• Bulletin of the Korean Chemical Society
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• v.6 no.1
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• pp.33-36
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• 1985

The luminescence intensity of $Tb^{3+}$ bound to picolinic acid, squaric acid, and 2,3-pyrazinedicarboxylic acid has been studied in water and water-ethanol mixtures. It has been found that the emission intensity of $Tb^{3+}$ in the complexes is enhanced with the increase of ethanol content in water-ethanol mixtures. Several factors affecting on the emission intensity of $Tb^{3+}$ in waterethanol mixtures are discussed.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.243-248
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• 2005

Membrane pervaporation processes could have advantages over distillation for separation of water/organics mixtures: a low energy demand and the ability to separate azeotropic mixtures or isomers. Zeolite membranes might show better thermal, mechanical and chemical stabilities than polymer membranes. Water could be effectively separated from water/organic mixtures using the NaA zeolite membrane because of its high hydrophilicity. In this study, water was separated by pervaporation using the NaA zeolite membrane from water/ethanol mixtures. As a mole fraction of ethanol increased, the total permeation flux and the water flux decreased while the separation factor increased, reached a maximum point, and decreased. As an experimental temperature increased, the total permeation flux increased while the separation factor increased at the lower mole fraction of ethanol than 0.8 and it decreased at the higher mole fraction of ethanol than 0.8. The total permeation flux and the separation factor could be maintained constant during the long term experiment longer than 160 hours. It was found that the NaA zeolite membrane synthesized in our study showed better performance on water/ethanol separation than that of a distillation process or PVA polymeric pervaporation membranes.

• Magazine of the Korean Society of Agricultural Engineers
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• v.39 no.2
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• pp.26-31
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• 1997

Abstract A series of permeability tests was performed on the mixtures with specific mixing rates of sand and bentonite using modified rigid-wall permeameter. Sand-bentonite mixtures were permeated by organics, ethanol and TCE. Permeability of bentonite with several mixing rates had a tendency to decrease up to initial one pore volume and permeability was thereafter converged to a constant value. When sand-bentonite mixtures was permeated by water, permeability was decreased at the beginning but it was thereafter converged to a constant. Among several mixing rates, permeability was greatly decreased at 15% of mixing rate. When sand-bentonite mixtures with 15% mixing rate was permeated by ethanol, permeability was about 10 times larger value than permeability of water. Peameability was shown greater values when permeated by TCE (TrichloroEthylene) followed by ethanol. Suitable mixing rate of sand-bentonite for a liner of waste landfills was detected.

• Magazine of the Korean Society of Agricultural Engineers
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• v.39 no.2
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• pp.32-43
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• 1997

Abstract A series of permeability tests was performed on the mixtures with specific mixing rates of sand and bentonite using modified rigid-wall permeameter. Sand-bentonite mixtures were permeated by organics, ethanol and TCE. Permeability of bentonite with several mixing rates had a tendency to decrease up to initial one pore volume and permeability was thereafter converged to a constant value. When sand-bentonite mixtures was permeated by water, permeability was decreased at the beginning but it was thereafter converged to a constant. Among several mixing rates, permeability was greatly decreased at 15% of mixing rate. When sand-bentonite mixtures with 15% mixing rate was permeated by ethanol, permeability was about 10 times larger value than permeability of water. Peameability was shown greater values when permeated by TCE (TrichloroEthylene) followed by ethanol. Suitable mixing rate of sand-bentonite for a liner of waste landfills was detected.

• Fire Science and Engineering
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• v.29 no.2
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• pp.39-43
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• 2015

The flash point is the major property to characterize fire and explosion hazard of liquid mixtures. The flash point is the lowest temperature at which a liquid gives off enough vapor to form a flammable air-vapor mixture. The flash points of two aqueous mixtures, water-methanol and water-ethanol, were measured using Seta flash closed cup tester. A prediction method based on activity coefficient models, Wilson and UNIQUAC equations, was used to calculate the flash point. The calculated flash points were compared to the results by the calculating method using Raoult's law. The calculated values based on activity coefficients models were found to be better than those based on the Raoult's law.

• Bulletin of the Korean Chemical Society
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• v.18 no.9
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• pp.1017-1021
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• 1997

Solvolyses of p-methoxyphenyl chloroformate in water, D2O, CH3OD, 50% D2O-CH3OD, and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25.0 ℃. Product selectivities are reported at 25 ℃ for a wide range of ethanol-water and methanol-water solvent compositions. The Grunwald-Winstein plots of first-order rate constants for p-methoxyphenyl chloroformate with YCl (based on 1-adamantyl chloride) show marked dispersions into three separate curves for the three aqueous mixtures with a small m value and a rate maximum for aqueous alcohol solvents. Third-order rate constants, kww, kaw, kwa and kaa were calculated from the observed kww and kaa values together with kaw and kwa calculated from the intercept and slope of the plot of 1/S vs. [alcohol]/[water]. The calculated rate constants, kcalc and mol % of ester agree satisfactorily with those of the observed rate constants, kobs and mol % of ester, supporting the stoichiometric solvation effect analysis. The kinetic solvent isotope effects determined in water and methanol are consistent with the proposed mechanism of the general base catalyzed carbonyl addition-elimination.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1293-1302
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• 2003

Rate constants at various temperatures and activation parameters are reported for solvolyses of acyl chlorides (RCOCl), with R = Me, Et, i-Pr, t-Bu, cyclopentylmethyl, benzyl, thiophenylmethyl, 2-phenylethyl, diphenylmethyl, and phenylthiomethyl in 100% ethanol, 100% 2,2,2-trifluoroethanol (TFE), 80% v/v ethanol/ water and 97% w/w TFE/water. Additional rate constants for solvolyses with R = Me, t-Bu, and $PhCH_2$ are reported for TFE/water and TFE/ethanol mixtures, and for solvolyses with R = t-Bu, and PhCH2 are reported for 1,1,1,3,3,3-hexafluoropropan-2-ol/water mixtures, as well as selected kinetic solvent isotope effects (MeOH/MeOD and TFE). Taft plots show that electron withdrawing groups (EWG) decrease reactivity significantly in TFE, but increase reactivity slightly in ethanol. Correlation of solvent effects using the extended Grunwald-Winstein (GW) equation shows an increasing sensitivity to solvent nucleophilicity for EWG. The effect of solvent stoichiometry in assumed third order reactions is evaluated for TFE/ethanol mixtures, which do not fit well in GW plots for R = Me, and t-Bu, and it is proposed that one molecule of TFE may have a specific role as electrophile; in contrast, reactions of substrates containing an EWG can be explained by third order reactions in which one molecule of solvent (ethanol or TFE) acts as a nucleophile, and a molecule of ethanol acts as a general base catalyst. Isokinetic relationships are also investigated.

• Bulletin of the Korean Chemical Society
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• v.6 no.5
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• pp.259-263
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• 1985

Rate Constants for the solvolysis of p-methylbenzyl chloride in various ethanol-water mixtures were studied at 30 and $40^{\circ}C$ under various pressures up to 1600 bar. The rates of reaction were increased with increasing temperature and pressure, and decreased with increasing solvent composition of ethanol mole fraction. From the rate constants, the values of the activation parameters (${\Delta}V^{\neq},{\Delta}{\beta}^{\neq},{\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$) were evaluated. The values of ${\Delta}V^{\neq}\;and\;{\Delta}{\beta}^{\neq}$ exhibit the extremum behavior at about 0.30 mole fraction of ethanol. This behavior is discussed in terms of solvent structure variation (electrostriction). From the relation between the reaction rate and the dielectric constant of solvent or the number of water molecule participated in the transition state, it could be postulated that the reaction proceeds through $S_N1$ mechanism.

• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1087-1095
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• 1996

Pervaporation experiments of ternary ethanol/isopropanol/water mixtures were performed using poly(dimethyl siloxane)(PDMS) membrane at $45^{\circ}C$ and the mutual effects of ethanol and isopropanol on the permeation characteristics were studied. Compared to the case of the binary aqueous ethanol or isopropanol solutions, the existence of ethanol or isopropanol in the ternary mixtures resulted in the depression of each other's permeation rate. The depression effect of ethanol on the isopropanol permeation was more considerable than the depression effect of isopropanol on the ethanol permeation. These decreases in the permeation rate were thought to be due to the larger interactions between permeants than the plasticizing effects of ethanol or isopropanol on the polymer membrane. The strong interactions between permeants reduced the driving forces for both ethanol and isopropanol permeation in the ternary mixtures.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2377-2381
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• 2007

Solvolyses of 3,4-dimethoxybenzenesulfonyl chloride (DSC) in water, D2O, CH3OD, and in aqueous binary mixtures of acetone, acetonitrile, 1,4-dioxane, ethanol, methanol, and 2,2,2-trifluoroethanol (TFE) have been investigated at 25.0 oC. Kinetic solvent isotope effects (KSIE) in water and in methanol and product selectivities in alcohol-water mixtures are also reported. The Grunwald-Winstein plot of first-order rate constants for the solvolyic reaction of DSC with YCl shows marked dispersions into separated lines for various aqueous mixtures. With use of the extended Grunwald-Winstein equation, the l and m values obtained are 1.12 and 0.58 respectively for the solvolyses of DSC. The relatively large magnitude of l is consistent with substantial nucleophilic solvent assistance. From Grunwald-Winstein plots the rate data are dissected approximately into contributions from two competing reaction channels. This interpretation is supported for alcohol-water mixtures by the trends of product selectivities, which show a maximum for ethanol-water mixtures. From the KSIE of 1.45 in methanol, it is proposed that the reaction channel favored in methanolwater mixtures and in all less polar media is general-base catalysed and/or is possibly (but less likely) an addition-elimination pathway. Also, the KISE value of 1.35 for DSC in water is expected for SN2-SN1 processes, with minimal general base catalysis, and this mechanism is proposed for solvolyses in the most polar media.