• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.5
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• pp.167-173
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• 2023

Li₃V₂(PO₄)₃ and Li₃V₂(PO₄)₃/C composite with single phase monoclinic structure for the cathode materials are successfully synthesized by direct co-precipitation method using N₂H₄·H₂O as the reducing agent and alginic acid as the carbon source, and their electrochemical properties were compared. The particles with approximately 1~2 ㎛ size and the uniform spherical-like morphology of the narrow particle size distribution were obtained. In addition, the residual carbon can also improve the electrical conductivity. The Li₃V₂(PO₄)₃/C composite has improved initial specific discharge capacity and excellent cycle characteristics to maintain capacity stably than Li₃V₂(PO₄)₃. The results indicate that the reducing agent and carbon composite can affect the good crystallinity and electrochemical performance of the cathode materials.

• Journal of Korean Society of Forest Science
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• v.112 no.4
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• pp.554-560
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• 2023

To prevent illegal timber distribution, DNA markers have been used to identify the species and origin. However, extracting high-quality DNA from timber is difficult because of its physical and chemical properties. In this study, we investigated whether the age of timber tissue influences the yield of DNA extraction and the success rate of polymerase chain reaction (PCR) to understand the relationship between the establishment time of the wood annual ring and the extracted DNA concentration (ng/μl), purity (A260/A280), and PCR success rate (%) from pinewood, a major Korean domestic species. According to the results, it was observed that as the distance from the cambium increased, indicating that the tissue was older, the concentration and purity of the extracted DNA decreased significantly. For the trnM-trnV (285 bp) and rpoC1 (298 bp) regions, the PCR success rate was 100%. However, for the rbcL (1.3 kb) region, the PCR success rate was 66.67%. Moreover, PCR amplification of the rbcL region failed at all points older than 30 years. Thus, it is deduced that as time passes, along with the decay of timber cells, DNA is degraded, leading to a decrease in DNA concentration, purity, and PCR success rate. The results of this study are expected to be beneficial for future applications, such as the species identification of timber, providing valuable insights and potential utilization in this field.

• Explosives and Blasting
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• v.41 no.3
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• pp.38-61
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• 2023

An Excavation Damaged Zone(EDZ) caused by blasting impact changes rock properties, in situ stress distribution, etc., and its effects are noticeable at around a radioactive waste repository located at deep underground. In particular, the increase in permeability due to the formation of cracks may significantly increase the amount of groundwater inflow and the possibility of radioactive nuclide outflow. In this study, FLAC2D and FLAC3D were used to analyze the mechanical and thermal behaviors for three categories: a)No EDZ, b)Uniform EDZ, and c)Random EDZ. It was found that the tunnel displacement in the Random EDZ case was 423% higher than that in the No EDZ case and was 16% higher than that in the Uniform EDZ case. Tunnel inflow in the Random EDZ was also 17.3% and 10.8% higher than that in the No EDZ and the Uniform EDZ case, respectively. The permeability around the tunnel was increased by up to 10 times in the corner of the tunnel wall and roof due to the stress redistribution after excavation. From the computer simulation, it was found that the permeability around the tunnel wall was partially increased but the overall tunnel inflow was decreased with increase of stress ratio. Mechanical analysis using FLAC 3D showed similar results. Slight difference between 2D and 3D could be explained with the development of plastic zone during the advance of tunnel excavation in 3D.

• Journal of Industrial Convergence
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• v.21 no.9
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• pp.33-39
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• 2023

Nano-sized materials can be coated on various substrates, and since this material is transparent and conductive, it can be used as a transparent electrode for electronic devices or an electrode for power supply. In this study, CNT and Ag nanowires were repeatedly coated using the silk screen technique, and samples formed up to 5 times were fabricated, and their optical and electrical properties were measured and analyzed. It was confirmed that marks were formed on the surface of the silkscreen-coated sample according to the coating direction, and the trend of transmittance and surface resistance according to the number of times of coating was investigated. As the number of coatings increased, transmittance and surface resistance tended to decrease. In particular, in the case of transmittance, the range of change was large in the samples coated 2 and 5 times. These changes were confirmed by the Ag nanowire coating. In addition, starting from 700 nm, the previous wavelength region increased according to the wavelength, while the above showed a tendency to decrease. The surface resistance was lowered from 9Ω/cm² when coating once to 0.856Ω/cm² when coating five times. It was found that the resistance value was affected by Ag similarly to the permeability. In the future, it is necessary to realize a desired transparent electrode through Ag concentration and coating of Ag nanowires with other methods and fusion with highly transparent CNT to apply to electronic devices.

• Phonetics and Speech Sciences
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• v.15 no.4
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• pp.91-100
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• 2023

Reverberation time (T60) is a typical acoustic parameter that provides information about reverberation. Since the impacts of reverberation vary depending on the frequency bands even in the same space, frequency-dependent (FD) T60, which offers detailed insights into the acoustic environments, can be useful. However, most conventional blind T60 estimation methods, which estimate the T60 from speech signals, focus on fullband T60 estimation, and a few blind FDT60 estimation methods commonly show poor performance in the low-frequency bands. This paper introduces a modified approach based on Attentive pooling based Weighted Sum of Spectral Decay Rates (AWSSDR), previously proposed for blind T60 estimation, by extending its target from fullband T60 to FDT60. The experimental results show that the proposed method outperforms conventional blind FDT60 estimation methods on the acoustic characterization of environments (ACE) challenge evaluation dataset. Notably, it consistently exhibits excellent estimation performance in all frequency bands. This demonstrates that the mechanism of the AWSSDR method is valuable for blind FDT60 estimation because it reflects the FD variations in the impact of reverberation, aggregating information about FDT60 from the speech signal by processing the spectral decay rates associated with the physical properties of reverberation in each frequency band.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.2
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• pp.27-34
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• 2024

This study was conducted to examine the feasibility of using Fe-activated wood-derived biochar as a conductive filler for manufacturing cement-based strain sensor. To evaluate the compressive and electrical properties of cement composite with 3% Fe-activated biochar, three cubic specimens of size 50 x 50 x 50mm³ and three prismatic cement-based sensors of size 40 x 40 x 80mm³ were prepared respectively. The four-probe method of electrical resistance measurement was used for cement-based sensors. For cement-based sensors with FE-activated biochar, the conductive performance such as electrical resistance and impedance under different water content and repeated compression was investigated. Results showed that the fractional changes in the DC electrical resistivity of cement-based sensors increase with increasing time and the maximum fractional changes in the resistivity decrease with increasing the moisture contents during 900s. At moisture content of 7.5% range, the conductive performance of cement composite including 3% Fe-activated biochar as a conductive filler showed the most stable, while the strain detection ability tended to decrease somewhat as the repeated compressive stress increased between repeated compressive strain and fractional change in resistivity (FCR).

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.83-90
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• 2024

This study investigates the 3D printing characteristics of strain hardening cement composites (SHCC) reinforced by PVA fibers. Three SHCC mixtures with diverse fiber volume fractions (1.0% for F1.0 mixture, 1.5% for F1.5 mixture, and 1.8% for F1.8 mixture) were designed. Except for the F1.0 mixture, all mixtures met the necessary conditions for multiple micro-cracking, with higher fiber volume fractions more readily satisfying these conditions. The flow values of three SHCC mixtures were within the 3D printable range of 120~160 mm, exhibiting decreased flow values with increasing the fiber volume fractions. Observation of the printed SHCC surfaces indicated that the F1.0 mixture had a Level-3 (good) rating, while F1.5 and F1.8 were rated as Level-2 (average). Higher fiber volume fractions resulted in poorer surface quality, thus, further research needs to be performed for modulating SHCC mixture suitable for 3D printing. The uniaxial tension behavior showed that the F1.0 mixture failed at lower strain, whereas F1.5 and F1.8 exhibited higher strain performance with multiple micro-cracks occurring.

• Journal of the Korean Geotechnical Society
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• v.40 no.1
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• pp.47-54
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• 2024

In current slope stability analysis techniques, slope stability is evaluated based on the saturated-soil theory. However, soil-water characteristics change frequently depending on the climate. Therefore, because the saturated soil theory has limitations, the application of the unsaturated soil theory is necessary for slope stability. It is also important to evaluate the engineering properties of unsaturated soil because the capillary absorption capacity is reduced due to heavy rain, thereby causing a reduction in slope stability. In this study, soil-water characteristic tests were performed using four samples with different fine contents (0%, 10%, 20%, and 30%) using granite-weathered soil in domestic production areas. In particular, to consider the previously conducted drying process as well as the evaluation of stability due to heavy rain on the actual slope, a wetting process was conducted, in which the water content was increased. In addition, the van Genuchten (1980) model, which is the most consistent theoretical equation for the experiment, was used with various theoretical equations, and the parameters were analyzed according to the fine content of the granite-weathered soil for the drying and wetting processes.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.70-79
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• 2024

Raman analyzer is an analytical technique that utilizes the "Raman effect", which occurs when light is scattered by the inherent vibrations of molecules. It is used for molecular identification and composition analysis. In the natural gas industry, it is widely used in bunkering and tank lorry fields in addition to LNG export and import terminals. In this study, a LNG-specific Raman analyzer was installed and operated under actual field conditions to analyze the composition and principal properties (calorific value, reference density, etc.) of LNG. The measured LNG composition and calorific value were compared with those obtained by conventional gas chromatograph that are currently in operation and validated. The test results showed that the Raman analyzer provided rapid and stable measurements of LNG composition and calorific value. When comparing the calorific value, which serves as the basis for LNG transactions, with the results from conventional gas chromatograph, the Raman analyzer met the acceptable error criteria. Furthermore, the measurement results obtained in this study satisfied the accuracy criteria of relevant international standards (ASTM D7940-14) and demonstrated similar outcomes compared to large-scale international demonstration cases.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.80-86
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• 2024

This study was conducted to evaluate the potential of rape stalk (RAS) as a raw material for the production of solid bio-fuels. RAS was immersed in an aqueous solution with acetic acid concentration of 1 percent, The content of reducing sugars separated from the RAS was analyzed. Glucose showed the highest content followed by xylose, galactose, arabinose and mannose. The immersed and non-immersed RAS were used for producing pellets with a pilot-scaled flat-die pellet mill. Bulk density and calorific values of the pellets improved with the use of the immersed RAS and the addition of wood particles. The values exceeded the minimum requirements for the A-grade of non-woody pellets (≧600 kg/m³ & ≧ 14.5 MJ/kg) designated by the ISO. Ash content of the pellets reduced with the immersion of RAS and the value satisfied the A-grade level (≦6.0%) of the ISO standard. The durability of the immersed RAS-based pellets was much higher than that of non-immersed IRS-based pellets, and the values were increased with the addition of wood particles. However, the durability did not meet the acceptance level for the B-grade of non-woody pellets (≧96.0%) designated by the ISO. These results suggested that the addition of binders in the production of non-woody pellets using an RAS immersed in acetic acid-based aqueous solution is required for the commercialization of the pellets.