• Title/Summary/Keyword: Environmental capacity

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Adsorption and Leaching of EPN in the Soil

  • Kim, Jung-Ho;Kam, Sang-Kyu;Park, Moon-Ki;Moon, Yung-Soo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1999.10a
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    • pp.221-223
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    • 1999
  • The adsorption and leaching of organophosphorus pesticide, EPN are investigated in Namwon soil(black volcanic soil), Aewol soil(very dark brown volcanic soil) and Mureung soil(dark brown nonvolcanic soil) sampled in Cheju Island. The organic matter of Namwon soil, Aewol soil and Mureung soil is 19.8%, 6.2%, 2.4%, respectively. The cation exchange capacity of Namwon soil, Aewol soil and Mureung soil is 24.8 meq/100g, 13.0 meq/100g, 9.5 meq/100g, respectively. The Freundlich constant, K value, is 89.4, 26.9 and 9.25 for Namwon soil, Aewol soil and Mureung soil, respectively. The K value of Namwon soil with very high organic matter content and cation exchange capacity was the highest for Aewol soil and Mureung soil. The Freundlich constant, 1/n, show a high correlation with organic matter content, i.e., it is less than unity for organic matter rich soil of Namwon soil and greater than unity for organic matter poor soil of Mureung soil. The leaching of EPN is slower for Namwon soil with high K values, and faster for Mureung soil with low K values. The results of the study is demonstrated the potential of pollution for EPN have little leached into soil environment.

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Seismic performance of reinforced engineered cementitious composite shear walls

  • Li, Mo;Luu, Hieu C.;Wu, Chang;Mo, Y.L.;Hsu, Thomas T.C.
    • Earthquakes and Structures
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    • v.7 no.5
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    • pp.691-704
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    • 2014
  • Reinforced concrete (RC) shear walls are commonly used for building structures to resist seismic loading. While the RC shear walls can have a high load-carrying capacity, they tend to fail in a brittle mode under shear, accompanied by forming large diagonal cracks and bond splitting between concrete and steel reinforcement. Improving seismic performance of shear walls has remained a challenge for researchers all over the world. Engineered Cementitious Composite (ECC), featuring incredible ductility under tension, can be a promising material to replace concrete in shear walls with improved performance. Currently, the application of ECC to large structures is limited due to the lack of the proper constitutive models especially under shear. In this paper, a new Cyclic Softening Membrane Model for reinforced ECC is proposed. The model was built upon the Cyclic Softening Membrane Model for reinforced concrete by (Hsu and Mo 2010). The model was then implemented in the OpenSees program to perform analysis on several cases of shear walls under seismic loading. The seismic response of reinforced ECC compared with RC shear walls under monotonic and cyclic loading, their difference in pinching effect and energy dissipation capacity were studied. The modeling results revealed that reinforced ECC shear walls can have superior seismic performance to traditional RC shear walls.

[ H2S ] Removal Characteristics by Combined System of Bioscrubber and Biofilter (Bioscrubber와 Biofilter 병합 시스템에 의한 H2S 제거특성)

  • Bin, Jung-In;Lee, Byung-Hun;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.16 no.6
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    • pp.763-769
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    • 2007
  • This study compared the performance of a bioscrubber, a biofilter, and a combined system of bioscrubber and biofilter employed being operated at the laboratory-scale. for the removal of hydrogen sulfide. The bioscrubber maintained 100% removal of hydrogen sulfide up to inlet load of $56\;g-S/m^3{\cdot}hr$, while the removal efficiency was decreased with the increase of inlet load. The biofilter showed 100% removal efficiency up to inlet load of $126\;g-S/m^3{\cdot}h$ and the maximum elimination capacity of $126\;g\;S/m^3{\cdot}h$ for the inlet load of $224\;g-S/m^3{\cdot}h$. On the other hand, the combined system of bioscrubber and biofilter showed 100% removal for an inlet hydrogen sulfide load of up to $85\;g-S/m^3{\cdot}h$ and the maximum elimination capacity of $153\;g-S/m^3{\cdot}h$ for inlet loads of $224\;g-S/m^3{\cdot}h$.

Variation of Copper and Zinc-Ion Adsorption Capacity via Zeolitification of Jeju Scoria (제주 스코리아의 제올라이트화에 따른 구리와 아연 이온의 흡착 용량 변화)

  • Chang-Han Lee;Sang-Kyu, Kam;Chul-Goo Hu
    • Journal of Environmental Science International
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    • v.32 no.8
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    • pp.563-572
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    • 2023
  • Scoria from Jeju-island (Jeju scoria) was converted into zeolitic material (Z-SA) via zeolitification using the fusion/hydrothermal method. Jeju scoria could be synthesized into Z-SA to from a surface covered with Na-A zeolite crystals, which was confirmed through an analysis of X-ray diffraction peak patterns and scanning electron microscopy images. Jeju scoria and Z-SA were employed as adsorbents to evaluate the adsorption rate and adsorption capacities for Cu2+ and Zn2+ ions. The adsorption rates and isothermal adsorption capacities could be well fitted by the pseudo-quadratic adsorption kinetics and Langmuir adsorption isotherm, respectively. The maximum adsorption capacities (qm) of Z-SA for Cu2+ and Zn2+ ions were found to be 163.36 mg/g and 120.51 mg/g, respectively, using the Langmuir adsorption isotherm. When Z-SA is synthesized from Jeju scoria via zeolitification using the fusion/hydrothermal method, Z-SA exhibits an adsorption capacity that is more than approximately 100 times the value exhibited by Jeju scoria. As a result, the synthesized Z-SA was regarded as an effective, economic adsorbent.

Evaluation of shear-key misalignment in grouted connections for offshore wind tower under axial loading

  • Seungyeon Lee;Seunghoon Seo;Seungjun Kim;Chulsang Yoo;Goangseup Zi
    • Computers and Concrete
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    • v.33 no.5
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    • pp.509-518
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    • 2024
  • In this study, we investigated the effect of shear-key placement on the performance of grouted connections in offshore wind-turbine structures. Considering the challenges of height control during installation, we designed and analyzed three grouted connection configurations. We compared the crack patterns and strain distribution in the shear keys under axial loading. The results indicate that the misalignment of shear keys significantly influences the ultimate load capacity of grouted connections. Notably, when the shear keys were positioned facing each other, the ultimate load decreased by approximately 15%, accompanied by the propagation of irregular cracks in the upper shear keys. Furthermore, the model with 50% misalignment in the shear-key placement exhibited the highest ultimate strength, indicating a more efficient load resistance than the reference model. This indicates that tensile-load-induced cracking and the formation of compressive struts in opposite directions significantly affect the structural integrity of grouted connections. These results demonstrate the importance of considering buckling effects in the design of grouted connections, particularly given the thin and slender nature of the inner sleeves. This study provides valuable insights into the design and analysis of offshore wind-turbine structures, highlighting the need for refined design formulas that account for shifts in shear-key placement and their structural implications.

Study on Carbon Dioxide Control by Using Dry Sorbent in Fludized Bed (유동층에서 dry sorbent를 이용한 CO2 제어에 관한 연구)

  • Lee, Sang-Sup;Kim, Min-Choul;Yoo, Jeong-Seok;Moon, Gil-Ho;Oh, Kwang-Joong
    • Clean Technology
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    • v.9 no.4
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    • pp.179-187
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    • 2003
  • The technology of fluidized bed to use dry sorbent can be new technology that reduce the operating cost and make efficient operation. Therefore, this study investigated $CO_2$ control by dry sorbents with operating variables in a fluidized bed, compared with fixed bed for $CO_2$ adsorption capacity and pressure drop, and presented the $CO_2$ adsorption capacity of activated carbon, molecular sieve 5A, molecular sieve 13X, and activated alumina. As the results of this study, the basic data could be achieved for operation of fluidized bed process, and fluidized bed process presented relatively high $CO_2$ adsorption capacity and low pressure drop with the increase of gas velocity. In addition, molecular sieve 5A showed 1.1~3.0-fold later breakthrough point and 1.1~2.7-fold higher adsorption capacity than the other dry sorbents.

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Parameters for Evaluating the Sink Capacity of Broad Leaves Trees for the Gas Phase Air Pollutants (가스상 대기오염물질에 대한 활엽수의 정화능력 평가인자)

  • Kim, Jeong-Gyu;Koh, Kang-Suk
    • Korean Journal of Environmental Agriculture
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    • v.15 no.4
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    • pp.472-478
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    • 1996
  • It was conducted to compare the availabilities of parameters for evaluating the sink capacity of the broad leaves trees such as Acer saccharium, Ailanthus altissima, Ginkgo biloba, Platanus occidentalis and Salix pseudolasiogyne. These trees, repoted as resistant species to air pollutants, were exposed to $SO_2$, $NO_2$ and CO within a phytotron at $25^{\circ}C$ with 70% of relative humidity. Since the amount of ad- or absorbed gas does not always agree with the amount of accumlated pollutants in leaves and with the stomatal density, it is assumed that the amount of ad- or absorbed gas is the most basal index to evaluate the sink capacity of trees. The stomatal diffusive resistance, which has a good agreement with the amount of ad- or absorbed gas, is also available for evaluating the sink capacity of broad leaves trees.

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Adsorption Characteristics of Toluene Vapor in Fixed-bed Activated Carbon Column (고정층 활성탄 흡착반응기에서 기상 톨루엔의 흡착특성)

  • Lim Jin-Kwan;Lee Song-Woo;Kam Sang-Kyu;Lee Dong-Whan;Lee Min-Gyu
    • Journal of Environmental Science International
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    • v.14 no.1
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    • pp.61-69
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    • 2005
  • Adsorption characteristics of toluene vapor, which is one of important source of volatile organic compounds (VOCs), by activated carbon were investigated using a fixed bed adsorption column. The operating parameters such as breakthrough curve, adsorption capacity, mass transfer zone (MTZ), and length of unused bed (LUB) were studied. The experimental results showed that the breakthrough time decreased with increasing inlet toluene concentration and gas flow rate. MTZ and LUB increased with the increase of inlet concentration, gas flow rate, and particle size of activated carbon. The adsorption capacity increased with the increase of inlet toluene concentration, while it decreased with increasing particle size. However, it was kept at constant value regardless of the increase of gas flow rate. Adsorption isotherm of toluene vapor could be represented by the Freundlich adsorption equation fairly well. From the adsorption experiments using some VOC gases such as toluene, xylene, butyl acetate. butanol and acetone, it was also found that the adsorption capacity was higher in the case of gas with higher boiling point and lower vapor pressure.

CO2 Absorption in Sodium Solution at High Pressure (고압에서의 나트륨계 흡수용액의 이산화탄소 흡수특성)

  • Oh, Myoung-Seog;Lee, Jin-Woo;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.3
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    • pp.602-606
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    • 2009
  • The absorption capacity and initial absorption rate in 5 %, 10%, 15 % and 20% $Na_{2}CO_{3}$ under the constant temperature at $40^{\circ}C$ and the initial absorption rate in mixture of different alkaline salts such as $KHCO_3$, $CaCO_3$ and $K_{2}CO_{3}$ were measured using batch type stirred cell contractor. 10% $Na_{2}CO_{3}$ showed the highest absorption capacity and $Na_{2}CO_{3}$ and $K_{2}CO_{3}$ showed the somewhat increased absorption capacity and initial absorption rate respectively. Further more, we have studied the effect of adding Pz and Pp to $Na_{2}CO_{3}$. The result showed that absorption rate of $CO_2$ was increased by adding these additives.

Determination of CSOs Treatment Capacity considering the Pollution Load (오염부하량을 고려한 월류수 처리시설 규모 결정)

  • Kim, Joong Hoon;Yoo, Do Geun;Lee, Eui Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3270-3278
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    • 2014
  • Many researches has been conducted as extreme rainfall in hydrology and extreme rainfall analysis is not proper for determination of CSOs treatment capacity. In this study, runoff is calculated by tranformation from rainfall to runoff according to Interevent Time Definition. The capacity of sewage treatment plant is designed by 3 times of DWF(Dry Weather Flow) and the efficiency of present sewage treatment plant is very low becauseat at present. Also, The sewage treatment plant can not control CSOs. In this research, the pollution load is calculated by EMC(Event Mean Concentration) and pollution concetration of total runoff is a standard deciding suitablility of present sewage treatment plant. Finally, CSOs treatment capacity is determinated considering pollution load.