• Title/Summary/Keyword: Error diffusion

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Modeling Residual Water in the Gas Diffusion Layer of a Polymer Electrolyte Membrane Fuel Cell and Analyzing Performance Changes (고분자 전해질막 연료전지의 기체확산층 내부 잔류수 모델링 및 성능변화해석)

  • Jiwon Jang;Junbom Kim
    • Applied Chemistry for Engineering
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    • v.35 no.1
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    • pp.16-22
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    • 2024
  • Polymer electrolyte membrane fuel cells have the advantage of low operating temperatures and fast startup and response characteristics compared to others. Simulation studies are actively researched because their cost and time benefits. In this study, the resistance of water residual in the gas diffusion layer (GDL) of the unit cell was added to the existing equation to compare the actual data with the model data. The experiments were conducted with a 25 cm2 unit cell, and the samples were separated into stopping times of 0, 10, and 60 minutes following primary impedance measurement, activation, and polarization curve data acquisition. This gives 0, 10, and 60 minutes for the residual water in the GDL to evaporate. Without the rest period, the magnitude of the performance improvement was not significantly different at the same potential and flow rate, but the rest period did improve the performance of the membrane electrode assembly when measuring impedance. By changing the magnitude of the resistance reduction to an overvoltage, the voltage difference between the fuel cell model with and without residual water was compared, and the error rate in the high current density region, which is dominated by concentration losses, was reduced.

An Evaluation of the Rapid Antimicrobial Susceptibility Test by VITEK MS and VITEK 2 Systems in Blood Culture (혈액배양에서 VITEK MS와 VITEK 2 System을 이용한 신속 항생제 감수성 시험의 유용성 평가)

  • Park, Kang-Gyun;Yu, Young-Bin;Yook, Keundol;Kim, Sang-Ha;Kim, Sunghyun;Kim, Young Kwon
    • Korean Journal of Clinical Laboratory Science
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    • v.49 no.3
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    • pp.279-284
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    • 2017
  • The results of rapid antimicrobial susceptibility test (AST) in blood cultures were obtained by inoculating the bacteria directly into the VITEK MS and the VITEK 2 systems without subculturing in the blood culture positive medium. The obtained results were compared with the results using a standard method to evaluate their reliability and accuracy. The direct AST results in blood culture positive specimens were 97.9% (1,936/1,978), consistent with the standard AST results. Gram-positive bacteria showed a concordance rate of 97.2% (1,051/1,081), a very major error rate of 0.5% (5/1,081), a major error rate of 0.1% (1/1,081), and a minor error rate of 2.2% (24/1,081). Staphylococcus epidermidis was the main cause of discordance, and gentamicin (N=9) and fusidic acid (N=8) showed high errors. The overall concordance rate and minor error among the Gram-negative bacteria were 98.6% (885/897) and 1.4% (12/897), respectively. Escherichia coli and Pseudomonas aeruginosa were the major causative bacteria of Gram-negative bacteria. Among them, amoxicillin/clavulanic acid (N=3) showed high error. Direct AST met the CLSI criteria and shortened the reporting time by 24 hours; however, we found that there was a need to perform an addition test via disk diffusion for antimicrobials with very large errors. These results suggest that the method of direct AST in blood culture positive medium may be very useful in efficiently treating patients.

Measurement of a refractive index and thickness of silicon-dioxide thin film on LCD glass substrate using a variable angle ellipsometry (가변 입사각 타원 해석법을 사용한 유리기판위의 이산화규소박막의 굴절율 및 두께 측정)

  • Pang, H. Y.;Kim, H. J.;Kim, S. Y.;Kim, B. I.
    • Korean Journal of Optics and Photonics
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    • v.8 no.1
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    • pp.31-36
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    • 1997
  • We measured refractive indices and thicknesses of SiO$_2$ thin films that have been plated on LCD glass substrate for the purpose of preventing the out-diffusion of sodium ions. The best experimental condition to determine refractive index and thickness of SiO$_2$ thin film by using ellipsometry is searched for, where ⅰ) the film thickness is increased uniformly by 20 $\AA$ from 0 $\AA$ to the period thickness while the angle of incidence is fixed and ⅱ) the angle of incidence is increased uniformly by 1$^{\circ}$ from 45$^{\circ}$ to 70$^{\circ}$ while the film thickness is fixed. We estimated the errors in determining the refractive index and thickness by comparing the measurement error of $\Delta$ and Ψ with the calculated one. The ellipsometric constants of SiO$_2$ thin film on LCD glass substrate are measured at several angle of incidence around the Brewster angle, which is the best angle if the experimental error of ellipsometer is not sensitive to the incident angle. Also the best fit refractive index and thickness of SiO$_2$ thin film to these ellipsometric constants measured at several angle of incidenc eas well as the best fit ones to the SE data are obtained using regressional analysis.

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Moisture Content Change of Korean Red Pine Logs During Air Drying: II. Prediction of Moisture Content Change of Korean Red Pine Logs under Different Air Drying Conditions (소나무 원목의 천연건조 중 함수율 변화: II. 소나무 원목의 천연건조 중 함수율 변화 예측)

  • HAN, Yeonjung;CHANG, Yoon-Seong;EOM, Chang-Deuk;LEE, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.6
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    • pp.732-750
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    • 2019
  • Air drying was carried out on 15 Korean red pine logs to provide a prediction model of the moisture content (MC) change in the wood during drying. The final MC was 17.4% after 880 days since the beginning of air drying in the summer for 6 Korean red pine logs with 68.7% initial MC. The final MC was 16.0% after 760 days since the beginning of air drying in the winter for 9 Korean red pine logs with 35.8% initial MC. A regression model with R-squared of 0.925 was obtained as a result of multiple regression analyses with initial MC, top diameter, temperature, relative humidity, and wind speed as independent variable and and MC change during air drying as dependent variable. The initial MC and top diameter, which is the characteristic of Korean red pine, have greater effect on the MC decrease during air drying compared to meteorological factors such as the temperature, relative humidity, and wind speed. Two-dimensional mass transfer analysis was performed to predict the MC distribution of Korean red pine logs during air drying. Two prediction models with different air drying days and different meteorological factors for the determination of the diffusion coefficient and surface emission coefficient were presented. The error between the different two methods ranged from 0.1 to 0.8% and the difference from the measured value ranged from 2.2 to 3.6%. By measuring the internal MC during air drying of Korean pine logs with various initial MC and diameter, and calculating the moisture transfer coefficient in wood for each meteorological condition, the error of the prediction model can be reduced.

Quantifying Chloride Ingress in Cracked Concrete Using Image Processing (이미지 분석을 이용한 균열 콘크리트 내 염화물 침투 정량화 평가)

  • Kim, Kun-Soo;Park, Ki-Tae;Kim, Jaehwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.4
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    • pp.57-64
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    • 2022
  • Chloride, which is one of the main deterioration factors in reinforced concrete structures, can degrade the performance of the structure due to chloride-induced corrosion of steel. Chloride content at steel depth or the rate of chloride penetration is necessary to determine deterioration of reinforced concrete or to calculate initiation time of steel corrosion caused by chloride attack. Chlorides in concrete are generally identified with typical two methods including chloride profiling using potentiometric titration method and discoloration method using AgNO3 solution. The former is advantageous to estimate chloride penetration rate (diffusion coefficient in general) with measured chloride contents directly, but it is laborious. In the case of latter, while the result is obtained easily with the range of discoloration, the error may occur depending on workmanship when the depth of chloride ingress is measured. This study shows that chloride penetrated depth is evaluated with the results obtained from discoloration method through image analysis, thereby the error is minimized by workmanship. In addition, the effect of micro-crack in concrete is studied on chloride penetration. In conclusion, the depth of chloride penetration was quantified with image analysis and as it was confirmed that chlorides can rapidly penetrate through micro-cracks, caution is especially required for cracks in concrete structure.

Study on Optimized Manual Development and Optimum Lighting System within Luminance-based Tunnel (휘도기반 터널내 운전자 적정조명시스템 개발 연구)

  • Lee, Mi-Ae;Kim, Yeon-Hwa;Han, Seung-Hun;Kim, Ji-Heon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.4
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    • pp.18-29
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    • 2015
  • The purposes of this research and development are as follows: first, to provide pleasant driving environments inside tunnels; second, to improve the current illumination environments lacking in diffusion luminance meters to meet tunnel lighting standards; and, third, to reduce the consumption of tunnel lighting energy accounting for approximately 65% of tunnel maintenance costs because of inadequate visual environments and tunnel operations. Further details are listed below. Firstly, an image luminance meter for tunnels that can implement the L20-method which is a tunnel luminance method that follows the international standards of CIE88, which was developed in order to improve and change the existing illumination-based tunnel lighting operation system to a luminance-based system. (The margin of error of below 5% according to the results of a test by an authorized agency and field test). Secondly, early illumination control is possible since the lighting control system that can be operated based on luminance enables interlocking control of the inside and outside of a tunnel using ethernet communication. Thirdly, guidelines for field application of the system are proposed. In addition, the luminance inducers of tunnels are found and the reflexibility of each facility that may reduce luminance of the boundaries is also proposed. Fourthly, as a result of a test bed, power consumption of luminance-based lighting operations decreased by 15.6% compared to illumination-based operations. Applying the feedback controls and maintenance factors of internal/external luminance meters, it reduced by 36.4%. Therefore, we became able to provide a luminance-based lighting operation system that complies with tunnel lighting design standards and provides a visual environment for drivers.

Implementing the Urban Effect in an Interpolation Scheme for Monthly Normals of Daily Minimum Temperature (도시효과를 고려한 일 최저기온의 월별 평년값 분포 추정)

  • 최재연;윤진일
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.4
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    • pp.203-212
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    • 2002
  • This study was conducted to remove the urban heat island effects embedded in the interpolated surfaces of daily minimum temperature in the Korean Peninsula. Fifty six standard weather stations are usually used to generate the gridded temperature surface in South Korea. Since most of the weather stations are located in heavily populated and urbanized areas, the observed minimum temperature data are contaminated with the so-called urban heat island effect. Without an appropriate correction, temperature estimates over rural area or forests might deviate significantly from the actual values. We simulated the spatial pattern of population distribution within any single population reporting district (city or country) by allocating the reported population to the "urban" pixels of a land cover map with a 30 by 30 m spacing. By using this "digital population model" (DPM), we can simulate the horizontal diffusion of urban effect, which is not possible with the spatially discontinuous nature of the population statistics fer each city or county. The temperature estimation error from the existing interpolation scheme, which considers both the distance and the altitude effects, was regressed to the DPMs smoothed at 5 different scales, i.e., the radial extent of 0.5, 1.5, 2.5, 3.5 and 5.0 km. Optimum regression models were used in conjunction with the distance-altitude interpolation to predict monthly normals of daily minimum temperature in South Korea far 1971-2000 period. Cross validation showed around 50% reduction in terms of RMSE and MAE over all months compared with those by the conventional method.conventional method.

Equilibrium Moisture Contents and Thin Layer Drying Equations of Cereal Grains and Mushrooms (II) - for Oak Mushroom (Lentinus erodes) - (곡류 및 버섯류의 평형함수율 및 박층건조방정식에 관한 연구(II) - 표고버섯에 대하여 -)

  • Keum, D. H.;Kim, H.;Hong, N. U.
    • Journal of Biosystems Engineering
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    • v.27 no.3
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    • pp.219-226
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    • 2002
  • Desorption equilibrium moisture contents of oak mushroom were measured by the static method using salt solutions at flour temperature levels of 35$\^{C}$, 45$\^{C}$, 55$\^{C}$ and 6$\^{C}$ and five relative humidity levels in the range from 11.0% to 90.8%. EMC data were fitted to the modified Henderson, Chung-Pfost, modified Halsey and modified Oswin models using nonlinear regression analysis. Drying tests far oak mushroom were conducted in an experimental dryer equipped with air conditioning unit. The drying test were performed in triplicate at flour air temperatures of 35$\^{C}$, 45$\^{C}$, 55$\^{C}$ and 65$\^{C}$ and three relative humidities of 30%, 50% and 70% respectively. Measured moisture ratio data were fitted to the selected four drying models(Lewis, Page, simplified diffusion and Thompson models) using stepwise multiple regression analysis. The results of comparing root mean square errors for EMC models showed that modified Halsey was the best model, and modified Oswin models could be available far oak mushroom. The results of comparing coefficients of determination and root mean square errors of moisture ratio for four drying models showed that Page model were found to fit adequately to all drying test data with a coefficient of determination of 0.9990 and root mean square error of moisture ratio of 0.00739.

A Study on Effect of Intellectual Study Cadastral Data Maintenance Business - Focusing on Uiwang-city - (지적공부 자료정비 사업의 효과에 관한 연구 - 경기도 의왕시를 중심으로 -)

  • Choe, cho-won;Shin, soon-ho
    • Journal of Cadastre & Land InformatiX
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    • v.47 no.1
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    • pp.237-250
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    • 2017
  • This study focuses on the maintenance of the registration details of the cadastral study (drawings, chiefs) in relation to Uiwang city real estate administration information unification project by the data maintenance business. The purpose of this study is to provide high quality data and improve the efficiency of data maintenance business in the unification of real estate administration information together with the intellectual study diffusion maintenance model in the future. In this study, based on the results of the intellectual study data maintenance project and the effectiveness of institutional, temporal and cost aspects, it was able to show the effect of the data maintenance project. And analyzed the current situation, typed the error shown here, and developed the maintenance plan and maintenance result.

Effects of Two-dimensional Heat and Mass Transports on Condensational Growth of Soot Particles in a Tubular Coater (원형관 코팅장치에서 연소 입자의 응축성장에 미치는 2차원 열 및 물질전달의 영향)

  • Park, Sung Hoon
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.163-171
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    • 2013
  • Soot particles emitted from combustion processes are often coated by non-absorbing organic materials, which enhance the global warming effect of soot particles. It is of importance to study the condensation characteristics of soot particles experimentally and theoretically to reduce the uncertainty of the climate impact of soot particles. In this study, the condensational growth of soot particles in a tubular coater was modeled by a one-dimensional (1D) plug flow model and a two-dimensional (2D) laminar flow model. The effects of 2D heat and mass transports on the predicted particle growth were investigated. The temperature and coating material vapor concentration distributions in radial direction, which the 1D model could not accounted for, affected substantially the particle growth in the coater. Under the simulated conditions, the differences between the temperatures and vapor concentrations near the wall and at the tube center were large. The neglect of these variations by the 1D model resulted in a large error in modeling the mass transfer and aerosol dynamics occurring in the coater. The 1D model predicted the average temperature and vapor concentration quite accurately but overestimated the average diameter of the growing particles considerably. At the outermost grid, at which condensation begins earliest due to the lowest temperature and saturation vapor concentration, condensing vapor was exhausted rapidly because of the competition between condensations on the wall and on the particle surface, decreasing the growth rate. At the center of the tube, on the other hand, the growth rate was low due to high temperature and saturation vapor concentration. The effects of Brownian diffusion and thermophoresis were not high enough to transport the coating material vapor quickly from the tube center to the wall. The 1D model based on perfect radial mixing could not take into account this phenomenon, resulting in a much higher growth rate than what the 2D model predicted. The result of this study indicates that contrary to a previous report for a thermodenuder, 2D heat and mass transports must be taken into account to model accurately the condensational particle growth in a coater.