• 제목/요약/키워드: Engineering critical current density

검색결과 187건 처리시간 0.028초

Improved Performance of Lithium-Ion Batteries using a Multilayer Cathode of LiFePO4 and LiNi0.8Co0.1Mn0.1O2

  • Hyunchul Kang;Youngjin Kim;Taeho Yoon;Junyoung Mun
    • Journal of Electrochemical Science and Technology
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    • 제14권4호
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    • pp.320-325
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    • 2023
  • In Li-ion batteries, a thick electrode is advantageous for lowering the inactive current collector portion and obtaining a high energy density. One of the critical failure mechanisms of thick electrodes is inhomogeneous lithiation and delithiation owing to the axial location of the electrode. In this study, it was confirmed that the top layer of the composite electrode contributes more to the charging step owing to the high ionic transport from the electrolyte. A high-loading multilayered electrode containing LiFePO4 (LFP) and LiNi0.8Co0.1Mn0.1O2 (NCM811) was developed to overcome the inhomogeneous electrochemical reactions in the electrode. The electrode laminated with LFP on the top and NCM811 on the bottom showed superior cyclability compared to the electrode having the reverse stacking order or thoroughly mixed. This improvement is attributed to the structural and interfacial stability of LFP on top of the thick electrode in an electrochemically harsh environment.

경두개직류자극 전기장의 분포 특성에 비등방성 전기 전도율이 미치는 영향 분석 :3차원 고해상도 유한요소 두뇌 모델을 통한 연구 (Changes in Distribution of Electrical Field in tDCS with Ring Electrode Due to Tissue Anisotropy: a 3D High Resolution Finite Element Head Model Study)

  • 김상혁;서현상;조영선;이원희;김태성
    • 대한의용생체공학회:의공학회지
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    • 제32권4호
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    • pp.305-311
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    • 2011
  • For effective stimulation with tDCS, spatial focality of induced electrical field(EF) and current density(CD) is one of the important factors to be considered. Recently, there have been some studies to improve the spatial focality via different types of electrodes and their new configurations: some improvements using ring electrodes were reported over the conventional pad electrodes. However, most of these studies assumed isotropic conductivities in the head. In this work, we have investigated the effect of tissue anisotropy on the spatial focality of tDCS with the 4 + 1 ring electrode configuration via a 3-D high-resolution finite element(FE) head model with anisotropic conductivities in the skull and white matter. By examining the profiles of the induced EF from the head models with isotropic and anisotropic conductivities respectively, we found that the spatial focality of the induced EF significantly drops and get diffused due to tissue anisotropy. Our analysis suggests that it is critical to incorporate tissue anisotropy in the effective stimulation of the brain via tDCS.

A comparative study on the flux pinning properties of Zr-doped YBCO film with those of Sn-doped one prepared by metal-organic deposition

  • Choi, S.M.;Shin, G.M.;Joo, Y.S.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권4호
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    • pp.15-20
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    • 2013
  • We investigated the flux pinning properties of both 10 mol% Zr-and Sn-doped $YBa_2Cu_3O_{7-{\delta}}$ (YBCO) films with the same thickness of ~350 nm for a comparative purpose. The films were prepared on the $SrTiO_3$ (STO) single crystal substrate by the metal-organic deposition (MOD) process. Compared with Sn-doped YBCO film, Zr-doped one exhibited a significant enhancement in the critical current density ($J_c$) and pinning force density ($F_p$). The anisotropic $J_{c,min}/J_{c,max}$ ratio in the field-angle dependence of $J_c$ at 77 K for 1 T was also improved from 0.23 for Sn-doped YBCO to 0.39 for Zr-doped YBCO. Thus, the highest magnetic $J_c$ values of 9.0 and $2.9MA/cm^2$ with the maximum $F_p$ ($F_{p,max}$) values of 19 and $5GN/m^3$ at 65 and 77 K for H // c, respectively, could be achieved from Zr-doped YBCO film. The stronger pinning effect in Zr-doped YBCO film is attributable to smaller $BaZrO_3$ (BZO) nanoparticles (the average size ${\approx}28.4$ nm) than $YBa_2SnO_{5.5}$ (YBSO) nanoparticles (the average size ${\approx}45.0$ nm) incorporated in Sn-doped YBCO film since smaller nanoparticles can generate more defects acting as effective flux pinning sites due to larger incoherent interfacial area for the same doping concentration.

Ag thickness effect on electrical and optical properties of flexible IZTO/Ag/IZTO multilayer anode grown on PET

  • 남호준;조성우;김한기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.379-379
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    • 2007
  • The characteristics of indium-zinc-tin-oxide (IZTO)-Ag-IZTO multilayer grown on a PET substrate were investigated for flexible organic light-emitting diodes. The IZTO-Ag-IZTO (IAI) multilayer anode exhibited a remarkably reduced sheet resistance of 4 ohm/sq and a high transmittance of 84%, despite the very thin thickness of the IZTO (30 nm) layer. In addition, it was shown that electrical and optical properties of IAI anodes are critically dependent on the thickness of the Ag layer, due to the transition of Ag atoms from distinct islands to continuous films at a critical thickness (14 nm). Moreover, the IAI/PET sample showed more stable mechanical properties than an amorphous ITO/PET sample during the bending test due to the existence of a ductile Ag layer. The current density voltage-luminance characteristics of flexible OLEDs fabricated on an IAI/PET substrate was better than those of flexible OLEDs fabricated on an ITO/PET substrate. This indicates that IAI multilayer anodes are promising flexible and transparent electrodes for flexible OLEDs.

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Magnetic circuit optimization in designing Magnetorheological damper

  • Yazid, Izyan I.M.;Mazlan, Saiful A.;Kikuchi, Takehito;Zamzuri, Hairi;Imaduddin, Fitrian
    • Smart Structures and Systems
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    • 제14권5호
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    • pp.869-881
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    • 2014
  • This paper presents the materials analysis for combination of working modes of Magnetorheological (MR) damper. The materials were selected based on the optimum magnetic field strength at the effective areas in order to obtain a better design of MR damper. The design of electromagnetic circuit is one of the critical criteria in designing MR dampers besides the working mechanism and the types of MR damper. The increase in the magnetic field strength is an indication of the improvement in the damping performance of the MR damper. Eventually, the experimental test was performed under quasi-static loading to observe the performances of MR damper in shear mode, squeeze mode and mixed mode. The results showed that the increment of forces was obtained with the increased current due to higher magnetic flux density generated by electromagnetic coils. In general, it can be summarized that the combination of modes generates higher forces than single mode for the same experimental parameters throughout the study.

전기화학적 전착에 의한 태양전지용 저가 유연 금속 메쉬 제작 (Preparation of Low-cost and Flexible Metal Mesh Electrode Used in the Hybrid Solar Cell by Simple Electrochemical Depositon)

  • 이주열;이상열;이주영;김만
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.123.1-123.1
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    • 2017
  • Hybrid solar cells have intensively studied in recent years due to their advantages such as cost effectiveness and possibility of applications in flexible and transparent devices. It is critical to fabricate individual layer composed of organic and inorganic materials in the hybrid solar cell at low cost. Therefore, it is required to manufacture cheaply and enhance the photon-to-electricity conversion efficiency of each layer in the flexible solar cell industry. In this research, we fabricated pure Cu metal mesh electrode prepared by using electroplating and/or electroless plating on the Ni mold which was manufacture through photolithography, electroforming, and polishing process. Copper mesh was formed on the surface of nickel metal working master when pulsed electrolytic copper deposition were performed at various plating parameters such as plating time, current density, and so on. After electrodeposition at 2ASD for 5~30seconds, the line/pitch/thickness of copper mesh sheet was $1.8{\sim}2.0/298/0.5{\mu}m$.

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PTC Behavior of Polymer Composites Containing Ionomers upon Electron Beam Irradiation

  • Kim, Jong-Hawk;Cho, Hyun-Nam;Kim, Seong-Hun;Kim, Jun-Young
    • Macromolecular Research
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    • 제12권1호
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    • pp.53-62
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    • 2004
  • We have prepared polymer composites of low-density polyethylene (LDPE) and ionomers (Surlyn 8940) containing polar segments and metal ions by melt blending with carbon black (CB) as a conductive filler. The resistivity and positive temperature coefficient (PTC) of the ionomer/LDPE/CB composites were investigated with respect to the CB content. The ionomer content has an effect on the resistivity and percolation threshold of the polymer composites; the percolation curve exhibits a plateau at low CB content. The PTC intensity of the crosslinked ionomer/LDPE/CB composite decreased slightly at low ionomer content, and increased significantly above a critical concentration of the ionomer. Irradiation-induced crosslinking could increase the PTC intensity and decrease the NTC effect of the polymer composites. The minimum switching current (Ι$\sub$trip/) of the polymer composites decreased with temperature; the ratio of Ι$\sub$trip/ for the ionomer/LDPE/CB composite decreased to a greater extent than that of the LDPE/CB composite. The average temperature coefficient of resistance (${\alpha}$$\sub$T/) for the polymer composites increased in the low-temperature region.

Numerical Simulation of Shock Wave Reflecting Patterns for Different Flow Conditions

  • Choi, Sung-Yoon;Oh, Se-Jong
    • International Journal of Aeronautical and Space Sciences
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    • 제3권1호
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    • pp.74-85
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    • 2002
  • The numerical experiment has been conducted to investigate the unsteady shock wave reflecting phenomena. The cell-vertex finite-volume, Roe's upwind flux difference splitting method with unstructured grid is implemented to solve unsteady Euler equations. The $4^{th}$-order Runge-Kutta method is applied for time integration. A linear reconstruction of the flux vector using the least-square method is applied to obtain the $2^{nd}$-order accuracy for the spatial derivatives. For a better resolution of the shock wave and slipline, the dynamic grid adaptation technique is adopted. The new concept of grid adaptation technique, which is much simpler than that of conventional techniques, is introduced for the current study. Three error indicators (divergence and curl of velocity, and gradient of density) are used for the grid adaptation procedure. Considering the quality of the solution and the numerical efficiency, the grid adaptation procedure was updated up to $2^{nd}$ level at every 20 time steps. For the convenience of comparison with other experimental and analytical results, the case of interaction between the straight incoming shock wave and a sharp wedge is simulated for various flow conditions. The numerical results show good agreement with other experimental and analytical results, in the shock wave reflecting structure, slipline, and the trajectory of the triple points. Some critical cases show disagreement with the analytical results, but these cases also have been proven to show hysteresis phenomena.

MOD-processed YBCO coated conductors on the $CeO_2$-buffered IBAD-MgO template

  • Shin, G.M.;Ko, R.K.;Oh, S.S.;Moon, S.H.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제11권4호
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    • pp.20-24
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    • 2009
  • YBCO coated conductors (CC) on the $CeO_2$-buffered IBAD-MgO template were fabricated by metal-organic deposition (MOD) Process with Ba-trifluoroacetate and fluorine-free Y and Cu precursor materials. The precursor solution was coated on $CeO_2$-buffered IBAD MgO templates using the multiple dip-coating method, decomposed into inorganic precursors by pyrolysis up to $400^{\circ}C$ within 3 h, and finally fired at $740{\sim}800^{\circ}C$ in a reduced oxygen atmosphere. Microstructure, texture, and superconducting properties of YBCO films were found highly sensitive to both the firing temperature and time. The high critical current density ($J_C$) of $1.15\;MA/cm^2$ at 77.3K in the self-field could be obtained from $1\;{\mu}m$ thick YBCO CC, fired at $740^{\circ}C$ for 3.5 h, implying that high performance YBCO CC is producible on IBAD MgO template. Further enhancement of $J_C$ values is expected by improving the in-plane texture of $CeO_2$-buffer layer and avoiding the metal substrate contamination.

MgB4와 Mg 분말을 원료로 사용하여 고상반응법으로 제조한 MgB2 초전도체의 상생성과 초전도 특성 (Superconducting Properties and Phase Formation of MgB2 Superconductors Prepared by the Solid State Reaction Method using MgB4 and Mg Powder)

  • 정현덕;김찬중;전병혁;김설향;박해웅
    • 한국분말재료학회지
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    • 제22권5호
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    • pp.344-349
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    • 2015
  • $MgB_2$ bulk superconductors are synthesized by the solid state reaction of ($MgB_4$+xMg) precursors with excessive Mg compositions (x=1.0, 1.4, 2.0 and 2.4). The $MgB_4$ precursors are synthesized using (Mg+B) powders. The secondary phases ($MgB_4$ and MgO) present in the synthesized $MgB_4$ are removed by $HNO_3$ leaching. It is found that the formation reaction of $MgB_2$ is accelerated when Mg excessive compositions are used. The magnetization curves of $Mg_1+_xB_2$ samples show that the transition from the normal state to the superconducting state of the Mg excessive samples with x=0.5 and x=0.7 are sharper than that of $MgB_2$. The highest $J_c-B$ curve at 5 K and 20 K is achieved for x=0.5. Further addition of Mg decreases the $J_c$ owing to the formation of more pores in the $MgB_2$ matrix and smaller volume fraction of $MgB_2$.