• 제목/요약/키워드: Engineered surface

검색결과 127건 처리시간 0.03초

The Role of Surface Oxide of Metal Nanoparticles on Catalytic Activity of CO Oxidation Unraveled with Ambient Pressure X-ray Photoelectron Spectroscopy

  • Park, Jeong Young
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.132-132
    • /
    • 2013
  • Colloidal synthesis of nanoparticles with well-controlled size, shape, and composition, together with development of in situ surface science characterization tools, such as ambient pressure X-ray photoelectron spectroscopy (APXPS), has brought new opportunities to unravel the surface structure of working catalysts. Recent studies suggest that surface oxides on transition metal nanoparticles play an important role in determining the catalytic activity of CO oxidation. In this talk, I will outline the recent studies on the influence of surface oxides on Rh, Pt, Ru and Co nanoparticles on the catalytic activity of CO oxidation [1-3]. Transition metal nanoparticle model catalysts were synthesized in the presence of poly(vinyl pyrrolidone) polymer capping agent and deposited onto a flat Si support as two-dimensional arrays using the Langmuir-Blodgett deposition technique. APXPS studies exhibited the reversible formation of surface oxides during oxidizing, reducing, and CO oxidation reaction [4]. General trend is that the smaller nanoparticles exhibit the thicker surface oxides, while the bigger ones have the thin oxide layers. Combined with the nature of surface oxides, this trend leads to the different size dependences of catalytic activity. Such in situ observations of metal nanoparticles are useful in identifying the active state of the catalysts during use and, hence, may allow for rational catalyst designs for practical applications. I will also show that the surface oxide can be engineered by using the simple surface treatment such as UV-ozone techniques, which results in changing the catalytic activity [5]. The results suggest an intriguing way to tune catalytic activity via engineering of the nanoscale surface oxide.

  • PDF

Living Building Material의 광합성 작용을 통한 CO2 흡수 능력 평가 (Photo-autotrophic Behavior of Engineered Living Building Materials)

  • 장인동;이종구
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2022년도 가을 학술논문 발표대회
    • /
    • pp.31-32
    • /
    • 2022
  • Unlike conventional building materials, the living building material (LBM) cube is composed of sand, gelatin, and cyanobacteria without cement. The surface of the LBM cube absorbs CO2 from the atmosphere by photosynthesis and is deposited in the form of CaCO3. In addition, the crystals generated in this process strengthened the gelatin-sand structure to enhance the compressive strength.

  • PDF

도심지 지하철 터널의 붕괴유형과 원인 (Modes and Causes of Collapse of Subway Tunnels)

  • 박광준;이인근
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 1993년도 봄 학술회 논문집
    • /
    • pp.41-48
    • /
    • 1993
  • The 2nd phase of Seoul Subway, Lines 5,6,7 and 8, is in progress. To reduce the surface traffic congestion during construction the greater part of the system has been engineered by bored tunnelling. The current tunnelling methodology is based on the New Austrian Tunnelling Method. Serveral collapses have been reported to date. Most of the collapses took place in the area forwed with soft ground. The modes and causes of the collapses were progressive failures in the unsupported surface and sliding failures due to the unfavourable joint direction. The major causes turned out to be the weakness of ground and the sudden influx of ground water from the surface. Some measures to prevent the failures are also presented. To ensure the safe tunnelling ghrough the soft ground the unsupported excavation area has to be minimized and closed as early as possible. Additional support measures such as supporting core, sealing shotcrete, forepoling, spread footing, face rock bolting and grouting should be employed as well depend on ground conditions.

  • PDF

A Case Study on the Safety Assessment for Groundwater Pathway in a Near-Surface Radioactive Waste Disposal Facility

  • Park, Joo-Wan;Chang, Keun-Moo;Kim, Chang-Lak
    • Nuclear Engineering and Technology
    • /
    • 제34권3호
    • /
    • pp.232-241
    • /
    • 2002
  • A safety assessment is carried out for the near-surface radioactive waste disposal in the reference engineered vault facility. The analysis is mainly divided into two parts. One deals with the release and transport of radionuclide in the vault and unsaturated zone. The other deals with the transport of radionuclide in the saturated zone and radiological impacts to a human group under well drinking water scenario. The parameters for source-term, geosphere and biosphere models are mainly obtained from the site specific data. The results show that the annual effective doses are dominated by long lived, mobile radionuclides and their associated daughters. And it is found that the total effective dose for drinking water is far below the general criteria of regulatory limit for radioactive waste disposal facility.

Study on Rainfall Infiltration Into Vault of Near-surface Disposal Facility Based on Various Disposal Scenarios

  • Kwon, Mijin;Kang, Hyungoo;Cho, Chunhyung
    • 방사성폐기물학회지
    • /
    • 제19권4호
    • /
    • pp.503-515
    • /
    • 2021
  • In this study, rainfall infiltration in vault of the second near-surface disposal facility was evaluated on the basis of various disposal scenarios. A total of four different disposal scenarios were examined based on the locations of the radioactive waste containers. A numerical model was developed using the FEFLOW software and finite element method to simulate the behavior of infiltrated water in each disposal scenario. The effects of the disposal scenarios on the infiltrated water were evaluated by estimating the flux of the infiltrated water at the vault interfaces. For 300 years, the flux of infiltrated water flowing into the vault was estimated to be 1 mm/year or less for all scenario. The overall results suggest that when the engineered barriers are intact, the flux of infiltrated water cannot generate a sufficient pressure head to penetrate the vault. In addition, it is confirmed that the disposal scenarios have insignificant effects on the infiltrated water flowing into the vault.

Important Parameters Related With Fault for Site Investigation of HLW Geological Disposal

  • Jin, Kwangmin;Kihm, You Hong;Seo, Dong-Ik;Kim, Young-Seog
    • 방사성폐기물학회지
    • /
    • 제19권4호
    • /
    • pp.533-546
    • /
    • 2021
  • Large earthquakes with (MW > ~ 6) result in ground shaking, surface ruptures, and permanent deformation with displacement. The earthquakes would damage important facilities and infrastructure such as large industrial establishments, nuclear power plants, and waste disposal sites. In particular, earthquake ruptures associated with large earthquakes can affect geological and engineered barriers such as deep geological repositories that are used for storing hazardous radioactive wastes. Earthquake-driven faults and surface ruptures exhibit various fault zone structural characteristics such as direction of earthquake propagation and rupture and asymmetric displacement patterns. Therefore, estimating the respect distances and hazardous areas has been challenging. We propose that considering multiple parameters, such as fault types, distribution, scale, activity, linkage patterns, damage zones, and respect distances, enable accurate identification of the sites for deep geological repositories and important facilities. This information would enable earthquake hazard assessment and lower earthquake-resulted hazards in potential earthquake-prone areas.

리버스 엔지니어링으로 생성된 데이터를 이용한 쾌속 조형 기술 연구 (Rapid Prototyping from Reverse Engineered Geometric Data)

  • 우혁제;이관행
    • 한국정밀공학회지
    • /
    • 제16권1호통권94호
    • /
    • pp.95-107
    • /
    • 1999
  • The design models of a new product in general are created using clay models or wooden mock-ups. The reverse engineering(RE) technology enables us to quickly create the CAD model of the new product by capturing the surface of the model using laser digitizers or coordinate measuring machines. Rapid prototyping (RP) is another technology that can reduce the product development time by fabricating the physical prototype of a part using a layered manufacturing technique. In reverse engineering process, however, the digitizer generates an enormous amount of point data, and it is time consuming and also inefficient to create surfaces out of these data. In addition, the surfacing operation takes a great deal of time and skill and becomes a bottleneck. In rapid prototyping, a faceted model called STL file has been the industry standard for providing the CAD input to RP machines. It approximates the CAD model of a part using many planar triangular patches and has drawbacks. A novel procedure that overcomes these problems and integrates RE with RP is proposed. Algorithms that drastically reduce the point clouds data have been developed. These methods will facilitate the use of reverse engineered geometric data for rapid prototyping, and thereby will contribute in reducing the product development time.

  • PDF

Viable Alternatives to in vivo Tests for Evaluating the Toxicity of Engineered Carbon Nanotubes

  • Kwon, Soon-Jo;Eo, Soo-Mi
    • 한국환경보건학회지
    • /
    • 제38권1호
    • /
    • pp.1-7
    • /
    • 2012
  • Carbon nanotubes (CNTs) stand at the frontier of nanotechnology and are destined to stimulate the next industrial revolution. Rapid increase in their production and use in the technology industry have led to concerns over the effects of CNT on human health and the environment. The prominent use of CNTs in biomedical applications also increases the possibility of human exposure, while properties such as their high aspect ratio (fiber-like shape) and large surface area raise safety concerns for human health if exposure does occur. It is crucial to develop viable alternatives to in vivo tests in order to evaluate the toxicity of engineered CNTs and develop validated experimental models capable of identifying CNTs' toxic effects and predicting their level of toxicity in the human respiratory system. Human lung epithelial cells serve as a barrier at the interface between the surrounding air and lung tissues in response to exogenous particles such as air-pollutants, including CNTs. Monolayer culture of the key individual cell types has provided abundant fundamental information on the response of these cells to external perturbations. However, such systems are limited by the absence of cell-cell interactions and their dynamic nature, which are both present in vivo. In this review, we suggested two viable alternatives to in vivo tests to evaluate the health risk of human exposure to CNTs.

잠수함 마스트 커버의 구조해석 및 3D 프린팅 (3D Printing and Structure Anlaysis of the Submarine Mast Cover)

  • 우재혁;차병준;진철규
    • 한국산업융합학회 논문집
    • /
    • 제26권5호
    • /
    • pp.937-943
    • /
    • 2023
  • In this study, the mast cover of submarine was reverse engineered and structural analysis was performed. In order to print with the 3D printer, the modeling was reduced to 1/5 size by applying geometric similarity. From the structural analysis results, it was found that the maximum value of equivalent stress generated in the mast cover was 180.9 MPa. This stress value occurs on the inner surface in the major axis. As a result of applying the load condition at a diving depth of 600 m, the mast cover is in a completely elastic state. The 1/5 size model printed on FDM 3D printer with PLA filament was the same as the reverse engineered modeling and it was printed in a perfect shape with no apparent defects. The 1/5 size model printed on PBF 3D printer with SUS316L powder was perfectly manufactured with no apparent defects.

화염경화 표면처리 공정에 의한 12Cr 강의 잔류응력 거동 (Behavior of the Residual Stress on the Surfaces of 12Cr Steels Generated by Flame Hardening Process)

  • 이민구;김광호;김경호;김흥회
    • 한국표면공학회지
    • /
    • 제37권4호
    • /
    • pp.226-233
    • /
    • 2004
  • The residual stresses on the surfaces of low carbon 12Cr steels used as a nuclear steam turbine blade material have been studied by controlling the flame hardening surface treatments. The temperature cycles on the surfaces of 12Cr steel were controlled precisely as a function of both the surface temperature and cooling rate. The final residual stress state generated by flame hardening was dominated by two opposite competitive contributions; one is tensile stress due to phase transformation and the other is compressive stress due to thermal contraction on cooling. The optimum processing temperatures required for the desirable residual stress and hardness were in the range of $850^{\circ}C$ to $960^{\circ}C$ on the basis of the specification of GE power engineering. It was also observed that the high residual tensile stress generated by flame hardening induced the cracks on the surfaces, especially across the prior austenite grain boundaries, and the material failure virtually, which might limit practical use of the surface engineered parts by flame hardening.