• Title/Summary/Keyword: Equilibrium State

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Seasonal Variations of Sedimentary Processes on Mesotidal Beach in Imjado, Southwestern Coast of Korea (한반도 서해남부 임자도 해빈 퇴적작용의 계절적 변화)

  • 류상옥;장진호;조주환;문병찬
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.3
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    • pp.83-92
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    • 2004
  • A continuous monitoring of textural characteristics of surface sediments, sedimentation rates and beach profile was carried out to investigate the seasonal variations of sedimentary processes in the Imjado beach, southwestern coast of Korea for two years. The beach profiles consist of steep beach face and relatively flat middle and low tide beaches. The slope of the beach face increases in summer and decreases in winter, in good accordance with the standard beach cycle. Ridge and runnel systems are well developed in the middle and low tide beaches during the summer, but these structures are replaced by mega-ripples during the winter. The sediments are fining southward as well as landward. The mean grain-size tends to be increasingly coarser during seasons of autumn and winter on the north beach and during seasons of winter and spring on the south one. In addition, the sediments are eroded on the north beach and accumulated on the south one as a whole. These are probably due to southward transportation of the sediments as long-shore current (NE-SW) runs around the coastal line of the beach. However, the seasonal variations in accumulation rates are very complex and irregular. It is considered that the Imjado beach represents in non-equilibrium state, as a result of coastal and submarine topographic changes by artificial agents and sea-level uprising associated with global warming.

Effect of Panax Ginseng Saponin on Metabolism and Ion Transport in Human Erythrocytes (인삼이 적혈구세포의 해당과정 및 막 투과도에 미치는 영향)

  • Kang, Bok-Soon;Han, Kyung-Hee
    • The Korean Journal of Physiology
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    • v.17 no.2
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    • pp.125-133
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    • 1983
  • Red cell glycolytic intermediates, metabolites and metabolic ratios were studied. Glycolytic intermediates were measured in neutralized perchloric acid extracts of red cell suspensions after 3 hr incubation at $37^{\circ}C$ in the presence and absence of saponin. Adenosine triphosphate(ATP), adenosine diphosphate(ADP), pyruvate and lactate were measured by enzymatic procedures involving stoichiometric oxidation or reduction of a pyridine nucleotide. Glucose was determined using glucose oxidase after zinc hydroxide extraction. The redox state was calculated from the lactate dehydrogenase equilibrium. Adenosine triphosphatase activity(ATPase) was measured by determining the amount of phosphate released from ATP by washed erythrocyte membranes(ghost) during 20 min. incubation. Both total hydrolysis and the amount of hydrolysis that occured in the presence of ouabain were measured. The second measurement yields Mg-ATPase and represents nonspecific ATPase activity of the membranes. The difference between total and Mg-ATPase activity can be attributed to Na-K-ATPase. For the measurement of sodium fluxes, human erythrocytes were preincubated in $^{22}Na$ for 3 hr at $37^{\circ}C$, washed and suspended in a tracer-free medium. The amount of $^{22}Na$ transported out of cells at any time was determined by analysis of supernatant samples taken at various time after addition of the labeled cells to isotope-free medium. The cells and medium were separated and the radioactivity appearing in the medium was measured. From the total radioactivity in the suspension and the radioactivity appearing in the medium at known time, the rate constant for sodium release was computed. The results are summarized as follows: 1) ATP and ATP/ADP were found to increase at every concentration of saponin tested whereas ADP declined at every cone. of saponin. The increase in pyruvate and lactate were observed at every cone, of saponin and thus $NAD^+/NADH$ computed from pyruvate/lactate also increased. Glucose utilization was stimulated by saponin. 2) $Na^+-K^+-ATPase$ activities showed a biphasic response to saponin, first increasing in lower concentration and then decreasing in higher concentration of saponin. 3) The efflux of sodium was significantly increased by saponin in the range of 5 to 10 mg%. The stimulatory effect of saponin on the rate constants for active(ouabain-sensitive) sodium efflux was inhibited by addition of ouabain.

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A Simulation Analysis on the Economic Impact of U.S. Tangerine Importing in the Korean Citrus Industry (미국 탄저린 수입이 감귤산업에 미치는 경제적 파급효과의 시뮬레이션 분석)

  • Kim, Bae-Sung;Kim, Hwa-Nyeon;Kim, Man-Keun;Ko, Seong-Bo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.7
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    • pp.303-311
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    • 2020
  • The acreage of tangerines in the U.S. sharply rose from 19,000 ha in 2009 to 27,000 ha in 2016, an increase of 42% in 7 years. Considering the recent surge in tangerine exports to Japan, the export volume of 6-7 thousand tons is highly likely to increase in the future. Therefore, the purpose of this study was to analyze the economic impact of U.S. tangerine imports on the Korean citrus industry under various scenarios. In order to examine the possibility of imports of U.S. tangerines, the unit price of U.S. exports to Japan was used since U.S. tangerines are not imported to South Korea. Citrus fruits are divided into field citrus, house citrus, and late-maturing citrus (including winter season citrus) based on the cultivation method and variety used to analyze. Considering both the field and house seasons, the import volume of U.S. tangerines can be expected to rise from roughly 4,700 tons in 2021 to 10,000 tons in 2027. Imports of U.S. tangerines may be pushed up or delayed depending not only on the harvest method and quality of domestic field and house citrus but also on the harvest of U.S. tangerines. However, it is necessary to note that tangerines could be imported after 2021, when the tariff rate on U.S. tangerines will fall below 50%.

Chemical Equilibria of Lanthanides{Ln(Ⅲ)=Pr, Sm, Gd, Dy}-Macrocyclic Complexes with Auxiliary Ligands in $CH_3OH$(PartⅡ):Study of the Coordination of Oxygen-Containing Bases. ($CH_3OH$ 용매에서 란탄족 원소{Ln(Ⅲ)=Pr, Sm, Gd, Dy}-거대고리 착물과 보조 리간드 간의 화학평형 (제2보): 주게원자가 산소인 염기를 중심으로 고찰.)

  • Byun, Jong Chul;Park, Yu Chul;Han, Chung Hun
    • Journal of the Korean Chemical Society
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    • v.43 no.6
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    • pp.628-635
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    • 1999
  • Direct preparative method of 2,6-diformyl-p-cresol and 2-hydroxy-3-hydroxy-5-methylbenzaldehyde from 2,6-bis(hydroxymethyl)-4-methylphenol using activated $Mn(IV)O_2$ was described. Hexadentate compartmental Iigands, $H_4L[A]\;and\; H_4L[B]$ were prepared by condensation reactions of 2-hydroxy-3-hydroxy methyl-5-methylbenzaldehyde with ethylenediamine and 1,3-diaminopropane respectively. By the reaction of macrocycle($H_4[20]DOTA$) with Ln(III) nitrate {Ln(III)=Pr, Sm, Cd, Dy }, discrete mononuclear Ln(III) complexes of the type $[Ln(H_2[20]DOTA)(ClO_4)(H_2O)]\;{\cdot}\;3H_2O$ were synthesized in the solid state. $[Ln([20]DOTA)(NO_3)(H_2O)](NO_3)_2\;{\cdot}\;xH_2O$ was placed in methanol for 2 days, and $[Ln([20]DOTA)(NO_3)(CH_3OH)]^{2+}$ was formed. The equilibrium constants(K) for the substitution of coordinated $CH_3OH$ in the Ln-[20]DOTA complexes by various auxiliary ligand, $L_a$(=salicylic acid, p-chlorobenzoic acid, benzoic acid, acetic acid, 4-bromophenol) were determined spectroscopically at 25$^{\circ}C$ and 0.1M $NaClO_4$. The K values calculated were in the order of salicylic acid > p-chlorobenzoic acid > benzoic acid > acetic acid > 4-bromophenol, while pKa of auxiliary ligands was in the opposite trend.

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Synthesis of pH-Sensitive Hydrogel Nanoparticles in Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 pH 감응성 하이드로젤 입자의 합성)

  • Yang, Juseung;Ryu, Won;Lee, Sangmin;Kim, Kyusik;Choi, Moonjae;Lee, Youngmoo;Kim, Bumsang
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.453-458
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    • 2009
  • Recently, new methods to synthesize and process polymers without toxic organic solvents are needed in order to solve environmental problems. The use of supercritical carbon dioxide as a solvent for the polymer synthesis is attractive since it is non-toxic, non-flammable, naturally abundant, and the product may be easily separated from the solvent. In this study, we developed the method using super critical $CO_2$ to prepare P(MAA-co-EGMA) hydrogel nanoparticles as an intelligent drug delivery carrier. The effects of concentrations of PtBuMA-PEO as a dispersion stabilizer and AIBN as an initiator on the particle synthesis were investigated. When PtBuMA-PEO concentration increased, the particle size decreased. However, there was no significant difference in the particle size according to the AIBN concentration. There was a drastic change of the equilibrium weight swelling ratio of P(MAA-co-EGMA) hydrogel nanoparticles at a pH of around 5, which is the $pK_a$ of PMAA. At a pH below 5, the hydrogels were in a relatively collapsed state but at a pH higher than 5, the hydrogels swelled to a high degree. In release experiments using Rh-B as a model solute, the P(MAA-co-EGMA) hydrogel nanoparticles showed a pH-sensitive release behavior. At low pH(pH 4.0) a small amount of Rh-B was released while at high pH(pH 6.0) a relatively large amount of Rh-B was released from the hydrogels.

Game Theory Based Co-Evolutionary Algorithm (GCEA) (게임 이론에 기반한 공진화 알고리즘)

  • Sim, Kwee-Bo;Kim, Ji-Youn;Lee, Dong-Wook
    • Journal of the Korean Institute of Intelligent Systems
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    • v.14 no.3
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    • pp.253-261
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    • 2004
  • Game theory is mathematical analysis developed to study involved in making decisions. In 1928, Von Neumann proved that every two-person, zero-sum game with finitely many pure strategies for each player is deterministic. As well, in the early 50's, Nash presented another concept as the basis for a generalization of Von Neumann's theorem. Another central achievement of game theory is the introduction of evolutionary game theory, by which agents can play optimal strategies in the absence of rationality. Not the rationality but through the process of Darwinian selection, a population of agents can evolve to an Evolutionary Stable Strategy (ESS) introduced by Maynard Smith. Keeping pace with these game theoretical studies, the first computer simulation of co-evolution was tried out by Hillis in 1991. Moreover, Kauffman proposed NK model to analyze co-evolutionary dynamics between different species. He showed how co-evolutionary phenomenon reaches static states and that these states are Nash equilibrium or ESS introduced in game theory. Since the studies about co-evolutionary phenomenon were started, however many other researchers have developed co-evolutionary algorithms, in this paper we propose Game theory based Co-Evolutionary Algorithm (GCEA) and confirm that this algorithm can be a solution of evolutionary problems by searching the ESS.To evaluate newly designed GCEA approach, we solve several test Multi-objective Optimization Problems (MOPs). From the results of these evaluations, we confirm that evolutionary game can be embodied by co-evolutionary algorithm and analyze optimization performance of GCEA by comparing experimental results using GCEA with the results using other evolutionary optimization algorithms.

The Study on Design of lead monoxide based radiation detector for Checking the Position of a Radioactive Source in an NDT (비파괴검사 분야에서 방사선원의 위치 확인을 위한 산화납 기반 방사선 검출기 설계에 관한 연구)

  • Ahn, Ki-Jung
    • Journal of the Korean Society of Radiology
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    • v.11 no.4
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    • pp.183-188
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    • 2017
  • In recent years, the automatic remote control controller of the gamma ray irradiator malfunctions, and radiation workers are continuously exposed to radiation exposure accidents. In the non-destructive testing field, much time and resources are invested in establishing a radioactive source monitoring system in order to prevent potential incidents of radiation. In this study, the gamma-ray response properties of the lead monoxide-based radiation detector were estimated through monte carlo simulation as a previous study for the development of a radioactive source location monitoring system that can be applied universally to various non-destructive testing equipment. As a result of the study, the optimized thickness of the radiation detector varies according to the gamma-ray energy emitted from the radioactive source, and the optimized thickness gradually increases with increasing energy. In conclusion, the optimized thickness of the lead monoxide-based radiation detector was $200{\mu}m$ for the Ir-192, $150{\mu}m$ for the Se-75 and $300{\mu}m$ for the Co-60. Based on these results, the appropriate thickness of lead monoxide-based radiation detector considering secondary-electron equilibrium was evaluated to be $300{\mu}m$ for general application. These results can be used as a basic data for determining the appropriate thickness required in the radiation detector when developing a radiation source location monitoring system for universal application to various non-destructive testing equipment in the future.

Magnetic Anisotropy Behavior in Antiparallely Coupled NiFe/Ru/NiFe Films (반자성으로 커플링된 NiFe/Ru/NiFe 박막에서의 자기이방성의 변화)

  • Song, Oh-Sung;Jung, Young-Soon;Lee, Ki-Yung
    • Journal of the Korean Magnetics Society
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    • v.13 no.3
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    • pp.97-102
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    • 2003
  • Synthetic ferrimagnetic layer (SyFL) with structure NiFe/Ru/NiFe which can be applied high density TMR device in free layer were prepared by an inductively coupled plasma (ICP) helicon-sputter. We proposed a model of predicting coercivity (H$\_$c/), spin-flopping field (H$\_$sf/), and saturation field (H$\_$s/) as a function of Ru thicknesses, from the equilibrium state of energies of Zeeman, exchange, and uniaxial anisotropy. We fabricated the samples of Ta(50 ${\AA}$)/NiFe(50${\AA}$)nu(4∼20${\AA}$)NiFe(30 ${\AA}$)/Ta(50${\AA}$), and measured the M-H loops with a superconduction quantum interference device (SQUID) applying the external field up to ${\pm}$ 15 kOe. The result was well agreed with the proposed model, and reveal K$\_$u = 1000 erg/㎤, J$\_$ex/ =0.7 erg/$\textrm{cm}^2$. We report that H$\_$c/ below 10 Oe is available, and R$\_$u/ thickness range should be in 4-10 ${\AA}$ for MRAM application. Our result implies that permalloy layers may lead to considerable magnetostriction effect in SyFL and intermixing in NiFe/Ru interfaces.

Study on Graft Polymerization of Acrylate and Methacrylate Monomers onto the Carbon Black Surface (Carbon Black 표면에의 아크릴레이트 및 메타크릴레이트의 그라프트 중합에 관한 연구)

  • Goo, Hyung-Seo;Chang, Byung-Kwon;Kim, Yong-Moo;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.395-405
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    • 1994
  • The various functional groups, such as hydroxyl(-OH), carboxyl(-COOH) and quinonic oxygen(OC<) on the carbon black(abbreviated to CB) surface were activated with n-butyl lithium solution in n-hexane and then acrylate and methacrylate monomers were graft polymerized onto these activated anionic sites and CB-grafted polymers were obtained. To separate homopolymers from reaction mixture, non-solvent precipitation method or centrifugal separating method were applied. Subsequently, conversion, grafting ratio and efficiency were determined at various reaction temperatures and times. In case of acrylates, the grafting ratio showed 20~30% but methacrylates showed 150~200%. Also the anion polymerizations between CB and monomers were nearly reached to equilibrium state within one or two hours under each reaction temperatures but conversion and grafting ratio were increased a little with reaction temperature increase. In colloidal dispersion stability test, before heat-drying, the all CB-grafted polymers showed good dispersed stability in good solvents for acrylic and methacrylic homopolymers. Futhermore, CB-polymethacrylates were found to show excellent collidal properties for good solvents of methacrylic homopolymer even after heat-drying. Identification of the grafted polyacrylates and polymethacrylates onto the CB surface was performed by FT-IR spectroscopy. In addition, electric resistance values of CB-grafted polymers were measured by Four-probe method, and the increase of the grafting ratio showed the increase of the surface resistance.

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Geochemistry and Origin of $CO_2$-rich Groundwater from Sedimentary Rocks of Kyungsang System (경상계 퇴적암에서 산출되는 탄산지하수의 지화학적 특성과 생성기원)

  • 정찬호;이진국
    • The Journal of Engineering Geology
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    • v.10 no.1
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    • pp.51-62
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    • 2000
  • The $CO_2$-richrich water pumps or springs out at two sites (Sinchon and Kohran) consisting of Cretaceous sedimentary rocks in Kyungpook area. The water has been long known as its soda pop-liketaste and therapeutic effect against calcium deficit, stomach and skin troubles, etc. The water arecharacterized by a high $CO_2$ concentration $(P_{CO2}=0.29~l.01 atm)$ and electrical conductance (1,093~2,810$\mu$S/cm). The $CO_2$-rich water belongs to Ca(Na)-$HCO_3$ type in chemical classification. The contents of Ca, Mg, Na, HCO$_3$ and Fe of $CO_2$-rich water show much higher values than those of general groundwater Environmental isotopic data $(^2H/^1H, ^{18}O/^{16}O and ^3H/^1H)$ indicate that the water is ofmeteoric origin recharged after 1950s. The $CO_2$ in the springs seems to be originated from deep-seatedsource related to acidic porphyry and granite nearby sedimentary rocks. Carbonate minerals and albiteare likely to be the major source minerals of the dissoved inorganic constituents in the $CO_2$-rich water.The equilibrium state between major minerals and $CO_2$-rich water was calculated by a thermodynamicprogram.

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