Objectives : The level of 4-hydroxyproline (4-Hyp) in human urine was measured using high performance liquid chromatography (HPLC) with a fluorescence detector. This method is useful for medical examinations and investigating the radicals induced by physical, chemical, mental stresses. This method is superior to many published several methods in terms of its low cost and ability to analyze many samples. Methods : The urine from workers in a tire manufacturing company (22 male pre- and post-shift workers) and 18 office-workers as controls were analyzed. Data concerning age, the cumulative drinking amount and the cumulative smoking amount was collected with a questionnaire. The optimum applied amount of dansyl-Cl, the optimum reaction temperature and time, the recoveries and the optimum pH of the eluent and buffer were determined.4-Hyp from human urine was derivatized with dansyl-Cl (dimethylamino-naphthalene-1-sulfonyl chloride) after removing the a-amino acid by a treatment with phthalic dicarboxaldehyde (OPA) and cleaned with Bond Elut C18 column. The 4-Hyp derivatives were separated on a reversed phase column by gradient elution with a phosphate buffer (5 mmol, pH 8.0) and acetonitrile, and detected by fluorescence measurements at 340 nm (excitation) and 538 nm (emission). Results : The detection limit for the urinary free 4-Hyp was $0.364{\mu}mol/l$. The recovery rate of 4-Hyp was 99.7%, and the effective pH of the phosphate buffer and borate buffer were 3.0 and 8.0, respectively. From statistical analysis, age, drinking and smoking did not affect the urinary free 4-Hyp in both the controls and workers. The range of urinary 4-Hyp in the controls, pre-shift, and post-shift workers were 0.33-16.44, N.D-49.06, and $0.32-56.27{\mu}mol/l$. From the pared-sample t-test, the urinary 4-Hyp levels in post-shift workers ($11.82{\pm}6.73\;nmmol/mg\;Cre$) were 2-fold higher than in pre-shift workers ($5.36{\pm}5.53\;nmol;/mg\;Cre$) and controls ($4.91{\pm}4.89\;nmol;/mg\;Cre$). Conclusions : This method was developed with high sensitivity, accuracy, and precision. The present method was effectively applied to analyze the urinary free 4-Hyp in both controls and workers.
Journal of the Korean Society of Marine Environment & Safety
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v.27
no.5
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pp.618-629
/
2021
The Fukushima nuclear power plant (NPP) accident caused by the East Japan Earthquake in 2011 and the recent increase in the frequency of earthquakes in Korea have caused safety concerns regarding radionuclide exposure. In addition, the Tokyo Electric Power Company (TEPCO) in Japan recently decided to release radionuclide-contaminated water from Fukushima's NPP into the Pacific Ocean, raising public concerns that the possibility of radionuclide contamination through both domestic- and foreign fishery products is increasing. Although many studies have been conducted on the input of artificial radionuclides into the Pacific after the Fukushima NPP accident, studies on the distribution and accumulation of artificial radionuclides in marine products from East Asia are lacking. Therefore, in this study, we attempted to explore recent research on the distribution of artificial radionuclides (e.g., 137Cs, 239+240Pu, 90Sr, and etc.) in marine products from Korean seas after the Fukushima NPP accident. In addition, we also discuss future research directions as it is necessary to prepare for likely radiation accidents in the future around Korea associated with the new nuclear facilities planned by 2030 in China and owing to the discharge of radionuclide-contaminated water from the Fukushima NPP.
Journal of Korean Tunnelling and Underground Space Association
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v.23
no.5
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pp.325-337
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2021
On the road and rail tunnels, the evacuation pathway and facilities such as smoke-control and fire suppression system are essential in tunnel fire. In the long twin tunnels, the cross-connection tunnel is usually designed to evacuate from the tunnel where the fire broke out to the other tunnel. In twin shield tunnels, the segment lining has to be demolished to construct the cross-connection tunnel. Considering the modern shield TBM is mostly the closed chamber type, the exposure of underground soil induced by removal of steel segment lining is the most danger construction step in the shield tunnel construction. This case study introduces the excavation method using the thrust of large steel pipe and reviews the measured data after the construction. The large steel pipe thrust method for the cross-connection tunnel can stabilize the excavated face with the two mechanisms. Firstly, the soil in front of excavated face is cylindrically pre-supported by the large steel pipe. Secondly, the excavated face is supported by the plugging effect caused by the soil pressed into the steel pipe. It was reviewed that the large steel pipe thrust method in the cross-connection tunnel is enough to secure the construct ability and stability in soil from the measurement results about the deformation and stress of steel pipe.
We have carried out granulometry and component analysis on pyroclastic deposits of the Maljandeung Tuff, Ulleung Island, to interpret the eruption types and prime dynamic mechanisms. It is divided into three members in the extracaldera area, each of which comprises the lithofacies of coarse tuffs and lapillistones in the lower part, and pumice deposits in upper one. The lithofacies present quantitative evidences in the granularity and component distribution patterns. As compared to the pumice deposits, the coarse tuffs and lapillistones exhibit a relative increase in both the lithic/juvenile and the crystal/juvenile ratios, and a preferential fragmentation of the juvenile fraction. The abundance of lithics and crystals in the tuffs and lapillistones can be attributed to preferential fragmentation of the aquifer-hosting rocks due to explosive evaporation of ground water, and indirect enrichment in lithics and crystals due to removal of juvenile fines from eruptive cloud. The above data exhibit that early phreatopmagmatic phase was followed by purely magmatic fragmentation phases. The coarse tuffs and lapillistones suggest phreatoplinian eruption derived from explosive interaction of magma with ground water near the conduit, while pumice deposits indicate magmatic eruption by magmatic explosion from juvenile gas pressure. In early stage, phreatoplinian eruption occurred from explosive magma/water interaction in connecting confining water with drawdown of the magma column in the conduit; Later it shifted to plinian eruption by explosive expansion of only magmatic volatiles in intercepting water influx due to higher magmatic gas pressure than confining water pressure with rising of the magma column in the conduit.
The purpose of this study is to study the effect of internatioanl entrepreneurial orientation of small and medium-sized Chinese manufacturing companies on export performance. A total of 183 corporate data were used for empirical analysis for Chinese manufacturing export companies. In summary, first, international entrepreneurial orientation was shown to have a significant positive effect on export performance, second, international etrprenurial orientation was shown to have a significant positive effect on absorption capacity, and third, the stronger environmental dynamics and network capacity, the stronger international business orientation and export ability. The implications of this study are summarized as follows. It suggests that the more innovative, enterprising and risk-taking Chinese SMEs are, the better their export performance and the better their ability to absorb foreign knowledge. It also suggests that small business managers must continue to strengthen their network capabilities to improve export performance through international entrepreneurial orientation, and this relationship is further strengthened in a dynamic environment. It also suggests that the impact of firm's absorption capacity on export performance will weaken over time.
Purpose: The effectiveness of the transport vehicle management system of the Chemical Substances Control Act will be studies and used as basic data for future system improvement plans. Method: After the enforcement of the Chemical Substances Control Act, the effectiveness for the transport vehicle management system was studies by comparing the transport plan, guidance and inspection status, safety training completion management, ect., and the reduction rate of chemical accidents. Results: The average number of chemical accidents in transport vehicles nationwide is 20 each year. And It is decreasing with the stabilization of the Chemical Substances Control Act('15.1.1). The first reason for the decrease in chemical accidents is the increase in submission of transport plans. Second, as the guidance and inspection rate increased every year, the shipper company's management of transport companies was naturally strengthened. Finally, it is judged that chemical accident caused by transport vehicles decrease through safety education. Conclusion: The current tranport vehicle management system of the Chemical Substances Control Act is effective. However, further research is needed to improve the practical and efficient transport vehicle management system.
Corporate ESG performance (environmental, social, and corporate governance) reflecting a company's strategic sustainability has emerged as one of the main factors in today's investment decisions. The traditional ESG performance rating process is largely performed in a qualitative and subjective manner based on the institution-specific criteria, entailing limitations in reliability, predictability, and timeliness when making investment decisions. This study attempted to predict the corporate ESG rating through automated machine learning based on quantitative and disclosed corporate financial information. Using 12 types (21,360 cases) of market-disclosed financial information and 1,780 ESG measures available through the Korea Institute of Corporate Governance and Sustainability during 2019 to 2021, we suggested a deep neural network prediction model. Our model yielded about 86% of accurate classification performance in predicting ESG rating, showing better performance than other comparative models. This study contributed the literature in a way that the model achieved relatively accurate ESG rating predictions through an automated process using quantitative and publicly available corporate financial information. In terms of practical implications, the general investors can benefit from the prediction accuracy and time efficiency of our proposed model with nominal cost. In addition, this study can be expanded by accumulating more Korean and international data and by developing a more robust and complex model in the future.
The Journal of the Convergence on Culture Technology
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v.9
no.6
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pp.715-720
/
2023
This study aims to select ESG items from a consumer perspective and examine the influence of these factors on corporate image and corporate reputation. ESG-related research tends to be conducted from a corporate or investment perspective. However, based on their evaluation of ESG activities, consumers form corporate image and corporate reputation. Accordingly, the E, S, and G evaluation items were applied from the consumer's perspective to analyze the impact of each item. As a result of the study, the impact on corporate image was found to be in the order of transparent management, support for small and medium-sized businesses, and response to climate change. The results of corporate reputation analysis showed transparent management, response to climate change, and support for small businesses. From the consumer's perspective, activities related to a company's response to climate change are considered a corporate obligation, and demands for coexistence and transparent corporate management of small and medium-sized businesses are growing. The significance of this study is that ESG requires environmental management, symbiotic management, and transparent management from a consumer point of view, suggesting that transparent corporate management is the most important factor. In addition, it suggests that communication with consumers of companies requires communication not only in the environmental area, but also in the social and governance areas.
According to the IEA (2022), global rechargeable battery demand is expected to reach 1.3 TWh in 2040. EV batteries will account for about 80% of this demand, and used EV batteries are expected to be discharged after 30 years. Used EV batteries can be recycled and reused to create new value. They can also resolve one of the most vulnerable parts of the battery supply chain: raw material insecurity. In this study, we analyzed the amount of used batteries generated by EV in Korea and their potential for reuse and recycling. As a result, it was estimated that the annual generation of used batteries for EV began to increase to more than 100,000 in '31 and expanded to 810,000 in '45. In addition, it was found that the market for recycling EV batteries in '45 could be expected to be equivalent to the production of 1 million batteries, and the market for reuse could be expected to be equivalent to the production of 36 Gwh of batteries. On the other hand, according to the plan standard disclosed by the recycling company, domestic used EV batteries can account for 11% of the domestic recycling processing capacity (pre-treatment) ('30). So it will be important to manage the import and export of used batteries in terms of securing raw materials.
Journal of the Korea Institute of Building Construction
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v.24
no.2
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pp.239-248
/
2024
The adjustment in guidelines for quality certification of recycled aggregate permitted the Quality Control Manager of a company specializing in recycled aggregate quality certification to concurrently assume the role of Environmental Management Manager. Analysis of the outcomes from the 2023 recycled aggregate quality certification follow-up management audit conducted by the certification agency revealed that in 95 out of 242 cases, constituting approximately 39% of the total cases, individuals held concurrent positions. Following the regulatory revision, there has been a notable proliferation of concurrent roles across various enterprises. Concerns arose regarding the potential neglect of quality control for certified recycled aggregates in comparison to scenarios where individuals are solely responsible for specific duties related to quality and environmental management. Audit results encompassing six aspects, including waste management, were evaluated on a scale of 6 points. A comparative analysis was conducted between the outcomes of 147 cases managed by dedicated personnel, as previously practiced, and 95 cases managed by individuals with concurrent roles. Although the average score of the latter group was marginally lower, no statistically significant disparity was observed between the two groups. Consequently, apprehensions regarding the oversight of quality control stemming from the allowance of concurrent roles appear unfounded. Within the context of recent regulatory revisions, permitting concurrent roles in managerial capacities is deemed an appropriate relaxation of regulations.
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