• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1526-1530
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• 2009

Solvent extraction reaction of Zn(II) by Alamine336 from strong HCl solution up to 10 M was identified by analyzing the data reported in the literature. The equilibrium constant of this reaction was estimated by considering the complex formation between zinc and chloride ion. The necessary thermodynamic parameters, such as equilibrium constant for the formation of complexes and the interaction parameters, were evaluated from the thermodynamic data reported in the literature. The following solvent extraction reaction and the equilibrium constant was obtained by considering the activity coefficients of solutes present in the aqueous phase with Bromley equation. $Zn^{2+}\;2Cl^{-}\;+\;R_3NHCl_{org}\;=\;ZnCl_3R_3NH_{org},\;K_{ex}\;=\;6.33\;{\times}\;10^2$ There was a good agreement between measured and calculated distribution coefficients of Zn(II).

• Polymer(Korea)
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• v.29 no.3
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• pp.304-307
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• 2005

The acid-catalyzed hydrolysis reaction of poly(vinyl acetate) (PVAc) in water/acetic acid solution at $35^{circ}C$ was studied at two different solvent compositions. The mole fractions of vinyl acetate (Vac) and vinyl alcohol (VA) during the course of the reaction were determined by NMR, and the equilibrium constant $K_{eq}$ of the reaction was determined using the molar ratio of VAc to VA at the chemical equilibrium. $K_{eq}$ was 0.75 (${\pm}0.01$) when the VAc mole faction at the equilibrium was 0.78 (${\pm}0.01$) and it was 0.69 (${\pm}0.01$) when the VAc mole fraction was 0.57 (${\pm}$0.02). The reaction was found to be a pseudo 1-st order reaction with the rate coefficient at $3.4{\times}10^{-6}/sec$.

• Physical Therapy Korea
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• v.9 no.2
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• pp.1-17
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• 2002

The purpose of this study was to identify the differences of the static and the dynamic balance reactions in the flexion syndrome (FS) and the extension syndrome (ES) group of the patients with chronic lowback pain (LBP) and healthy subjects. Twenty subjects were included in each group. By using EquiTest 5.02, the static balance was measured by the equilibrium score and the strategy score of sensory organization test (SOT), while the dynamic balance was measured by the latency of motor control test (MCT) and the sway energy of adaptation test (ADT). Oswestry Disability Index (OSI) was used to measure level of the disability in patients with chronic LBP. The equilibrium scores, the strategies of SOT, and thelatencies of MCT of three groups were compared with one way ANOVA, while the sway energy of ADT was compared with repeated measures one way ANOVA. The results of this study showed that the equilibrium scores and the strategy scores of SOT were significantly lower in patients with chronic LBP than in healthy subjects. The equilibrium scores and the strategy scores of SOT were significantly differences between the FS and ES groups in condition 5 (support surface was sway-referenced and visual information waseliminated by eye closure), and 6 (support surface was sway-referenced and visual information was altered by sway-referencing). The FS group showed delayed average reaction time at large posterior translation, however, the ES group showed delayed average reaction time at large anterior translation, Even though the sway energy of the patients with chronic LBP were greater than that of healthy subjects during the toe down (plantar flexion rotation), the values between the FS and ES groups didn't show any significant difference. The disability level showed highly correlation with the equilibrium score of the condition 5. As the results, the FS and ES groups divided by the their symptoms and signs in patients with chronic LBP showed different balance reaction. Therefore, more accurate evaluation and balance treatments are needed to focus on their symptoms and signs in patients with chronic LBP.

• Korean Journal of Metals and Materials
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• v.46 no.4
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• pp.227-232
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• 2008

Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.7
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• pp.89-96
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• 2006

The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

• Transactions of the Korean hydrogen and new energy society
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• v.5 no.2
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• pp.65-71
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• 1994

Electrochemical and thermodynamic properties of $MmNi_5$ and the related alloys for nickel-metal hydride battery(Ni-MH) were studied in terms of the equilibrium hydrogen pressure. $MmNi_5$ alloy with high equilibrium hydrogen pressure(10~20atm at room temperature), which is usually difficult to charge, was substituted for Al in part. Partial substitution of Al made not only the equilibrium pressure to be reduced remarkably, but also the enthalpy change depending on the formation of metal hydride to be agreed to the value in gas phase reaction and electrochemical reaction. Besides the composition of Al which can be given the maximum discharge capacity was turned out to be between the 0.5~1.0 atoms of Al.

• Textile Coloration and Finishing
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• v.10 no.3
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• pp.36-42
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• 1998

The dyeabilities of C.I. Reactive Blue 19(B19, MW ; 626), C.I. Reactive Blue 4(B4, MW ; 637) and C.I. Reactive Black 5(B5, MW : 991) were investigated. Initial dyeing rates were increased and the amount of dye on the fabric at equilibrium was decreased with temperature like other ordinary dyeing processes. Activation entropy$(\Delta{S}^*)$ was decreased because of loose bonding between dyestuffes and fiber molecules at transition state. It can be clarified that the entire reaction is exothermic and the number of molecular species at transition state becomes greater from decrease in activation enthalpy$(\Delta{H}^*)$ and the increase in activation free energy$(\Delta{G}^*)$ with temperature, respectively. The amount of B19 on the fabric at equilibrium was greater than that of B4, because B4 became unreactive towards textile substrates through hydrolysis. Due to the biggest size of the dye molecule, the reaction rate of B5 was the slowest but its difunctional group played an important role in achieving the greatest amount of dye on the fabric at equilibrium.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.545-549
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• 2013

For the purpose of development of effective synthetic process of CHMI, a series of experiments were preformed on the preparation of CHMAIE, the intermediate of CHMI. For the first step, CHMA was synthesized by dropwise mixing of cyclohexylamine with maleic anhydride in toluene and 98.2% of theoretical CHMA was obtained by precipitation at $10^{\circ}C$ for 2 hours. The optimum reaction temperature of the esterfication, preparation reaction of CHAMIE from CHMA, was $68^{\circ}C$, and equilibrium conversion at optimum temperature was 98.5%. Equilibrium reaction time decreased with reaction temperature, and 4 hours was taken to reach equilibrium at optimum reaction temperature. Toluene in the final reaction product could be recovered by vacuum distillation. The recovery of toluene was increased with distillation temperature and 98% of toluene could be recovered at $55^{\circ}C$.

• Plant Journal
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• v.13 no.3
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• pp.36-46
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• 2017

In the reaction furnace of modified Claus process, chemical equilibrium reactions and kinetic reactions occur simultaneously. The main kinetic components are hydrogen ($H_2$), carbon monoxide (CO), carbonyl sulphide (COS) and carbon disulphide ($CS_2$). The equilibrium calculations, empirical correlations and sulfur recovery technology providers' (licensors) data for kinetic components (COS and $CS_2$) in the reaction furnace were analyzed to evaluate the amount of kinetic components by applying them to five different projects in which GS Engineering & Construction participated. Kinetic components ($H_2$ and CO) are also calculated and the results are analyzed to evaluate the impact of temperature in the reaction furnace and the waste heat boiler. Total required $O_2$ deviations for combustion in the reaction furnace are additionally shown, with and without side reactions. A full understanding of side reactions in the modified Claus process can help to improve sulfur recovery efficiency and optimize equipment design.

• Journal of the Korean Chemical Society
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• v.8 no.1
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• pp.25-29
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• 1964

Benzhydryl azide 類에 Benzhydrol 類를 混合하여 Schmidt 反應을 逐行할 때에 Benzhydryl 基 間에 完全한 Radical exchange 現象이 일어남을 알았다. 故로 Benzhydrol 類의 Schmidt 反應에 있어서는 一但 生成된 Benzhydryl azide가 濃硫酸存在下에서 Benzhydryl cation과 Hydrazoic acid로 分離되어 完全平衡狀態에 있음을 確認할 수 있었다.