• Title/Summary/Keyword: Energy density

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Degradation of a nano-thick Au/Pt bilayered catalytic layer with an electrolyte in dye sensitized solar cells (염료감응태양전지의 Au/Pt 이중 촉매층의 전해질과의 반응에 따른 열화)

  • Noh, Yunyoung;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.4013-4018
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    • 2014
  • A 0.45 $cm^2$ DSSC device with a glass/FTO/blocking layer/$TiO_2$/N719(dye)/electrolyte/50 nm-Pt/50 nm-Au/FTO/glass was prepared to examine the stability of the Au/Pt bilayered counter electrode (CE) with electrolyte and the energy conversion efficiency (ECE) of dye-sensitized solar cells (DSSCs). For comparison, a 100 nm-thick Pt only CE DSSC was also prepared using the same method. The photovoltaic properties, such as the short circuit current density ($J_{sc}$), open circuit voltage ($V_{oc}$), fill factor (FF), and ECE, were checked using a solar simulator and potentiostat with time after assembling the DSSC. The microstructure of the Au/Pt bilayer was examined by optical microscopy after 0~25 minutes. The ECE of the Pt only CE-employed DSSC was 4.60 %, which did not show time dependence. On the other hand, for the Au/Pt CE DSSC, the ECEs after 0, 5 and 15 minutes were 5.28 %, 3.64 % and 2.09 %, respectively. The corrosion areas of the Au/Pt CE determined by optical microscopy after 0, 5, and 25 minutes were 0, 21.92 and 34.06 %. These results confirmed that the ECE and catalytic activity of Au/Pt CE decreased drastically with time. Therefore, a Au/Pt CE-employed DSSC may be superior to the Pt only CE-employed one immediately after integration of the device, but it would degrade drastically with time.

Dietary Fermented Soybean Meal as a Replacement for Fish Meal in Juvenile Olive Flounder Paralichthys olivaceus (치어기 넙치(Paralichthys olivaceus) 사료내 어분 대체원으로서 발효 대두박 이용성)

  • Kim, Kang-Woong;Kim, Kyoung-Duck;Lee, Bong-Joo;Lee, Jin-Hyeok;Han, Hyon-Sob;Koo, Ja-Wan;Choi, Youn Hee;Bai, Sungchul C.
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.6
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    • pp.769-776
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    • 2013
  • This study evaluated fermented soybean meal (FSM) as a fish meal (FM) replacement and determined the appropriate amount of FSM in juvenile olive flounder diet. Twenty-four aquaria with a flowing-water system were stocked with fish averaging 20.9 g at a density of 25 fish/tank. Five experimental diets were prepared replacing FM with 0, 10, 20, 30, or 40% FSM based on FM protein (designated $FSM_{0}$, $FSM_{10}$, $FSM_{20}$ $FSM_{30}$, and $FSM_{40}$, respectively). Two additional diets were prepared that replaced 30 or 40% of the FM with FSM with added amino acids (methionine and lysine) (designated $FSM_{30+AA}$, and $FSM_{40+AA}$, respectively). Fish (triplicates) were fed one of the eight experimental diets (50% crude protein and 16.7 kJ available energy $g^{-1}$ diet) for 8 weeks. Survival did not differ among the treatments during the feeding experiment. There were no significant differences in weight gain (WG) or specific growth rate (SGR) among the fish fed diets with up to 30% of the FM replaced. However, fish fed $FSM_{40}$ or $FSM_{40+AA}$ had a reduced WG and SGR, as compared to $FSM_0$ (control) (P < 0.05). The feed efficiency and apparent digestibility showed a similar trend (P < 0.05). The proximate composition in the whole body of fish differed only between the control and $FSM_{40}$ for the crude protein level and between the control and $FSM_{30+AA}$ for the crude lipid level. The whole-body amino acid composition did not differ among treatments. No significant differences were found between the diet groups with and without amino acid supplementation, indicating that amino acid supplementation had no effect. The major finding of this study is that fermented soybean meal may replace up to 30% of fish meal without amino acid supplementation for normal growth of juvenile olive flounder.

Recent Developments and Field Application of Foreign Waterworks Automatic Meter Reading (국외 상수도 원격검침시스템의 개발 동향 및 현장 적용 사례 고찰)

  • Joo, Jin Chul;Ahn, Hosang;Ahn, Chang Hyuk;Ko, Kyung-Rok;Oh, Hyun-Je
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.12
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    • pp.863-870
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    • 2012
  • The market trends of automatic meter reading associated with smart water meters were investigated. Also, recent developments and field applications of key technology for automatic meter reading associated with smart water meters were analyzed. Smart water meters have been manufactured mostly in United States and Europe and have been expanded their business to Asia. Integrated water management system combining with the additional functions such as real-time consumption metering, cost notification, water conservation, leak detection, water quality monitoring, and flow control have been operated in automatic meter reading. Both water quality and quantity data measured from smart water meters and sensors were transferred to data concentration units through neighborhood area network, and then were transferred to integrated server through wide area network. The data transfer methods were determined by comprehensively considering urban scale, density of smart water meters, power supply and network topologies. Common data collection methods such as fixed network to data concentation units, vehicles drive by, people walk by, and drone fly by have been applied. The automatic meter reading associated with smart water meters are spread throughout the world, and both water and energy savings result in saving the money and reducing the greenhouse gases emission.

Electrochemical Oxidation of Pigment Wastewater Using the Tube Type Electrolysis Module System with Recirculation (재순환방식 튜브형 전해모듈시스템을 이용한 안료폐수의 전기화학적 산화)

  • Jeong, Jong Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.8
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    • pp.411-419
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    • 2016
  • The objective of this study was to evaluate the application possibility of tube type electrolysis module system using recirculation process through removal organic matters and nitrogen in the pigment wastewater. The tube type electrolysis module consisted of a inner rod anode and an outer tube cathode. Material used for anode was titanium electroplated with $RuO_2$. Stainless steel was used for cathode. It was observed that the pollutant removal efficiency was increased according to the decrease of flowrate and increase of current density. When the retention time in tube type electrolysis module system was 180 min, chlorate concentration was 382.4~519.6 mg/L. The chlorate production was one of the major factors in electrochemical oxidation of tube type electrolysis module system using recirculation process used in this research. The pollutant removal efficiencies from the bench scale tube type electrolysis module system using recirculation operated under the electric charge of $4,500C/dm^2$ showed the $COD_{Mn}$ 89.6%, $COD_{Cr}$ 67.8%, T-N 96.8%, and Color 74.2%, respectively and energy consumption was $5.18kWh/m^3$.

Chemical Devulcanization for the Recycling of Rubber Powder of Waste Tires and Mechanical Properties (폐타이어 고무분말 재활용을 위한 화학적 탈황과 기계적 물성 평가)

  • An, Ju-Young;Park, Jong-Moon;Bang, Daesuk;Kim, Bong-seok;Oh, Myung-Hoon
    • Resources Recycling
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    • v.24 no.3
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    • pp.59-65
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    • 2015
  • Recycling of vulcanized rubber products is a serious problem in the world. A quantity of generated waste tires becomes much more and more because of increasing demands on automobiles, resulted in the cause of serious secondary pollution by sulfur component that is crosslinked to incineration or landfill. In addition, crosslinked surfur is used to interfere with the binding of the raw material rubber. In this study, we analyzed the degree of devulcanization by the chemical devulcanization. Devulcanization ratio of the samples were systematically analysed by variables such as time and temperature. In addition, the effect of swelling method as a pre-treatment process was also measured. A rubber specimen was deepened in a organic 2-buthanol solutions during various times of 1 ~ 5 hrs at 100, 150, $200^{\circ}C$ respectively, then to calculate the crosslink density and the number average molecular weight by using a parallel expansion process, which showed devulcanization degree of analyzed samples quantitatively. Also, the mechanical properties were measured with the samples prepared by using a hot press.

Metabolic engineering of the genus Clostridium for butanol production (Clostridium 속 미생물 대사공학을 통한 butanol 생산)

  • Woo, Ji Eun;Kim, Minji;Noh, Hyeon Ji;Hwang, NuRi;Kim, Jin-Hyo;Lee, Sang Yup;Jang, Yu-Sin
    • Korean Journal of Microbiology
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    • v.52 no.4
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    • pp.391-397
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    • 2016
  • Clostridium is a genus of Gram-positive, rod shape, spore-forming obligate anaerobe. Recently, Clostridium has been attracted as a host for bio-based chemical production, due to its diversity of substrate utilization and the production ability for metabolites which can be used as a building block for chemical production. Especially, butanol produced from Clostridium has been considered as an alternative fuel. As a transportation fuel, butanol has a higher energy density and lower hygroscopicity compared to ethanol, the first generation biofuel. Recently, metabolic engineering of Clostridium has been massively conducted for butanol production. In this study, the metabolic engineering strategy of Clostridium for butanol production has been reviewed with a brief perspective.

Investigation of Regraphitization during Cam Shaft Remelting (캠 샤프트 재용융 처리시 재흑연화 현상에 관한 연구)

  • Oh, Young-Kun;Kim, Gwang-Soo;Koh, Jin-Hyun
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.648-652
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    • 1998
  • TIG remelting was performed to harden the surface of automobile earn shaft. Multipass remelting was conducted in longitudinal direction under argon gas atmosphere. The microstructure of as-east earn shaft was gray iron which consisted of flake graphite and pearlitic matrix. The remelted area had microstructue of both fine pearlite and ledeburite structure that consisted of globular austenite and $Fe_3C$. Hardness for as-cast earn shaft had HRc 25~28, however it increased at remelted area to HRc 53~55. Black line was found at heat affected zone next to the fusion line, that is remelt area of previous pass, during multipass remelting. Black line was identified as graphite, which was transformed from $Fe_3C$. in the ledeburite structure. It is observed that all graphites were nucleated at $Fe_3C$. and matrix interface. High density energy laser remelting process was also applied to verify whether black line could be eliminated. However, black line was still existed as observed in TIG remelting process. Regraphitization was simulated on the ledeburitic structure specimen using Gleeble 1500 with conditions of 1100 and 100$0^{\circ}C$ for 0.5, I, 3, 5 and 1Osee. From the fact that graphite was formed even at the simulation condition of 100$0^{\circ}C$ for 0.5sec, it is seen that regraphitization is an inevitable phenomenon generated whatever processes used during multipass overlap remelting.

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Analysis of Pollution Characteristics in the Mainstream and Its Tributaries of Gongneung Stream Using Water Quality Index and Pollution Load Data (통합수질지수 및 오염부하자료를 이용한 공릉천 유입지천과 본류의 오염특성 분석)

  • Yu, Jae-Hyun;Lee, Han-Saem;Lim, Byung-Ran;Kang, Joo-Hyoung;Ahn, Tae-Ung;Shin, Hyun-Sang
    • Journal of Korean Society on Water Environment
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    • v.36 no.2
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    • pp.125-136
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    • 2020
  • In this study, we identified the major pollution-zones of the mainstream and its tributaries of Gongneung stream and investigated their pollution sources based on water quality, flowrate and pollution-load data of the stream having the characteristics of the urban-rural complex to examine the effect of the tributaries on the water quality changes in the mainstream. The water quality and flowrate data were collected for 10 months (2018 ~ 2019) at 3 points of mainstream and ten tributaries. Water quality index (WQI), load duration curve (LDC), discharge load density (DLD)and delivery ratios for each tributary were obtained so as to investigate the pollution characteristics and some of the information visualized on GIS. The main pollution-zone in the Gongneung stream was in the middle and lower streams, and the tributaries that may affect the pollution of the area were JS, JY, SL and SM. JS and SL had low WQI levels (34.7/37.5) and DLD (kg/d/㎢) of BOD and T-P were relatively high in JY (99.2/6.00) and SL (60.0/2.07). BOD and T-P delivery ratios in JS were high (0.94/0.83), suggesting that JS had significant influence on the water quality of the main pollution-zone in the Gongneung stream. Meanwhile, SM having a high T-P delivery ratio (0.97) was found to be more affected by the non-point source due to the higher LDC excess rate (%) in the low flow compared to high flow. This study provides basic data on the water quality and pollution characteristics of the Gongneung stream, and the analysis results are expected to be used as examples for identifying the main pollution-zone and tributaries of stream and their pollution sources.

Effect of Schmidt Number on Cohesive and Non-cohesive Sediment Suspension Modeling (점착성, 비점착성 부유사 모형에 대한 Schmidt 수의 영향)

  • Byun, Ji-Sun;Son, Minwoo
    • Journal of Korea Water Resources Association
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    • v.47 no.8
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    • pp.703-715
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    • 2014
  • This study aims to investigating the effect of Schmidt number (${\sigma}_c$) on sediment suspension and hydrodynamics calculation. The range of ${\sigma}_c$ is also studied based on the flux Richardson number ($Ri_f$) and gradient Richardson number ($Ri_g$). Numerical experiments are carried out by 1 dimensional vertical model. Both cohesive and non-cohesive sediments are tested under the conditions of pure current and oscillatory flow. The turbulence damping effect due to sediment suspension is examined considering ${\sigma}_c$ as a constant for the damping effect. The results of this study show the consistent effect of ${\sigma}_c$ on sediment suspension regardless of hydrodynamic condition. It is also found that the model overestimates the flow velocity and turbulent kinetic energy when the damping effect is not considered. Under the conditions of $Ri_f$ and $Ri_g$ causing density stratification, it is known that the vertical mixing of sediment is reasonably calculated in the range of ${\sigma}_c$ from 0.3 to 0.5.

Optimal Site Selection of Floating Offshore Wind Farm using Genetic Algorithm (유전 알고리즘을 활용한 부유식 해상풍력단지 최적위치 선정)

  • Lee, Jeong-Seok;Son, Woo-Ju;Lee, Bo-Kyeong;Cho, Ik-Soon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.6
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    • pp.658-665
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    • 2019
  • Among the renewable energy resources, wind power is growing rapidly in terms of technological development and market share. Recently, onshore wind farm have been affected by limitations of terrestrial space and environmental problems. Consequently, installation sites have been moved to the sea, and the development of floating offshore wind farms that are installed at deep waters with more abundant wind conditions is actively underway. In the context of maritime traffic, the optimal site of offshore wind farms is required to minimize the interference between ships and wind turbines and to reduce the probability of accidents. In this study, genetic algorithm based AIS(Automatic Indentification System) data composed of genes and chromosomes has been used. The optimal site of floating offshore wind farm was selected by using 80 genes and by evaluating the fitness of genetic algorithm. Further, the final site was selected by aggregating the seasonal optimal site. During analysis, 11 optimal site were found, and it was verified that the final site selected usng the genetic algorithm was viable from the perspective of maritime traffic.