• Title/Summary/Keyword: Ester

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Studies on the Polymeric Surface Active Agent (II);Synthesis Activities of Sodium ${\alpha}-Sulfo$ Fatty Acid Vinyl Ester Oligomers (고분자(高分子) 계면활성제(界面活性劑)에 관(關)한 연구(硏究) (제(第) 2 보(報));나트륨 알파 술폰 지방산(脂肪酸) 비닐에스테르 올리고머류(類)의 계면활성(界面活性))

  • Jeong, No-Hee;Nam, Ki-Dae;So, Boo-Young;So, Hee-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.1
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    • pp.51-57
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    • 1989
  • A series of four sodium ${\alpha}-sulfo$ fatty vinyl ester oligomers including sodium ${\alpha}-sulfo$ lauric acid vinyl ester oligomer, sodium ${\alpha}-sulfo$ myristic acid vinyl ester oligomer, sodium ${\alpha}-sulfo$ palmitic acid vinyl ester oligomer and sodium ${\alpha}-sulfo$ stearic acid vinyl ester oligomer were examined for surface activities such as surface tension, foaming power, foam stability, emulsifying power, dispersion effect, solubilization of orange OT. The critical micelle concentration(CMC) was also evaluated. Consequently, these sodium ${\alpha}-sulfo$ fatty acid vinyl ester oligomers were shown to have a good cohesive power and dispersion effect.

The Variation of Offset Ink Properties According to Methyl Ester of Soy Oil and Resin Molecular Weight (대두유의 Methyl Ester와 수지 분자량에 따른 평판 잉크의 물성 변화에 관한 연구)

  • Park, Jung-Min;Kim, Sung-Bin
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.1
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    • pp.45-59
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    • 2011
  • According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

Cashew Nut Oil: Extraction, Chromatographic and Rheological Characterisation.

  • Vincent Okechuwku ANIDIOBU;Chioma Oluchi ANIDIOBU
    • The Korean Journal of Food & Health Convergence
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    • v.9 no.4
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    • pp.11-18
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    • 2023
  • Oil was extracted from cashew nuts. The physicochemical parameters of the oil were determined. A chromatographic assay of the oil was carried out using Gas Chromatography-Mass Spectrometry. Seventeen compounds were detected: Phenol, Phenol 2-methyl-, Cyclohexene 4, 4-dimethyl-, m-Fluoro-2-diazoacetophenone 4-dimethyl-, Tetradecanoic acid, Phenol 4-octyl-, n-Hexadecanoic acid. Others are 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Hexadecanoic acid methyl ester, Methyl stearate, Dodecanoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid (Z, Z, Z)-, Oleic acid, Octadecanoic acid, Tetracosanoic acid and 9-Octadecenoic acid methyl ester. Among the components are omega three and omega six essential free fatty acids. The rheological profiling and flow properties of cashew nut oil were determined using a Programmable Rheometer. Cashew nut oil exhibits slight dilatant behaviour at the low end of shear rate. The long chain and high molecular weight of its constituents controlled its rheology. Long-chained 9-Octadecenoic acid methyl ester, 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Tetracosanoic acid and methyl stearate, coupled with their high molecular weights are responsible for the shear thickening effect observed. Two models, Carreau-Yasuda and Ostwald-de Waele Power Law were employed to fit the rheological data. The Carreau-Yasuda model followed well the data.

Enzymatic Synthesis of Ethyl Butyrate Using Ester Synthetase Derived from Banana Peel and Pineapple Peel (바나나 껍질과 파인애플 껍질 Ester Synthetase를 이용한 Ethyl Butyrate의 효소적 합성)

  • Yoon, Ki-Hong;Kim, Kee-huck;Lee, Gyu-Hee
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.9
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    • pp.1122-1127
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    • 2017
  • Currently, the consumer trends are increasing towards "natural" in all food systems. Therefore, in the flavor industry, the production of flavor esters by "natural" methods are needed. On the other hand, "natural flavor" is expensive to produce because of the limited natural source. Recently, the flavor obtained from the enzyme or microbial could be represented as "natural flavor". Ethyl butyrate is used most frequently as a fruity aroma in drinks and the processed food industry. In this study, ethyl butyrate was synthesized enzymatically using the ester synthetase obtained from the waste of pineapple and banana peel. The ethyl butyrate production optimization was analyzed using a response surface methodology. The enzyme reaction variances were composed of the ethanol content, butyric acid content, and reaction time. As a result, in ester synthetase obtained from banana peel, the maximum predicted production amounts were 45.8199 mM at an ethanol content of 38.7050 mM, butyric acid content of 50.9019 mM, and reaction time of 4.3662 h. In ester synthetase obtained from pineapple peel, the maximum predicted production was 65.1087 mM at an ethanol content of 54.6502 mM, butyric acid content of 58.7638 mM, and reaction time of 4.7436 h. In conclusion, ethyl butyrate production was shown the more useful using the ester synthetase obtained from pineapple peel than that from banana peel.

Effect of Dietary Lutein and Apocarotenoic Acid Ethyl Ester Supplementation on the Lipid Oxidation of Broiler Meat during Storage (Lutein과 Apocarotenoic Acid Ethyl Ester 급여가 계육의 저장중 지질 산화에 미치는 영향)

  • 민병진;김혜정;강창기;이성기
    • Food Science of Animal Resources
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    • v.23 no.3
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    • pp.209-214
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    • 2003
  • This study was carried out to investigate the influence of dietary xanthophylls(lutein and apocarotenoic acid ethyl ester) supplementation on the antioxidation of broiler meat. The broilers fed with 10 ppm or 20 ppm xanthophylls were raised for 6 weeks and then slaughtered. The broiler meats were stored at 3$^{\circ}C$ for 9 days and frozen at -18$^{\circ}C$ for 4 months until analysis, respectively. The pH of all treatments significantly(p<0.05) increased during the storage periods. The pH of the thigh was higher than that of the breast. TBARS (thiobarbituric acid reactive substance) and POV(peroxide value) were higher in thigh than breast. All meats from broiler fed with lutein and apocarotenoic acid ethyl ester(apo-ester) had greater antioxidant properties during the storage period than control meat(p<0.05). Antioxidant activity of dietary xanthophylls supplementation was more effective in thigh than breast, and in broiler meats during frozen storage than chilled storage. The higher concentration of xanthophylls in feed, the more inhibition of lipid oxidation in meat during storage. The meat from broiler fed with 20 ppm of lutein showed the highest antioxidant property during both refrigerated and frozen storage although there was no significant difference between lutein and apo-ester(p>0.05). Consequently, this results indicated that the antioxidant activity of dietary xanthophylls(lutein and apocarotenoic acid ethyl ester) supplementation was more effective.

Developing Eco-Friendly Resin Wax Remover for Printing Table of Flat Screen (친환경 플랫스크린 수지왁스용해제의 개발에 관한 연구)

  • Son, Eun-Jong;Park, Geon-Hui;Lee, Beom-Su;Im, Sang-Jun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.95-97
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    • 2008
  • In this study eco-friendly wax remover for printing table of flat screen was investigated. Seven organic solvents, diethylene glycol monomethyl ester, triethylene glycol monomethyl ester, triethylene glycol monobutyl ester, tripropylene glycol monomethyl ester, dimethyl sulfoxide(DMSO), trichloro ethylene(TCE), tolune, were used as resin wax remover. The resin wax solubility with solvents was investigated. DMSO was found to be the most suitable eco-friendly resin wax remover.

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A Triterpene Glucosyl Ester from the Roots of Rubus crataesifolius

  • Jung, Sung-Wook;Shin, Myung-Hee;Jung, Jee-H.;Kim, Nam-Deuk;Im, Kwang-Sik
    • Archives of Pharmacal Research
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    • v.24 no.5
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    • pp.412-415
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    • 2001
  • Along with five known triterpene glycosides, a new triterpene glucosyl ester, named crataegioside, was isolated from the roots of Rubus crataesifolius Bunge. The structure was established as ilexosapogenin A 28-O-$\beta$-D-glucopyranosyl ester by chemical and spectroscopic methods.

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Flavor Components in Mash of Takju Prepared by Different Raw Materials (원료를 달리하여 담금한 탁주 술덧의 향기성분)

  • Lee, Joo-Sun;Lee, Taik-Soo;Park, Sung-Oh;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.28 no.2
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    • pp.316-323
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    • 1996
  • Flavor components in mash of Takju prepared by different raw materials such as nonglutinous rice, glutinous rice, barley and wheat flour were detected by GC and GC-MS method using non-polar column. Seven alcohols, 15 esters, 10 organic acids, 1 aldehyde, 4 benzenes, 3 phenols, 8 alkans, 2 ketones and 5 others were found in takju after 16 day of fermentation. takju by wheat flour had the most various components of volatile flavor. Treatment with addition starter had less flavor component than that without addition starter in takju by nonglutinous rice. Nine kinds of flavor components including acetic acid ethyl ester, 3- methyl-1-butanol, acetic acid, ethyl benzene, acetic acid 3-methyl butyl ester, 2-phenylethanol, 2,6-di-tert-butyl-4-methyl phenol. plumbagic acid and 1,2-benzenedicarboxylic acid dibutyl ester were commonly detected in all the treatments. Especially, 2,4,0-trimethyl-1,3-benzenediamine was isolated in takju that was made of nonglutinous rice without addition starter. Diethyl sulfide, 4-methoxy benzaldehyde, docosane and 2-methyl propyl octadecanoic acid were isolated from takju by nonglutinous rice with addition starter. Propionic acid ethyl ester, acetic acid butyl ester, 2-methyl butane and 3-methyl pentane were isolated from takju glutinous rice. 2-Hydroxy-4-methyl pentanoic acid and 2-methyl tridecane were isolated from akju by barley 3-(Methylthio)-1-propanol. hexanoic acid ethyl ester, butanoic acid monomethyl ester, tridecanoic acid, ethyl tetramethyl cyclopentadiene and 1,5-diaza-2,9-diketocyclotetradecane were isolated from takju by wheat flour. Major volatile flavor components were acetic acid ethyl ester, 3-methyl-1-butanol, acetic acid and 2-phenylethanol.

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