• Title/Summary/Keyword: Equivalent leading method

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Resolution of a Multi-Step Electron Transfer Reaction by Time Resolved Impedance Measurements: Sulfur Reduction in Nonaqueous Media

  • Park, Jin-Bum;Chang, Byoung-Yong;Yoo, Jung-Suk;Hong, Sung-Young;Park, Su-Moon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.9
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    • pp.1523-1530
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    • 2007
  • The first reduction peak of the cyclic voltammogram (CV) for sulfur reduction in dimethyl sulfoxide has been studied using time resolved Fourier transform electrochemical impedance spectroscopic (FTEIS) analysis of small potential step chronoamperometric currents. The FTEIS analysis results reveal that the impedance signals obtained during short potential steps can be resolved into electron transfer reactions of two different time constants in a high frequency region. The FTEIS method provides snap shots of impedance profiles during an earlier phase of the reaction, leading to time resolved EIS measurements. Our results obtained by the FTEIS analysis are consistent with a series of electron transfer and chemical equilibrium steps of a complex reaction, making up an ECE (electrochemical-chemical-electrochemical) mechanism postulated from the results of computer simulation.

An innovative idea for developing a new gamma-ray dosimetry system based on optical colorimetry techniques

  • Ioan, Mihail-Razvan
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.519-525
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    • 2018
  • Obtaining knowledge of the absorbed dose up-taken by a certain material when it is exposed to a specific ionizing radiation field is a very important task. Even though there are a plenitude of methods for determining the absorbed dose, each one has its own strong points and also drawbacks. In this article, an innovative idea for the development of a new gamma-ray dosimetry system is proposed. The method described in this article is based on optical colorimetry techniques. A color standard is fixed to the back of a BK-7 glass plate and then placed in a point in space where the absorbed dose needs to be determined. Gamma-ray-induced defects (color centers) in the glass plate start occurring, leading to a degree of saturation of the standard color, which is proportional, on a certain interval, to the absorbed dose. After the exposure, a high-quality digital image of the sample is taken, which is then processed (MATLAB), and its equivalent $I_{RGB}$ intensity value is determined. After a prior corroboration between various well-known absorbed dose values and their corresponding $I_{RGB}$ values, a calibration function is obtained. By using this calibration function, an "unknown" up-taken dose value can be determined.

Analysis of Rectangular Plates under Distributed Loads of Various Intensity with Interior Supports at Arbitrary Positions (분포하중(分布荷重)을 받는 구형판(矩形板)의 탄성해석(彈性解析))

  • Suk-Yoon,Chang
    • Bulletin of the Society of Naval Architects of Korea
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    • v.13 no.1
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    • pp.17-23
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    • 1976
  • Some methods of analysis of rectangular plates under distributed load of various intensity with interior supports are presented herein. Analysis of many structures such as bottom, side shell, and deck plate of ship hull and flat slab, with or without internal supports, Floor systems of bridges, included crthotropic bridges is a problem of plate with elastic supports or continuous edges. When the four edges of rectangular plate is simply supported, the double Fourier series solution developed by Navier can represent an exact result of this problem. If two opposite edges are simply supported, Levy's method is available to give an "exact" solution. When the loading condition and supporting condition of a plate does not fall into these cases, no simple analytic method seems to be feasible. Analysis of a simply supported rectangular plate under irregularly distributed loads of various intensity with internal supports is carried out by applying Navier solution well as the "Principle of Superposition." Finite difference technique is used to solve plates under irregularly distributed loads of various intensity with internal supports and with various boundary conditions. When finite difference technique is applied to the Lagrange's plate bending equation, any of fourth order derivative term in this equation produces at least five pivotal points leading to some troubles when the resulting linear algebraic equations are to be solved. This problem was solved by reducing the order of the derivatives to two: the fourth order partial differential equation with one dependent variable, namely deflection, is changed to an equivalent pair of second order partial differential equations with two dependent variables. Finite difference technique is then applied to transform these equations to a set of simultaneous linear algebraic equations. Principle of Superposition is then applied to handle the problems caused by concentrated loads and interior supports. This method can be used for the cases of plates under irregularly distributed loads of various intensity with arbitrary conditions such as elastic supports, or continuous edges with or without interior supports, and this method can also be solve the influence values of deflection, moment and etc. at arbitrary position of plates under the live load.

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Nonlinear stability of the upper chords in half-through truss bridges

  • Wen, Qingjie;Yue, Zixiang;Liu, Zhijun
    • Steel and Composite Structures
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    • v.36 no.3
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    • pp.307-319
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    • 2020
  • The upper chords in half-through truss bridges are prone to buckling due to a lack of the upper transverse connections. Taking into account geometric and material nonlinearity, nonlinear finite-element analysis of a simple supported truss bridge was carried out to exhibit effects of different types of initial imperfections. A half-wave of initial imperfection was proved to be effective in the nonlinear buckling analysis. And a parameter analysis of initial imperfections was also conducted to reveal that the upper chords have the greatest impact on the buckling, followed by the bottom chords, vertical and diagonal web members. Yet initial imperfections of transverse beams have almost no effect on the buckling. Moreover, using influence surface method, the combinatorial effects of initial imperfections were compared to demonstrate that initial imperfections of the upper chords play a leading role. Furthermore, the equivalent effective length coefficients of the upper chord were derived to be 0.2~0.28 by different methods, which implies vertical and diagonal web members still provide effective constraints for the upper chord despite a lack of the upper transverse connections between the two upper chords. Therefore, the geometrical and material nonlinear finite-element method is effective in the buckling analysis due to its higher precision. Based on nonlinear analysis and installation deviations of members, initial imperfection of l/500 is recommended in the nonlinear analysis of half-through truss bridges without initial imperfection investigation.

Polymerization Shrinkage Behavior Measured by Digital Image Correlation for Methacrylate-based and Silorane-based Composites During Dental Restoration (디지털 이미지 상관법을 이용한 Methacrylate기질과 Silorane기질 복합레진의 치아 수복 시 중합수축거동)

  • Park, Jung-Hoon;Choi, Nak-Sam
    • Composites Research
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    • v.33 no.3
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    • pp.125-132
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    • 2020
  • The polymerization shrinkage behavior of dimethacrylate-based composite (Clearfil AP-X, Kuraray) and silorane-based composite (Filtek P90, 3M ESPE) used for dental composite restorations was measured using digital image correlation method. The stress distribution on the surface of specimen was calculated by finite element analysis with equivalent elastic modulus and was compared with the measured shrinkage distribution. Camera images were monitored by a CCD camera during and after the irradiation of light. As a result of the DIC analysis, a non-uniform shrinkage distribution was observed in both composite resins, and the resin core inside the ring specimen had free flowability, leading to in greater shrinkage strain than the resin/ring interfacial region. It was observed that as the distance from the center of the resin increased, the radial average shrinkage strain decreased. The radial average shrinkage strain during light irradiation occurred to be 33% for P90 and 57% for AP-X of the entire strain at the end of the test. The shrinkage behavior of P90 and AP-X was measured to be significantly different from each other during light irradiation. In the resin near the resin/ring interface, it was confirmed that the tensile strain rapidly formed to increase after light irradiation, causing a tensile stressed, interface weak.

Life Prediction of Composite Pressure Vessels Using Multi-Scale Approach (멀티 스케일 접근법을 이용한 복합재 압력용기의 수명 예측)

  • Jin, Kyo-Kook;Ha, Sung-Kyu;Kim, Jae-Hyuk;Han, Hoon-Hee;Kim, Seong-Jong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.9
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    • pp.3176-3183
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    • 2010
  • A multi-scale fatigue life prediction methodology of composite pressure vessels subjected to multi-axial loading has been proposed in this paper. The multi-scale approach starts from the constituents, fiber, matrix and interface, leading to predict behavior of ply, laminates and eventually the composite structures. The multi-scale fatigue life prediction methodology is composed of two steps: macro stress analysis and micro mechanics of failure based on fatigue analysis. In the macro stress analysis, multi-axial fatigue loading acting at laminate is determined from finite element analysis of composite pressure vessel, and ply stresses are computed using a classical laminate theory. The micro stresses are calculated in each constituent from ply stresses using a micromechanical model. Three methods are employed in predicting fatigue life of each constituent, i.e. a maximum stress method for fiber, an equivalent stress method for multi-axially loaded matrix, and a critical plane method for the interface. A modified Goodman diagram is used to take into account the generic mean stresses. Damages from each loading cycle are accumulated using Miner's rule. Monte Carlo simulation has been performed to predict the overall fatigue life of a composite pressure vessel considering statistical distribution of material properties of each constituent, fiber volume fraction and manufacturing winding angle.

Study on new type vehicle fuel economy correction formula review according to the applicable (신형식 자동차 적용에 따른 연비 보정식 검토에 관한 연구)

  • Lim, Jaehyuk;Kim, Sungwoo;Lee, Minho;Kim, Kiho
    • Journal of Energy Engineering
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    • v.25 no.4
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    • pp.198-206
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    • 2016
  • Fuel economy label will be used as a national indicator in energy management, leading to the development of car technology manufacturer and plays a role in providing consumer vehicle purchase information. But the government's fuel economy label is continued consumer complaint is different and diminishing fuel economy were introduced by the government to measure the exact fuel economy label than resetting the 5-cycle test method in the US for the domestic vehicle standards. Originally two test mode in order to reduce the impact of the sharp increase in the resources required but methods of calculating a measured result value by driving all of the five test mode a variety of environmental conditions and the running pattern is reflected to the fuel economy label (city( FTP-75 mode), highway(HWFET mode)) and using 5-cycle correction formula for calculating a fuel consumption value and the equivalent value to calculate the result of the 5-cycle test. The compensation was calculated expression 30s, 5-Cycle Test Method of vehicles in 2011 was considered necessary to review the existing 5-cycle correction formula for the New Type car due to the recent rapid development of automotive technology. In this study, recent technology is targeting 14 units New Type car applied over the same test method and the existing check test mode specific fuel economy properties and, as a result of analyzing the corrected expression differences that have already been developed with the existing test vehicle resulting large did not show the difference was found to correction formula also not getting the existing fuel correction expression significant effect on the improvement of the current automobile technology as a maximum error of less than 1.5%.

The Current Status of the Warsaw Convention and Subsequent Protocols in Leading Asian Countries (아시아 주요국가(主要國家)들에 있어서의 바르샤바 체제(體制)의 적용실태(適用實態)와 전망(展望))

  • Lee, Tae-Hee
    • The Korean Journal of Air & Space Law and Policy
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    • v.1
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    • pp.147-162
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    • 1989
  • The current status of the application and interpretation of the Warsaw Convention and its subsequent Protocols in Asian countries is in its fredgling stages compared to the developed countries of Europe and North America, and there is thus little published information about the various Asian governments' treatment and courts' views of the Warsaw System. Due to that limitation, the accent of this paper will be on Korea and Japan. As one will be aware, the so-called 'Warsaw System' is made up of the Warsaw Convention of 1929, the Hague Protocol of 1955, the Guadalajara Convention of 1961, the Guatemala City Protocol of 1971 and the Montreal Additional Protocols Nos. 1,2,3 and 4 of 1975. Among these instruments, most of the countries in Asia are parties to both the Warsaw Convention and the Hague Protocol. However, the Republic of Korea and Mongolia are parties only to the Hague Protocol, while Burma, Indonesia and Sri Lanka are parties only to the Warsaw Convention. Thailand and Taiwan are not parties only to the convention or protocol. Among Asian states, Indonesia, the Phillipines and Pakistan are also parties to the Guadalajara Convention, but no country in Asia has signed the Guatemala City Protocol of 1971 or the Montreal Additional Protocols, which Protocols have not yet been put into force. The People's Republic of China has declared that the Warsaw Convention shall apply to the entire Chinese territory, including Taiwan. 'The application of the Warsaw Convention to one-way air carriage between a state which is a party only to the Warsaw Convention and a state which is a party only to the Hague Protocol' is of particular importance in Korea as it is a signatory only to the Hague Protocol, but it is involved in a great deal of air transportation to and from the united states, which in turn is a party only to the Warsaw Convention. The opinion of the Supreme Court of Korea appears to be, that parties to the Warsaw Convention were intended to be parties to the Hague Protocol, whether they actually signed it or not. The effect of this decision is that in Korea the United States and Korea will be considered by the courts to be in a treaty relationship, though neither State is a signatory to the same instrument as the other State. The first wrongful death claim in Korea related to international carriage by air under the Convention was made in Hyun-Mo Bang, et al v. Korean Air Lines Co., Ltd. case. In this case, the plaintiffs claimed for damages based upon breach of contract as well as upon tort under the Korean Civil Code. The issue in the case was whether the time limitation provisions of the Convention should be applicable to a claim based in tort as well as to a claim based in contract. The Appellate Court ruled on 29 August 1983 that 'however founded' in Article 24(1) of the Convention should be construed to mean that the Convention should be applicable to the claim regardless of whether the cause of action was based in tort or breach of contract, and that the plaintiffs' rights to damages had therefore extinguished because of the time limitation as set forth in Article 29(1) of the Convention. The difficult and often debated question of what exactly is meant by the words 'such default equivalent to wilful misconduct' in Article 25(1) of the Warsaw Convention, has also been litigated. The Supreme Court of Japan dealt with this issue in the Suzuki Shinjuten Co. v. Northwest Airlines Inc. case. The Supreme Court upheld the Appellate Court's ruling, and decided that 'such default equivalent to wilful misconduct' under Article 25(1) of the Convention was within the meaning of 'gross negligence' under the Japanese Commercial Code. The issue of the convention of the 'franc' into national currencies as provided in Article 22 of the Warsaw Convention as amended by the Hague Protocol has been raised in a court case in Korea, which is now before the District Court of Seoul. In this case, the plaintiff argues that the gold franc equivalent must be converted in Korean Won in accordance with the free market price of gold in Korea, as Korea has not enacted any law, order or regulation prescribing the proper method of calculating the equivalent in its national currency. while it is unclear if the court will accept this position, the last official price of gold of the United States as in the famous Franklin Mint case, Special Drawing Right(SDR) or the current French franc, Korean Air Lines has argued in favor of the last official price of gold of the United States by which the air lines converted such francs into us Dollars in their General Conditions of Carriage. It is my understanding that in India, an appellate court adopted the free market price valuation. There is a report as well saying that if a lawsuit concerning this issue were brought in Pakistan, the free market cost of gold would be applied there too. Speaking specifically about the future of the Warsaw System in Asia though I have been informed that Thailand is actively considering acceding to the Warsaw Convention, the attitudes of most Asian countries' governments towards the Warsaw System are still wnot ell known. There is little evidence that Asian countries are moving to deal concretely with the conversion of the franc into their own local currencies. So too it cannot be said that they are on the move to adhere to the Montreal Additional Protocols Nos. 3 & 4 which attempt to basically solve many of the current problems with the Warsaw System, by adopting the SDR as the unit of currency, by establishing the carrier's absolute liability and an unbreakable limit and by increasing the carrier's passenger limit of liability to SDR 100,000, as well as permiting the domestic introduction of supplemental compensation. To summarize my own sentiments regarding the future, I would say that given the fact that Asian air lines are now world leaders both in overall size and rate of growth, and the fact that both Asian individuals and governments are becoming more and more reliant on the global civil aviation networks as their economies become ever stronger, I am hopeful that Asian nations will henceforth play a bigger role in ensuring the orderly and hasty development of a workable unified system of rules governing international commercial air carriage.

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Refractometric Glucose Biosensor Incorporating a Vertically Coupled Microring Resonator in Polymeric Waveguides (수직형 폴리머 마이크로링 공진기 기반의 글루코스 바이오 센서)

  • Kim, Gun-Duk;Son, Keun-Sik;Lee, Hak-Soon;Kim, Ki-Do;Lee, Sang-Shin
    • Korean Journal of Optics and Photonics
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    • v.19 no.2
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    • pp.127-131
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    • 2008
  • A refractometric glucose biosensor incorporating a vertically coupled microring resonator in polymers was proposed and realized. The ring was covered with a target analyte of glucose solution with a certain concentration, so that its effective refractive index could be altered and, as a result, the resonance wavelength of the sensor was shifted. Therefore the concentration of the glucose solution can be estimated by observing the shift in the resonance wavelength. Two schemes were exploited for enhancing the sensitivity of the sensor. First, the effective refractive index of the polymeric waveguide used for the resonator sensor was adjusted to approach that of the target analyte as best as possible. Second, the ring waveguide, which serves as a crucial sensing part, was appropriately over-etched to enlarge its contact area with the analyte. The proposed resonator sensor was designed with the beam propagation method. The refractive indices of the core and cladding polymer involved were 1.430 and 1.375 respectively, leading to the waveguide's effective refractive index of ${\sim}1.390$, which is faiirly close to that of the glucose solution of ${\sim}1.333$. The prepared ring resonator with the $400-{\mu}m$ radius exhibited the free spectral range of 0.66 nm, the bandwidth of 0.15 nm, and the quality factor of 10,000. For the sensor operating at 1,550 nm wavelength, the achieved sensitivity was as great as 0.28 pm/(mg/dL), which is equivalent to 200 nm/RIU.

The Structural Equivalence and Role Equivalence of Container Ports in Asia-Europe Container Shipping Networks (아시아-유럽 컨테이너 해운 네트워크 구성 항만의 구조적 등위성과 역할 등위성)

  • Lee, Sang-Yoon
    • Journal of Korea Port Economic Association
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    • v.32 no.2
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    • pp.105-122
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    • 2016
  • Numerous studies have evaluated the status of seaports. However, the majority of the research has approached this topic from the view-point of port capabilities, including locational advantage, infrastructure, productivity, and competitiveness. The position and/or role of a port can be understood more precisely and comprehensively by considering the interconnectivity among ports making up enormous global transportation networks. The main objective of this study is to compare the status of 82 container ports on the trunk shipping routes between Asia and Europe by applying the concepts of structural equivalence and role equivalence proposed by the social network analysis method. Network similarities and differences among competing ports in the regions are assessed by analysing their structural equivalence. Furthermore, the hierarchical structures of the ports located on the trunks between Asia and Northwest Europe and between Asia and the Mediterranean are constructed by evaluating their role equivalence. The results of this empirical research shows that Singapore and Rotterdam possess the most significant positions on the ocean corridors between Asia and Northwest Europe. Singapore also holds a leading position on the Asia-Mediterranean shipping route. Lastly, no ports located in the Middle East or Mediterranean regions have an equivalent weight to those of Rotterdam, Hamburg, Antwerp on the Asia-Northwest Europe route.