract of Scutellaria baicalensis significantly inhibited HCl ethanol-induced gastric lesions at the oral dose of 300, 500 mg/kg. In pylorus ligated rats, the treatments of the water extract from Scutellaria baicalensis showed decrease in the volume of gastric secretion and acid output and increase pH at oral dose of 300, 500 mg/kg. And significantly reduced acetic acid-induced ulcer at the oral dose of 500 mg/kg for 12 days. In this study, we have found that the water extract from Scutellaria baicalensis had significant improvement in acute gastritis and ulcer at the dose of 300, 500 mg/kg and in chronic gastritis and ulcer at the dose of 500 mg/kg. Also we evaluated the antibacterial activity against Helicobacter pylori treated with Scutellaria baicalensis. Scutellaria baicalensis had a equivalent antibacterial activity with ampicilin against H. pylori at the dose of $100\;{\mu}/ml$. In histological examination, the water extract of Scutellaria baicalensis drastically restored gastric damages induced by HCl ethanol solution, pylorus- ligature and acetic acid. Therefore, we may use the water extract from Scutellaria baicalensis as antigastritic and antiulcerative agent for the purpose of the improvement or treatment of gastritis and gastric ulcer.

Analysis of $NO_X$ Conversion Reaction using Platinum supported on Alumina (알루미나에 담지된 플라티늄을 이용한 $NO_X$의 전환반응에 미치는 요인 분석)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.2
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    • pp.168-174
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    • 2005
  • Aluminum tri-butoxide was mixed with the water/ethanol solution and then chloroplatinic acid was added to the solution. The solution was dried at $100^{\circ}C$ for 15hrs to remove the solvent and water then it was calcined at $500^{\circ}C$. The catalyst was activated with a gas mixture. During the activation, the temperature was increased from $150^{\circ}C$ to $500^{\circ}C$. The necessary amount of urea was dissolved in 50mL water and injected. Aqueous urea solution was then mixed with the feed gas stream. At low temperatures, nitrogen containing compounds of urea decomposition are used as reductants in the reducton of $NO_X$. However at high temperatures the nitrogen containing compounds are oxidized to NO and $NO_2$ by oxygen instead of being used in the reduction. The activity of the catalyst was dependent on urea concentration in the feed stream when there was not adequate water vapor in the feed. The maximum conversion was shifted from $250^{\circ}C$ to $150^{\circ}C$ when water concentration was increased from 2 to 17%. It seems that the maximum temperature shifts to lower temperatures because the hydrolysis rate of HNCO increases with water, resulting in higher amounts of $NH_3$.

The Analysis of Ethanol Distribution Level in Biological Specimens (생체 시료중에서 Ethanol 농도 분포에 관한 연구)

  • Hong, Hoon-Gi;Kim, Dong-Wook
    • Analytical Science and Technology
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    • v.11 no.3
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    • pp.222-228
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    • 1998
  • Five kinds of packed column and two kinds of capillary column were used to get optimum condition for ethanol analysis by using fifteen different volatile, low molecular weight organic substances. Only two columns, Gaskuropack 54 and DB-1, showed good separation efficiency. In the adding salt-effect experiment 0.6N - perchloric acid, 1M - meta-phosphoric acid and saturated NaCl solution were used for alcohol concentration measurement of biological fluids and tissue specimens. Among adding salt experiment, adding saturated NaCl solution showed the most stable value of alcohol concentration. This fact might be due to the increased vaporization of alcohol in the saturated NaCl solution. In the time-course of blood alcohol concentration, the alcohol level was lineary decreased to the diameter of vessel containing specimens. This result was interpreted in view of ethanol level, weight, water content, and hematocrit value. The ethanol distribution levels were measured from samples of blood and tissue obtained from 25 postmortems cases investigated by NISI. This study showed that the distribution level was decreased in order of brain, blood, kidney, spleen, liver, and lung.

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Particle Growth in Oxalate Process I

  • Park, Zee-Hoon;Shin, Hyo-Soon;Lee, Byung-Kyo
    • The Korean Journal of Ceramics
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    • v.2 no.2
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    • pp.63-69
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    • 1996
  • Barium titanyl oxalates, strontium titanyl oxalates and calcium zirconyl oxalates were prepared with variation of solution concentration and method of adding mixed metal ion solution into oxalic acid. Then they were aged in distilled water, ethanol or methanol, respectively. Barium titanyl oxalates and calcium zironyl oxalates were grown in water and strontium titanyl oxalates were groun in both water and methanol. They were supposed to be grown through the solutionl and reprecipitation mechanism. Nonuniform dispersion of particles in liquid phase is thought to cause abnormal particle growth.

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Effect of Extraction Temperature and Ethanol Concentration on Nitrogeneous Constituents of Red Ginseng Extract (추출조건이 홍삼엑기스의 질소화합물 조성에 미치는 영향)

  • Seong, Hyeong-Sun;Kim, U-Jeong;Yang, Cha-Beom
    • Journal of Ginseng Research
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    • v.9 no.1
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    • pp.95-103
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    • 1985
  • The concentrated red ginseng extract (RG-EXT) was prepared by extracting the ginseng tails with 0-90% ethanol solution at 70-100$^{\circ}C$ and analyzed for amino acids composition and other nitrogeneous fractions. The results showed that nonprotein fraction was more than 90% of the total N-compounds and 17 free amino acids were identified by High Performance Liquid Chromatography. Maximum and minimum N-compounds or total free amino acids were recovered in RG-EXT with 50% and 90% ethanol, respectively. An increase in ethanol concentration resulted a significant change in free amino acid composition while extraction temperature caused a little gradual decrease in water soluble nonprotein and total nitrogen fractions.

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Antioxidant Action of Malotilate on Prolonged Hepatic Injury Induced by Carbon Tetrachloride Alone or in Combination with Ethanol in Rat (사염화탄소 및 에탄올에 의해 유도된 만성간 손상에 미치는 말로틸레이트의 항산화 작용)

  • Kim, Hyoung-Chun;Hur, In-Hoi
    • YAKHAK HOEJI
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    • v.34 no.4
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    • pp.267-276
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    • 1990
  • To achieve a better understanding of antioxidant action manifested by malotilate, the dithiol malonates, we monitored the oxy radical-scavenging system against the chronic hepatic damage induced by $CCl_4$ alone or in combination with ethanol. Malotilate was given orally at a dose of 100 mg/kg/day and $CCl_4$ 1.5 ml/kg was injected subcutaneously twice a week for 4 weeks. In each group receiving ethanol, drinking water was replaced by 20% aqueous solution or glucose, isocaloric amounts of ethanol, as a control of ethanol was diluted in its drinking water. Each rat was killed as a starved state at 18 hours after the period of the experiment, four weeks. The results were summarized as follows: 1) Malotilate inhibited the rate of generation of superoxide radicals, the accumulation of lipoperoxides, and promoted the synthesis of glutathione in the liver. 2) Malotilate stimulated the enhancement of activity of superoxide dismutase in hepatic mitochondria. 3) Malotilate had no effects on the hepatic $H_2O_2$ contents. 4) Malotilate showed the increase of catalase activity in the liver poisoned with $CCl_4$, and also gave a tendency to increase it in the liver intoxicated with ethanol. Thus, our data suggested that the activation of hepatic antioxidant system in the presence of malotilate would play a role in protecting liver against the toxic effects of oxy radical and/or lipid peroxides under the hepatotoxic conditions induced by $CCl_4$ with or without ethanol. However, the effects of malotilate against the ethanol-induced hepatotoxicity appear to be insignificant.

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The Study on Cooling Characterics of TMA Clathrate with Ethanol (에탄올을 첨가한 TMA 포접화합물의 냉각특성에 대한 연구)

  • 김창오;김진흥;정낙규;김석현
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.8
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    • pp.634-640
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    • 2002
  • The purpose of this study is to investigate the propriety of TMA clathrate as a cold storage medium. Particularly, this is to examine the extent of subcooling improvement when the additives is added to the TMA clathrate, because water used for cold storage ma terial has low phase change temperature and subcooling. This study has been analyzed and compared pure water with TMA 30 wt% clathrate how phase change temperature, subcooling and specific heat in the various concentrations are changed. This results prove low phase change temperature and subcooling control effect when the ethanol is added to the TMA 30 wt% clathrate than the TMA 30 wt% clathrate. In addition, it results low specific heat when there is added to the TMA 30 wt% clathrate over 0.5 wt% ethanol in the cold heat source temperature under $-7^{\circ}C$. The other side, it results high specific heat when the ethanol is added in it at the cold heat source temperature under $-5^{\circ}C$. Therefore, it is found that the additive must be controlled by available solution limit and study for new additive must be lasted to know its effect.