• Title/Summary/Keyword: Equilibrium State

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Development of a Continuous Electrolytic System for pH-control with Only One Discharge of Electrolytic Solution by Using Non-equilibrium Steady State Transfer of Ions across Ion Exchange Membranes (이온 교환막에서 이온의 비 평형 정상상태 이동을 이용한 단일 전해액의 배출만을 가지는 pH 조절용 연속식 전해 반응기 개발)

  • Kim Kwang-Wook;Lyu Je-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.101-109
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unused solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through other counter chamber with its pH being controlled as acid or base. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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Feasibility about the Direct Measurement of 226Ra Using the Gamma-Ray Spectrometry (감마분광분석을 이용한 226Ra의 직접 측정방법에 대한 적용성 평가)

  • Ji, Young-Yong;Chung, Kun Ho;Lim, Jong-Myoung;Kim, Change-Jong;Jang, Mee;Kang, Mun Ja;Park, Sang Tae;Woo, Zuhee;Koo, Boncheol;Seo, Bokyun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.2
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    • pp.97-105
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    • 2014
  • In the case of the direct measurement of $^{226}Ra$ using a HPGe gamma-ray spectrometer, the interference between gammarays with 186.21 keV of $^{226}Ra$ and 185.7 keV of $^{235}U$ should be corrected to calculate the net peak area in the energy spectrum. In general, it is very difficult to conduct peaks stripping with difference of about 0.5 keV, although a HPGe with the superior resolution is applied and the maximum channels is applied to the spectrometer. In this study, several interference correction techniques in the direct measurement were surveyed to evaluate the feasibility for the measurement of $^{226}Ra$ using the gamma-ray spectrometery. Applying the interference corrections to the analysis of raw materials and by-products, the method validation for the direct measurement of $^{226}Ra$ was conducted by evaluating the measurement uncertainty, linearity, and range. As a result, the optimum method of the interference correction was selected by comparing with the indirect measurement of which progenies of $^{226}Ra$, such as $^{214}Pb$ and $^{214}Bi$, were analyzed in the secular equilibrium state.

Hydraulic Characteristics Investigation due to the Change of GapWidth between Artificial Reefs (인공리프 개구폭 변화에 따른 흐름특성 고찰)

  • Kim, Kyu-Han;Shim, Kyu-Tae
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.28 no.6
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    • pp.408-415
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    • 2016
  • Small fishing ports and coastal structures installed in a relatively low sea water depth disturb the wave induced current and cause the collapse of equilibrium state of sediment transport. These structures creates diffracted waves and matter the concentration of waves to cause the beach erosion. In order to mitigate these eroding problems on the beach, many counter measurements were proposed such as detached breakwater, groin or headland; however, these methods interrupt the aesthetic view of sandy beach due to the exposed structures above the sea level and have difficulty of applying to those beaches with the good scenery. Furthermore, some of these methods create secondary environmental problems after the installations. To eliminate these problems, one of the countermeasures, artificial reefs have been selected and used worldwide to minimize the disturbance of the scenery and secondary effects on the environment. Meanwhile, it is important to set the design elements for installing the artificial reefs such as that of length, opening width, clearing distances from the shoreline and more. Nevertheless, there are no construction manuals or standards for designing the artificial reefs with these important design elements yet. In this study, different conditions of artificial reefs were used with various cases throughout hydraulic model test to precisely analyze the changes of waves and currents to propose the standards of design elements to install the artificial reefs.

Algebraic Analysis for Partitioning Root and Stem Lodging in Rice Plant

  • Chang, Jae-Ki;Yeo, Un-Sang;Lee, Jeom-Sig;Oh, Byong-Geun;Kim, Jeong-Il;Yang, Sae-Jun;Ku, Yeon-Chung;Kim, Ho-Yeong;Sohn, Jae-Keun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.6
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    • pp.539-543
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    • 2006
  • Lodging is classified as root lodging caused by the loss of supporting force in the root, bending caused by the deformation of the stem and breaking where the stem breaks down as loads exceeding critical elasticity were applied. This research excluded breaking which is not in a state of equilibrium and tried to partition the level of lodging using an algebraic model in root lodging and stem lodging, or bending. When a vertical load was applied, the deformation of the stem of rice plant showed the form of a quadratic equation. The trace of the panicle neck in the process of lodging was an ellipse-shape. When loading was pure root lodging, the trace of the panicle neck became a circle of which culm length is the radius. When it was a pure stem lodging, the trace of the panicle neck is an ellipse of which major axis is culm length and minor axis is 0.64* culm length. When both stem lodging and root lodging occurred in a natural setting, the partitioning of lodging can be calculated by a formula using eccentricity of an ellipse, S=e*100/0.768(S is the ratio of stem lodging in the whole lodging, e is eccentricity of the ellipse). This method is expected to be useful in simple lodging partitioning. We could also calculate the partitioning of stem lodging and root lodging as units of angles as an accuracy method, by using a straight line calculated by differentiating a quadratic equation of stem deformation at the origin of the coordinates. These two methods for dividing root and stem lodging showed different values. However, each of them showed almost same values with different lodging degree in one plant.

A Study on the Crustal Structure of the Southern Korean Peninsula through Gravity Analysis (중력자료분석을 통한 한반도 지각구조에 관한 연구)

  • Kwon, Byung Doo;Yang, Su Yeong
    • Economic and Environmental Geology
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    • v.18 no.4
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    • pp.309-320
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    • 1985
  • The crustal structure of the southern part of the Korean peninsula has been investigated based on the results of processing and anlaysis of gravity data. The processing techniques involve i) seperation of regional and residual anomalies by polynomial fittings, ii) power spectral analyses to determine the mean depth to the crustal base, iii) a filtering operation called "high-cut filtering and resampling," and iv) downward continuation to determine the undulation of the crustal base. The Bouguer anomalies show a lineation in the NE-SW direction which is the same as that of most mountains and tectonic lines of this area. The mean crustal depth is found to be 34km. The depth of the crustal base is varying in the estimated range of 26km to 36km with a thinner crust below the east coast than that of the west coast. The relief of the crustal base is appeared to be correlated with the regional surface topography. The linear regression relations computed between elevations and gravity anomalies indicate that the crust of this area seems to be not in perfect isostatic equilibrium but a little undercompensated state.

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Adsorption Characteristics of Copper using Biochar Derived from Exhausted Coffee Residue (커피찌꺼기 biochar를 활용한 구리의 흡착특성)

  • Park, Jong-Hwan;Kim, Hong-Chul;Kim, Yeong-Jin;Kim, Seong-Heon;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.36 no.1
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    • pp.22-28
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    • 2017
  • BACKGROUND: There is very limited knowledge of the effects of biochar derived from exhausted coffee residue on metal adsorption processes. Furthermore, only limited information is available on the adsorption mechanism of copper. The aim of this study was to evaluate the absorption behaviors of copper by biochar derived from exhausted coffee residue. METHODS AND RESULTS: Biochars produced by pyrolysis of exhausted coffee residue at $300^{\circ}C$(CB300) and $600^{\circ}C$(CB600) were characterized and investigated as adsorbents for the removal of copper from aqueous solution. The results indicated that the adsorption equilibrium was achieved around 2 h and the pseudo-second-order kinetic model fit the data better than the pseudo-first-order kinetic model. The maximum Cu adsorption capacities of CB600 by Freundlich and Langmuir isotherms were higher than those of CB300. The adsorption data were well described by a Langmuir isotherm compare to Freundlich isotherm. CONCLUSION: Our results suggest that exhausted coffee residue can be used as feedstock materials to produce high quality biochar, which could be used as adsorbents to removal copper.

A Fundamental Study for the Automatic Control System in Greenhouse Using Microcomputer(III) -A variation of temperature and humidity by the window opening ways of the even-Span type house- (마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(III) -양지붕형 하우스의 창 개방방법에 따른 온.습도의 변화-)

  • 김진현;김철수;구건효;이기명
    • Journal of Biosystems Engineering
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    • v.20 no.2
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    • pp.162-172
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    • 1995
  • The ventilation in greenhouse have been important for such as adjustment of temperature, supplying of the oxygen, prevention of the overhumidity, density adjustment of $CO_2$, discharge of harmfulness gas, etc. However, the general ventilation which had been used the quantitative control method in discharge of a property of air mechanism in greenhouse, and caused mainly in waste of the heating energy and growth obstacle of the vegetable. Therefore, this study was peformed to obtain more scientific ventilation method using by analysis and measurement of the isothermal lines according to opening of window ventilation in greenhouse, and the results are summarized as follows. 1. The ventilating amount was more influenced by rather opening amount of window than the ventilating time. 2. In window ventilation, the temperature in greenhouse was mostly changed within 5 minutes after ventilating not regard to the spot of opening, after about 10 minutes temperature became to equilibrium state under the respective ventilating conditions. 3. In opening of the skylight only, isothermal lines were complicated, therefore, a tall vegetable may be possible to damage by a cold-weather from the lower central port in greenhouse. 4. Isothermal lines were a tendency to simply in opening of a side window that may be more effective ventilation in kinds of the short vegetable. 5. In conditions of internal temperature>setting temperature>external temperature, a skylight can be suitable to open 10~20cm in order to the optimum ventilation in greenhouse. 6. In conditions of internal temperature>external temperature>setting temperature, opening of all the windows or both the side windows that can be suitable in order to obtain the optimum ventilation in greenhouse. 7. An effect of ventilation was the most excellent to open of all the windows or both the side windows, and it were also found orderly excellent to open of the side window and the skylight or the skylight only, to open of the side window only. 8. Temperature was varied as the equation of T=Tc+ (To-Tc)e-at, and the ranges of (a) values were limited within 0.34~0.68. 9. A variations of humidity were similar to that of temperature, s.

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Studies on Food Preservation by Controlling Water Activity 1. Measurement of Sorption Isotherm of Dried Filefish Muscle by Equilibration in Dynamic Stream of Conditioned Air (식품보장과 수분활성에 관한 연구 1. 조절기류에 의한 건조말쥐치육의 등온흡습곡선의 측정)

  • HAN Bong-Ho;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.189-193
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    • 1981
  • An apparatus for continuous measurements of sorption isotherm of dried food was manufactured to shorten the time required for equilibration. The apparatus was so designed that the temperature, air velocity and relative humidity in the experimental chamber could be controlled. The use of dynamic stream of conditioned air with a velocity of 0.2m/sec, instead of static atmosphere, allowed a faster equilibration of dried filefish muscle at $25^{\circ}C$. The mean time necessary for the equilibration of dried filefish muscle at the water activity of a given state to a higher water activity was about 45 hours. The monolayer moisture content of dried filefish muscle calculated from BET-equation was 0.092 kg water /kg dry matter at $25^{\circ}C$.

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Effect of Aging Time on the Sonic Conductivity of $PEO_8LiClO_4/Al_2O_3$ Composite Polymer Electrolytes ($PEO_8LiClO_4/Al_2O_3$ 복합 고분자 전해질에서의 이온 전도도의 노화 현상)

  • Choi, Byoung-Koo;Park, Young-Hwan
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.263-268
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    • 2007
  • Most of current works on the PEO-salt electrolytes has been focused on the enhancement of ionic conductivity with an addition of nano-ceramic fillers, but the significant drop of the conductivity with storage time is still in question and has been frequently overlooked. The conductivity drop with aging time has been assumed to come from the incorporation of ceramic particles. However, according to authors, the reported high-temperature values of the conductivity of pure $PEO_8LiCIO_4$ electrolytes are nearly in agreements, but the low temperature values are in great discrepancy reaching up to 10000 times. It indicates that the conductivity at ambient temperature is greatly dependent on the thermal history and sample preparations. In this paper, we showed that the ionic conductivities of both $PEO_8LiCIO_4$ and $PEO_8LiClO_4/Al_2O_3$ polymer electrolytes are strongly dependent on the thermal pretreatment and aging time. The conductivity drop with aging time of both ceramic-free and ceramic composite electrolytes has been measured to be nearly parallel. We showed that the conductivity relaxation with aging time is inherent irrespective of the incorporation of nano-ceramic fillers, since the PEO electrolytes at ambient temperature are in two-phase nature being in non-equilibrium state, never reaching completion.

Experimental Study to Parameterize Salt-Wedge Formations in Coastal Aquifer (해안대수층에서 담수-염수 경계면 형성에 영향을 미치는 조건에 대한 실험적 연구)

  • Park, Hwa-Jun;Kim, Won-Il;Ho, Jung-Seok;Ahn, Won-Sik
    • Journal of Korea Water Resources Association
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    • v.42 no.11
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    • pp.1005-1015
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    • 2009
  • Saltwater intrusion in coastal aquifer was investigated using a laboratory model. Salt-wedge profiles were reproduced in a porous media tank 140 cm long, 70 cm high, and 10 cm wide. The experiments were performed with various conditions of porous media hydraulic conductivity, salinity, and ground surface slope to assess relationships on salt wedge location and inclination. Salt-wedge profiles induced by saltwater intrusion were observed in porous media equilibrium state, and compared with previously derived formulas of the Glover (1959), Henry (1959) and Strack (1976). It was found that salt-wedge shape and formations were affected by the water level ratio ($H_F/H_S$) due to high hydraulic conductivity, saltwater salinity and ground surface slope. High $H_F/H_S$ of porous media having high hydraulic conductivity shifted the saltwater interface toward the saltwater reservoir. Increasing surface slope of the porous media caused the salt-wedge profile inclination to decrease. Saltwater salinity also contributed to the location of saltwater interface, yet the impact was not more significant than hydraulic conductivity.