• Journal of the Korean Ceramic Society
• /
• v.37 no.3
• /
• pp.271-279
• /
• 2000

5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

• Proceedings of the SAREK Conference
• /
• 2007.11a
• /
• pp.618-622
• /
• 2007

In the present study, the cooling and heating operation characteristics of a multi-heat pump have been experimentally investigated for the number of the indoor units(A, B, C) and the operating conditions. The heat pump was controlled by an inverter scroll compressor. The performance of the heat pump was measured by the multi-calorimeter of an air enthalpy method. Cooling and heating capacities and COPs were obtained at the cooling and heating temperature conditions and the setting temperatures of an indoor unit. With increasing the operation frequency of the compressor, the cooling and heating capacities of the heat pump increased linearly. The operation frequency region of the compressor was different as the combination of the indoor unit and the cooling/ heating condition.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.11
• /
• pp.1645-1647
• /
• 2004

Potential energy surfaces for the reaction Al + $O_2{\to}$AlO + O have been calculated with the multireference configuration interaction (MRCI) method using molecular orbitals derived from the complete active space selfconsistent field (CASSCF) calculations. The end-on geometry is the most favourable for the reaction to take place. The small reaction barrier in the present calculation (0.11 eV) is probably an artefact related to the ionicneutral avoided crossing. The charge analysis implies that the title oxidation reaction occurs through a harpooning mechanism. Along the potential energy surface of the reaction, there are two stable intermediates of $AlO_2(C_{{\infty}v}$ and $C_{2v}$) at least 2.74 eV below the energy of reactants. The calculated enthalpy of the reaction (-0.07 eV) is in excellent agreement with the experimental value (-0.155 eV) in part due to the fortuitous cancellation of errors in AlO and $O_2$ calculations.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.28 no.12
• /
• pp.477-482
• /
• 2016

Airtight containers have been widely used in many industries and household. They need a packing for sealing between the inside and outside. Previous packing materials have some drawbacks like stench, stickiness, and difficulty of applying to automated manufacturing systems. So, a new packing material which is harmless and suitable for automation is needed. This study performed a hot plate welding process of thermoplastic elastomer (TPE) as the packing material. The hot plate welding process included a phase change process of solidification and melting. The porosity-enthalpy method was adopted in order to simulate phase change problems. The TPE showed non-Newtonian fluid characteristics during the melting process. Since properties of SEBS are not well-defined, we established TPE properties by observing the melting behavior of TPE. In order to find an optimized condition, a parametric study including packing thickness, shapes, hot plate temperature, and thermal resistance, was conducted.

• Proceedings of the KIEE Conference
• /
• 2002.06a
• /
• pp.88-93
• /
• 2002

$Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}$ and $Zn_{0.5}Cd_{0.5}Al_{2}Se_{4}:Co^{2+}$ + single crystals were grown by CTR method. The grown single crystals have defect chalcopyrite structure with lattice constant a= 5.5966A. c= 10.8042${{\AA}}$ for the pure. a= 5.6543${{\AA}}$. c= 10.8205${{\AA}}$ for the Co-doped single crystal. respectively. The optical energy band gap was given as indirect band gap. The optical energy band gap was decreased according to add of Co-impurity. Temperature dependence of optical energy band gap was fitted well to the Varshni equation. From this relation. we can deduced the entropy. enthalpy and heat capacity. Also. we can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.6
• /
• pp.4253-4259
• /
• 2015

In this study, the effects of various control methods of outdoor air cooling control system on control characteristics and energy consumption in building are researched by simulation. The system analysis modelling is done by using TRNSYS program package, and the control performances with existing outdoor air cooling methods are compared with the control ones without outdoor air cooling. As a result, appropriate operating temperature conditions of outdoor air cooling system according to outdoor temperature changes are required, and the outdoor air/return air dry bulb temperature comparison control method among the control methods shows best responses in energy savings.

• Journal of the Korean institute of surface engineering
• /
• v.26 no.4
• /
• pp.192-202
• /
• 1993

The characteristics of the high-performance ceramic coatings fabricated on the optimum processings con-ditions for the atmospheric plasma spraying are evaluated by various material tests and analyses. The opti-mum processing parameters for the plasma spraying are determined by using the two-level orthogonal arrays of fractional factorial testing method as a statistical approach. Material tests for the coating specimens are carried out to evaluate microstructure, hardness, adhesion strength, and deposition efficiency. The properties of Al2O3-13%TiO2 coating are discussed with regard to the effective processings parameters. The decarburization effects of WC-12%Co coating is examined by XRD analysis in terms of the arc power and the secondary gas species. The hardness of Al2O2-13%TiO2 coating is increased with the arc power and shows the maximum value at around 40 lpm of Ar gas flowrate, which appears to be the most critical parame-ter on the deposition efficiency. For reducing the decarburization of WC-12%Co coating, the injection of inert He gas instead of reactive H2 gas as a secondary gas is more effective than the dropping of arc power to lessen the plasma enthalpy.

• Bulletin of the Korean Chemical Society
• /
• v.4 no.3
• /
• pp.115-119
• /
• 1983

The ionic association constants (K) of 2, N-dimethyl pyridinium iodide (2NDMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $20^{\circ}C{\sim}50^{\circ}C$ under 1 to 2000 bars. The K values increase with increasing pressure and decrease with temperature. The total partial molar volume change (${\Delta}V$) has relatively small negative value and the absolute ${\Delta}V$ value decrease with increasing pressure and temperature. The ion size (a) and solvation number (n) of 2NDMPI were about 5 $\AA$ and changed from 1 to 3 with decreasing temperature. Other thermodynamic parameters such as enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$) for the equilibrium of the 2NDMPI were evaluated. From all the parameters mentioned above, we came to conclusion that the electrostriction effect of 2NDMPI in the ethanol-water mixture is enhanced with increasing pressure and decreasing temperature.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2012.05a
• /
• pp.397-402
• /
• 2012

The objective of this study is the estimation of the two unknown thermal conductivity and thermal diffusivity by an inverse heat conduction analysis using the Levenberg-Marguardt method. One dimensional formulation of heat conduction problem in the model was applied. Two point transient temperature of test pieces and heat flux of inflow were measured under the high enthalpy flow environment. Estimated thermal conductivity and thermal diffusivity by an inverse analysis were compared with the known values of graphite test piece. It showed the effectiveness of proposed experimental inverse analysis.

• International Journal of Air-Conditioning and Refrigeration
• /
• v.17 no.4
• /
• pp.129-134
• /
• 2009

The objectives of this paper are to study the effects of thermal and geometric conditions on the performance of indoor heat exchangers with R-410A for Gas Engine Driven Heat Pump (GHP) application and to find the optimum design conditions of indoor heat exchangers by parametric analysis for the key parameters. The key parameters are number of tube row, number of tube pipe, fin pitch and transverse tube pitch. In the air side, moisture out of the humid air condenses on the fin surface while the refrigerant (R-410A) boils inside the smooth tube. Therefore this study uses Log Mean Enthalpy Difference (LMHD) method to analyze the heat transfer from the humid air to the refrigerant. This study determines the heat exchanger size, air side/refrigerant side pressure drop and overall heat transfer coefficient. Optimum design conditions for the key parameters are also determined by the parametric analysis. The results show that number of rows and pipes, fin pitch have significant effect on the heat exchanger size. It is also found that the tube length of the louver fin is $17{\sim}30%$ shorter than that of the plate fin.