• Corrosion Science and Technology
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• 제7권6호
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• pp.350-361
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• 2008

Canada's oil sands contain one of the largest reserves of oil in the world. According to recent estimates, there are nearly 180 billion barrels of oil in the Canadian oil sands trapped in a complex mixture of sand, water and clay. More than 40 companies have been currently operating or developing oil sands facilities since the first production in 1967. The process of oil sands upgrading is similar with down stream refinery, but the corrosion environment in upgrading refinery is often more severe than in the refinery because of high chlorides, mineral contents, carbonic acid, heavy viscosity and fouling, higher naphthenic acid [$NA-R(CH_{2})nCOOH$], and greater sulfur contents. Naphthenic acid corrosion (NAC) which is one of the most critical corrosion issues in up & downstream refinery plants was observed for the first time in 1920's in refinery distillation processes of Rumania, Azerbaizan (Baku), Venezuela, and California. As a first API report, the 11th annual meeting stated sources and mechanism of NAC in early 1930's. API has been developing the risk base standards, such as API RP580, 571, and Publication 581 which are based on the worst NAC damage in the world since 2000. Nevertheless not only the NAC phenomena and control in Canadian sands oil process are not much widely known but also there are still no engineering guidances for the Canadian sands oil in API standards. This paper will give NAC phenomina and materials selection guidance against NA environment in Canadian oil sands upgrading processes.

• 대한기계학회논문집A
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• 제30권5호
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• pp.533-542
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• 2006

In order to assess the integrity of pipes with local thinning area, the plastic strain as well as the elastic strain at the root of thinned region are required particularly when fluctuating load is applied to the pipe. For estimating elastic-plastic strain at local wall thinning area in a straight pipe under tensile load, an estimation model with idealized fully circumferential constant depth wall thinning area is proposed. Based on the compatibility and equilibrium equations a nonlinear estimation equation, from which local elastic-plastic strain can be determined as a function of pipe/defect geometry, material and the applied strain was derived. Estimation results are compared with those from detailed elastic-plastic finite element analysis, which shows good agreements. Noting that practical wall thinning in nuclear piping has not only a circular shape but also a finite circumferential length, the proposed solution for the ideal geometry is extended based on two-dimensional and three-dimensional numerical analysis of pipes with circular wall thinning.