• Title/Summary/Keyword: Environment strength

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Study on the Development and Property of Epoxy Putty with Excellent Low Shrinkage and Cutting Force Using Mercaptan Type and Diamine Type (Mercaptan계와 Diamine계를 이용한 저수축·절삭력이 우수한 Epoxy Putty의 개발 및 물성에 관한 연구)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Adhesion and Interface
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    • v.16 no.4
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    • pp.137-145
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    • 2015
  • This study aimed to develop epoxy putty as a multi-purpose connection and restoration material that can be used for material-specific restoration work such as metal, wood, ceramics, earthenware and stone artifacts by replacing synthetic resins currently being used for preservation treatment of cultural assets. Existing synthetic resins have the issue of cutting force resulting from high strength, deflection resulting from long hardening time, contaminating the surface of artifacts through staining on tools or gloves and need for re-treatment resulting from material discoloration. Accordingly, paste type restoration material most widely being used in the field of cultural assets preservation treatment was selected and examined the property to select it as an object of comparison. Based on such process, epoxy putty was developed according to the kind of agent, hardener and filler. For the purpose of solving the issues of existing material and allowing the epoxy putty developed to have similar property, property experiments were conducted by selecting agents and hardeners with different characteristics and conditions. The study findings showed that both kinds are paste type that improved work convenience and deflection issue as a result of their work time of within 5~10 minutes that are about 3~10 times shorter than that of existing material. In regards to wear rate for increasing cutting force, it improved by about 3 times, thereby allowing easy molding. For the purpose of improving the issue of surface contamination that occurs during work process, talc and micro-ballon were added as filler to reduce the issue of stickiness and staining on hand. Furthermore, a multi-purpose restoration material with low shrinkage, low discoloration and high cutting force was developed with excellent coloring, lightweight and cutting force features.

Synthesis of Renewable Resource-derived Furan-based Epoxy Compounds and Their Adhesive Property (재생자원 유래 퓨란계 에폭시 화합물의 합성 및 접착 특성)

  • Lee, Jae-Soung;Lee, Sang-Hyeup;Jeong, Jaewon;Kim, Baekjin;Cho, Jin Ku;Kim, Hyun Joong
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.41-49
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    • 2010
  • Furan-containing epoxide monomers (8, 9) were designed and synthesized as carbon-neutral, environment-friendly adhesion material. Bicyclic skeleton were constructed using the Diels-Alder reaction of furan and methyl acrylate, both readily accessible starting material from a biomass via bio-refinery process. After reduction of ester functionality, resulting hydroxyl moieties were coupled to epichlorohydrin to provide the epoxy-functionalized furanic monomers (8, 9). The structure of new furanic monomers was confirmed by $^1H$ and $^{13}C$ NMR spectroscopy. As UV-curable monomers, basic properties such as UV curing time and the extent of UV curing were evaluated by photo DSC. Photo-curing shrinkages were measured by linear variable differential transformer transducer (LVDT) and the effect of molecular structure on shrinkage was considered. In addition, new synthetic compounds showed the shear strength over 3 MPa when they were photo-cured between polycarbonate plates, which indicates these compounds are feasible to use as photo-curable adhesive materials.

A Study on High Strength Nitrogen Wastewater Treatment and Sludge Granulation Characteristics in a Pilot-scale Air-lift Sequencing Batch Reactor (파일럿 규모의 공기 유동 연속회분반응기에서 고농도 질소제거 및 슬러지 그래뉼화 특성 연구)

  • Lee, Soochul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.4
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    • pp.398-403
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    • 2012
  • Selective nitrification and granulation have been carried out in a pilot scale air-lift sequencing batch reactor (SBR) for stable and economical nitrogen removal from wastewater. The SBR showed about 100% nitrification efficiency up to 1.0 kg ${NH_4}^+-N/m^3{\cdot}d$, about 90% efficiency at 1.0-2.0 kg ${NH_4}^+-N/m^3{\cdot}d$, and it was less than 90% when the load was higher than 2.0 kg ${NH_4}^+-N/m^3{\cdot}d$. Nitrite accumulation was induced by selective inhibition of nitrite oxidizing bacteria by free ammonia inhibition and dissolved oxygen limitation. For the purpose, high nitrite ratio (> 0.95) was obtained by keeping the pH higher than 8.0 and dissolved oxygen lower than 1.5 mg/L. In addition, sludge granulation was achieved by keeping reactor settling time to 5 minutes to wash out poor settling sludge and to promote the growth of granulation sludge. The operation accelerated sludge granulation and the sludge volume index (SVI) decreased and stably maintained to less than 75 in 60 days.

Electron Beam Radiation Syntheses of Carboxymethylcellulose-based Composite Superabsorbent Hydrogels: Dependence of Gel Properties on Polymer Composition and Additives (전자빔 조사에 의한 카르복시메틸셀룰로스 기반 복합 초흡수제 제조시 폴리머 조성 및 첨가물질의 종류에 따른 겔 특성 변화)

  • Sung, Yoonki;Kim, Tak-Hyun;Lee, Byunghwan
    • Clean Technology
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    • v.22 no.4
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    • pp.258-268
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    • 2016
  • In this work, carboxymethylcellulose-based composite superabsorbent hydrogels were prepared by electron beam radiation. The composition of carboxymethylcellulose (CMC) varied from 4 wt%, 5 wt%, and 6 wt% to 7 wt% based on the amount of distilled water in the syntheses of hydrogels. Graphite oxide, reduced graphene oxide, activated carbon, and bentonite were used as additives for the synthesis of composite superabsorbent. The effect of CMC composition and the type of additives on the gel properties of the prepared hydrogels was investigated. In order to verify the functional groups in the prepared materials, Fourier transform infrared spectroscopy was used. In addition, mechanical strength, gel fraction, swelling kinetics, and equilibrium swelling ratios were measured for the prepared hydrogels. Swelling experiments were carried out in distilled water, urea solution, and physiological saline water. Prepared hydrogels were reused for 5 times, and gel fraction and swelling ratio were measured at every 24 hours. Among the prepared hydrogels, $C_{5%}GO$ and $C_{5%}rGO$ exhibited excellent mechanical property and relatively high swelling ratios for urea solution and physiological saline water with promising applicability as slow-release fertilizers.

A Study on Anisotropy of Magnetic Susceptibility of Clastic Sedimentary Rocks in the Gyeongsang Basin (경상분지 쇄설성 퇴적암의 대자율 이방성 연구)

  • Choi, Eun-Kyeong;Kim, Sung-Wook;Hwang, Woong-Ki;Kwon, Hyun-Wook;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.34 no.8
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    • pp.5-14
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    • 2018
  • The grain size of clastic sedimentary rocks classifies the rock types and also causes of anisotropy of the rock. The anisotropy is one of the most important factors that dominates the strength and weathering behavior of rocks. The anisotropy of clastic sedimentary and igneous rocks in the Gyeongsang Basin including Yeongju, Daegu, and Busan were analyzed by magnetic susceptibility expressed by the degree of anisotropy and shape parameter. As the results of the study, the sandstone deposited under lacustrine environment unaffected by the external force shows 1.03 degree of anisotropy. The degrees of anisotropy of the rocks affected by faults and fault rocks show 1.06 and 1.14, respectively. The magnetic susceptibility of rocks is to decrease with the distance from the fault. A fresh mudstone and shale formed by fines show a similar magnitude of the degree of anisotropy to fault rock and correspond to oblate shape parameter due to their sedimentary structure. Due to these reasons, we need attention in design, construction, and maintenance of a structure constructed in mudstone and shale.

A Study on the Evaluation of Greening Level of Domestic Public Libraries (국내 공공도서관의 녹색화 수준 평가 연구)

  • Noh, Younghee
    • Journal of the Korean BIBLIA Society for library and Information Science
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    • v.28 no.2
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    • pp.5-34
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    • 2017
  • This study measured greening level on the 978 public libraries nationwide, making and distributing questionnaires based on green library evaluation indicators developed to measure the greening level of public libraries. As a result of analyzing the averages by evaluation area, among the green library evaluation areas, the whole average of the library resources was the highest by 1.93, and followed by land use and traffic 1.81, indoor environment 1.30, management of water circulation 1.20, etc. The greening evaluation area which shows the best strength in the surveyed public libraries, was the area of the library resource, and it turned out that it use spaces effectively like effective use of the entire area, effectiveness of conservation of books, use and management of eco-friendly products etc., or use the equipments in eco-friendly way which are purchased or used frequently in the libraries, and, as for the land use and traffic area, most of the libraries had bicycle racks, and chose the location of the libraries, considering accessibility to public transportation and a distance between central urban area and libraries. Also, it turns out that, in the area of materials and resources, most of the libraries were equipped with hand dryers and rolling towels and maintained the eco-friendly view.

Genome-Wide Association Study of Bone Mineral Density in Korean Men

  • Bae, Ye Seul;Im, Sun-Wha;Kang, Mi So;Kim, Jin Hee;Lee, Soon Hang;Cho, Be Long;Park, Jin Ho;Nam, You-Seon;Son, Ho-Young;Yang, San Deok;Sung, Joohon;Oh, Kwang Ho;Yun, Jae Moon;Kim, Jong Il
    • Genomics & Informatics
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    • v.14 no.2
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    • pp.62-68
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    • 2016
  • Osteoporosis is a medical condition of global concern, with increasing incidence in both sexes. Bone mineral density (BMD), a highly heritable trait, has been proven a useful diagnostic factor in predicting fracture. Because medical information is lacking about male osteoporotic genetics, we conducted a genome-wide association study of BMD in Korean men. With 1,176 participants, we analyzed 4,414,664 single nucleotide polymorphisms (SNPs) after genomic imputation, and identified five SNPs and three loci correlated with bone density and strength. Multivariate linear regression models were applied to adjust for age and body mass index interference. Rs17124500 ($p=6.42{\times}10^{-7}$), rs34594869 ($p=6.53{\times}10^{-7}$) and rs17124504 ($p=6.53{\times}10^{-7}$) in 14q31.3 and rs140155614 ($p=8.64{\times}10^{-7}$) in 15q25.1 were significantly associated with lumbar spine BMD (LS-BMD), while rs111822233 ($p=6.35{\times}10^{-7}$) was linked with the femur total BMD (FT-BMD). Additionally, we analyzed the relationship between BMD and five genes previously identified in Korean men. Rs61382873 (p = 0.0009) in LRP5, rs9567003 (p = 0.0033) in TNFSF11 and rs9935828 (p = 0.0248) in FOXL1 were observed for LS-BMD. Furthermore, rs33997547 (p = 0.0057) in ZBTB and rs1664496 (p = 0.0012) in MEF2C were found to influence FT-BMD and rs61769193 (p = 0.0114) in ZBTB to influence femur neck BMD. We identified five SNPs and three genomic regions, associated with BMD. The significance of our results lies in the discovery of new loci, while also affirming a previously significant locus, as potential osteoporotic factors in the Korean male population.

Holocene Climate Optimum and environmental changes in the Paju and the Cheollipo areas of Korea (한반도 홀로세 온난기후 최적기 (Holocene Climate Optimum)와 지표환경 변화)

  • Nahm, Wook-Hyun;Lim, Jae-Soo
    • The Korean Journal of Quaternary Research
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    • v.25 no.1
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    • pp.15-30
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    • 2011
  • Three sediment cores from two different locations (UJ-03 and UJ-12 cores of valley sediment in Paju area, and CL-4 core of wetland sediment in Cheollipo area) along the western Korean Peninsula yield crucial information on the timing and spatial pattern of century-scale climate changes and subsequent surficial responses during the Holocene. In Paju area, the sediments included abundant coarse-grained sediment (coarse sands and pebbles) from 7100 to 5000 cal. yrBP, total organic carbon (TOC) values showed a marked increase from 5000 to 2200 cal. yrBP, several intermittent depositional layers were observed from 2200 cal. yrBP. In Cheollipo area, lake environment developed from 7360 to 5000 cal. yrBP, the deposition of organic materials increased from 5000 to 2600 cal. yrBP, peatland formed from 2600 cal. yrBP. The two patterns of surficial responses to the climate changes through the Holocene are different to each other. This might be due to the dissimilarity in geomorphic conditions. However, the approximate simultaneity of environmental changes in two areas shows that they both can be correlated to the major climate changes. Two areas which have undergone significant changes indicated that the hydrological factors including precipitation and strength of water flow were most responsible for the landscape and geomorphic evolutions. Although the upwards trend in relative sea-level also played a primary role for environmental changes in coastal area (Cheollipo area), detailed studies have still to be undertaken.

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A Study on the Influence of Social Regulation on Competition and Innovation: A Case of Fire-retardant Coating Material for Steel Structure Sector in Korea (사회적 규제가 대체재 간 경쟁과 혁신에 미치는 영향에 관한 연구 : 국내 철강 구조물용 내화 피복재 산업의 사례연구)

  • Chang, Chul Kwon;Ji, Ilyong
    • Journal of Korea Technology Innovation Society
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    • v.20 no.4
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    • pp.939-969
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    • 2017
  • The interest in social regulation and its influence on innovation are increasing as the society concerns more for environment and safety. There have been plenty of literature about the impact of social regulation on innovation and its mechanism. Majority of research have been influenced by or based on the famous Porter's hypothesis. However, majority of the literature focus on internal factors such as expected benefits from change of regulations, and it is hard to find one studying social regulation's influence on innovation through external factors such as market or industrial structure. This study addresses this issue of the impact of social regulation on innovation by analyzing the case of fire-retardant coating material for steel structure industry in Korea. It scrutinizes the impact of social regulation which affects competition and innovation on substitute competing market, and tries to reveal that there might exist the other path to innovation, besides the way that the expected benefit from compliance of regulation directly drives innovation. As a result of the case study, we have found that changes in social regulation may act like economic regulation and restructure the market segment and this effect may lead to innovation. It can be explained by the fact that expected benefits from compliance of regulation can be a direct source of innovation, as Porter suggested, but the change of industry structure and competitive strength caused by the change in social regulation can also act as a driving force of innovation.

Evaluation of Silicon Carbide (SiC) for Deep Borehole Disposal Canister (심부시추공 처분용기 재료로서 SiC 세라믹의 적합성 평가)

  • LEE, Minsoo;LEE, Jongyoul;CHOI, Heuijoo;YOO, MalGoBalGaeBitNaLa;JI, Sunghoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.233-242
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    • 2018
  • To overcome the low mechanical strength and corrosion behavior of a carbon steel canister at high temperature condition of a deep borehole, SiC ceramics were studied as an alternative material for the disposal canister. In this paper, a design concept for a SiC canister, along with an outer stainless steel container, was proposed, and its manufacturing feasibility was tested by fabricating several 1/3 scale canisters. The proposed canister can contain one PWR assembly. The outer container was also prepared for the string formation of SiC canisters. Thermal conductivity was measured for the SiC canister. The canister had a good thermal conductivity of above $70W{\cdot}m^{-1}{\cdot}K^{-1}$ at $100^{\circ}C$. The structural stability was checked under KURT environment, and it was found that the SiC ceramics did not exhibit any change for the 3 year corrosion test at $70^{\circ}C$. Therefore, it was concluded that SiC ceramics could be a good alternative to carbon steel in application to deep borehole disposal canisters.