• Journal of the Korean Society of Combustion
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• v.21 no.1
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• pp.1-7
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• 2016

This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1146-1151
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• 2004

Measurements of OH chemiluminescence in an atmospheric pressure, laboratory-scale dump combustor at equivalence ratios ranging from 0.63 to 0.89 were reported. The signal from the first electronically excited state of OH to ground state was detected through a band-pass filter with an ICCD. The objectives of this study are two: One is to see the effects of equivalence ratio on global heat release rate and local Rayleigh index distribution. To get the local Rayleigh index distribution, the line-of-sight images were inverted by tomographic method, such as Abel de-convolution. Another aim is to investigate the validity of using OH chemiluminescence acquired with an ICCD as a qualitative measure of local heat release. For constant inlet velocity and temperature, the overall intensities of OH emission acquired at different equivalence ratio showed periodic and higher value at high equivalence ratio. OH intensity averaged over one period of pressure increased exponentially with equivalence ratio. Local Rayleigh index distribution clearly showed the region of amplifying or damping the combustion instability as equivalence ratio increased. It could provide an information/insights on active control such as secondary fuel injection. Finally, local heat release rate derived from reconstructed OH images were presented for typical locations.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.10
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• pp.1311-1317
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• 2001

To investigate only the effects of the stratified mixture distribution on initial flame propagation and combustion characteristics, the instantaneous equivalence ratio in the spark plug gap and combustion pressure were measured simultaneously In a constant volume chamber, To induce the stratified propane-air mixture distribution near the spark plug, counter-flow typed mixture injection system was used under the constant mean equivalence ratio $\Phi$$\_$mean/= 1.0 The instantaneous equivalence ratio was measured by a single-shot Raman scattering with narrow-band KrF excimer laser. The measuring error was within the limit of $\pm$ 3.5% provided that the proposed method was applied to the measured Raman signals. Judging from mass fraction burned derived from the measured pressure, the optimum combustion characteristics were shown under the condition that the local equivalence ratio in the spark plug was near 1.28$\pm$0.04, and these characteristics were more remarkable at the initial stage of combustion.

• Journal of ILASS-Korea
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• v.27 no.2
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• pp.84-93
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• 2022

To implement carbon-neutrality in transportation sectors until 2050, hydrogen is considered a promising fuel for internal combustion engines because hydrogen does not contain carbon itself. Although hydrogen does not emit CO₂ emission from its combustion process, the low energy density in a volume unit hinders the adoption of hydrogen. Therefore, the understanding of hydrogen jet behavior and measurement of equivalence ratio must be conducted to completely implement the high-pressure hydrogen direct injection. The main objective of this research is feasibility test of hydrogen local equivalence ratio measurement by laser-induced breakdown spectroscopy (LIBs). To visualize the macroscopic structure of hydrogen jet, high-speed schlieren imaging was conducted. Moreover, LIBs has been adopted to validate the feasibility of hydrogen local equivalence ratio measurement. The hydrogen injection pressure was varied from 4 MPa to 8 MPa and injected in a constant volume chamber where the ambient pressure was 0.5 MPa. The increased injection pressure extends the vertical penetration of hydrogen jet. Due to the higher momentum supply when the injection pressure is high, the hydrogen has easily diffused in all directions. As the laser trigger timing has delayed, the low hydrogen atomic emission was detected due to the longer mixture formation time. Based on equivalence ratio measurement results, LIBs could be applied as a methodology for hydrogen local equivalence ratio measurement.

• 유체기계공업학회:학술대회논문집
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• 2006.08a
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• pp.569-572
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• 2006

In present study, the influence of changing combustor pressure on flame stabilization and nitrogen oxide (NOX) emission in the swirl flame with secondary fuel injection was investigated. The combustor pressure was controlled by suction at combustor exit. Pressure index ($P^*=Pabs/Patm$), where Pabs and Patm indicated the absolute pressure and atmosphere pressure, was controlled in the range of 0.7~1.15 for each equivalence ratio conditions. It could be observed that flame stable region became narrower with decreasing equivalence ratio and pressure index. In this combustion system, stable flames were formed until $P^*=\;0.7$. Emission index decreased with decreasing pressure index for overall equivalence ratio conditions and NOx reduction rates were almost identical for $P^*<1$ regardless of equivalence ratio though EINOx values showed different level with change of equivalence ratio for $P^*{\geq}1$. It is also observed that EINOx decreased with increasing secondary fuel injection ratio. Emission index of nitric oxide was controllable by adjusting the changing combustor pressure and injecting secondary fuel and this NOx reduction technology is applicable to industrial furnaces and air conditioning system.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.3 s.258
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• pp.292-299
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• 2007

In gas turbine technology, the flame stability is inherently greater in conventional diffusion type combustion over a wider range fuel to oxidizer ratio. However, premixed type combustion which has narrow flame stability region, is widely used due to environmental reason. It has been observed in experiments that combustion instability of low frequency (${\sim}10Hz$) results from the modulation of equivalence ratio at fuel injection hole when a pressure fluctuation propagates upwards along the channel of the burner under an unchoked fuel flow condition. In this study, a commercial program was used to determine how the fuel flow rate changed with respect to the pressure, velocity of the fuel flow and the mass fraction in a choked and an unchoked condition. The calculation focuses on the upstream of the dump plane to know how the forced pressure with the fuel injection conditions affects the modulation of the equivalence ratio. Therefore, it is found that pressure fluctuation leads to oscillation of mass flow rate and then results in equivalence ratio modulation under the unchoked fuel flow condition.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.187-194
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• 2004

The surface flames in porous ceramic burner are experimentally characterized to investigate the effects of equivalence ratio and firing rates. The results show that the surface flames are classified into green, red radiant and blue surface flame as the decrease of equivalence ratio. And each flame is maintained very stable and represents the same flame characteristics at any orientation of ceramic burner. Particularly the blue surface flame is found to be very stable at very lean equivalence ratio at 7000kcal/hr to 20000kcal/hr firing rates. And the exhausted NOx was analysed to find out which flame has lower NOx emission. The blue surface flame shows the lowest NOx emission regardless of the location of burner since it sustains very stable at lean mixture ratio.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.10
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• pp.1193-1201
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• 2004

The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations fur typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). It was also shown that phase-resolved averaged temperature oscillated in phase with pressure cycle, while normalized standard deviations which represent temporal turbulent intensity of temperature showed nearly constant value around 0.1. The characteristics on the occurrence of high temperature also displayed periodic wave form which was very similar to the pressure signal. And the amplitude of this profile went larger as the fuel/air mixing quality became poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.54-59
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• 2001

OH radical concentration have been measured in a methane-air partially premixed flames using PLIF. Excitation lines were selected $Q_{1}(6)$ branch, (1,0) band. The system is consisted of Nd:YAG laser, dye laser and frequency doubler to make pump beam for OH radical. On the direct photographs, flame height increases as fuel flow rate and equivalence ratio increase. And on the PLIF images, OH radical is distributed from premixed flame front to nonpremixed flame front through the flame structure with all equivalence ratio. OH overall concentrations increase with equivalence ratio. At the stoichiometric equivalence ratio, the peak of OH radical concentration exists strongly near the inner cone. As equivalence ratio is changed to richer, OH radical distribution goes thinly and the peak is increased as longitudinal direction. As the flow goes to the downstream, OH radical concentration decreases and broadens, because OH radical reacts with another species after OH formation at the initial oxidization. This phenomenon resembles radial distribution. At the l00cc fuel flowrate, the radial peak of OH radical exists from x/R=l.0 to 1.5.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.9
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• pp.658-665
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• 2009

Lean premixed combustors are used for significant NOx reduction which one of issues in current gas turbine combustor. This study was investigated to estimate the effects of the unmixedness of fuel-air, equivalence ratio on the instability mechanism, NOx emission and combustion oscillation in a lean premixed combustor. The experiments were conducted in a dump combustor at atmospheric pressure conditions using methane as fuel. The swirler angle was $45^{\circ}$, the degrees of fuel-air mixing were 0, 50 and 100 and inlet temperature was 650K. The equivalence ratio was ranging from 0.5 to 0.8. This paper shows that NOx emission was increased when the degree of fuel-air mixing is increased in same equivalence ratio and when equivalence ratio is increased. And the range of the combustion instability was enlarged as a function of increasing of the degree of fuel-air mixing.