• Title/Summary/Keyword: Energy density

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A Study on the Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Atomic Layer-Deposited Thin-Film Electrolyte (수소연료를 이용하는 원자층증착 박막전해질 세라믹연료전지의 초기성능 저하에 관한 연구)

  • JI, SANGHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.410-416
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~17% for 40 minutes, which rapidly decreased in the early stage of the performance evaluation but gradually decreased. The open circuit voltage ratio decreased with respect time; however, its time behavior was remarkably different with the reduction behavior of the peak power density ratio. The activation resistance ratio increased as ~15% for 40 minutes, which was almost similar with the time behavior of the peak power density ratio.

Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Plasma-Enhanced Atomic Layer-Deposited Ultra-Thin Electrolyte (플라즈마 원자층증착 초박막전해질 수소 세라믹연료전지의 초기성능 저하)

  • JI, SANGHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.340-346
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte fabricated by plasma-enhanced atomic layer deposition method was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~52% for 30 min, which continually decreased as time increased but degradation rate gradually decreased. The open circuit voltage ratio decreased with respect time; however, its behavior was evidently different from the reduction behavior of the peak power density. The activation resistance ratio increased as ~127% for 30 min, which was almost similar with the reduction behavior of the peak power density ratio.

A Study on the Prediction of the Material Properties of Magnesium Alloys Using Density Functional Theory Method (밀도함수 이론법을 이용한 마그네슘 합금의 재료특성 예측에 관한 연구)

  • Baek, Min-Sook;Won, Dae-Hee;Kim, Byung-Il
    • Korean Journal of Materials Research
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    • v.17 no.12
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    • pp.637-641
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    • 2007
  • The total energy and strength of Mg alloy doped with Al, Ca and Zn, were calculated using the density functional theory. The calculations was performed by two programs; the discrete variational $X{\alpha}\;(DV-X{\alpha})$ method, which is a sort of molecular orbital full potential method; Vienna Ab-initio Simulation Package (VASP), which is a sort of pseudo potential method. The fundamental mixed orbital structure in each energy level near the Fermi level was investigated with simple model using $DV-X{\alpha}$. The optimized crystal structures calculated by VASP were compared to the measured structure. The density of state and the energy levels of dopant elements was discussed in association with properties. When the lattice parameter obtained from this study was compared, it was slightly different from the theoretical value but it was similar to Mk, and we obtained the reliability of data. A parameter Mk obtained by the $DV-X{\alpha}$ method was proportional to electronegativity and inversely proportional to ionic radii. We can predict the mechanical properties because $\Delta{\overline{Mk}}$is proportional to hardness.

Parametric Study for Excimer Laser-induced Crystallization in the a-Si thin film

  • Moon, Min-Hyung;Kim, Hyun-Jae;Choi, Kwang-Soo;Souk, Jun-Hyung;Seo, Chang-Ki;Kim, Do-Young;Dhungel, Suresh Kumar;Yi, Junsin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.630-633
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    • 2003
  • Integrating the driver circuitry directly onto the glass substrate would be one of the advantages of polycrystalline Si (poly-Si) TFT-(LCD). Low-temperature poly-Si TFT(LTPS) is well-suited for higher-definition display applications due to its intrinsically superior electrical characteristics. In order to improve LTPS electrical characteristics, currently the excimer laser-induced crystallization (ELC) processes and sequential lateral solidification method were developed. Grain size of the poly-Si is mainly affected by beam pitch and energy density. Key parameter for making a larger poly-Si using excimer laser annealing(ELA) and increasing a throughput is due to increase in beam pitch and energy density to a certain degree. Furthermore, thin $SiO_{2}$ capping is effective to suppress the protrusion of the poly-Si thin films and to reduce the interface state density. From the ELA process, we are able to control grain size by varying different parameters such as number of shots and energy density.

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Enhancement of the Critical Current Density of $MgB_2$ Prepared using Mechanically Milled and Glycerin Treated Boron Powder (기계적 밀링 및 글리세린 처리된 보론 분말을 사용하여 제조된 $MgB_2$의 임계전류밀도 향상)

  • Jun, Byung-Hyuk;Kim, Yi-Jeong;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.10 no.1
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    • pp.40-44
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    • 2008
  • A combined process of a mechanical ball milling and liquid glycerin ($C_{3}H_{8}O_3$) treatment of boron (B) powder has been conducted to enhance the superconducting properties of $MgB_2$. The individual aims of the mechanical milling and the glycerin treatment were to reduce the grain size of the $MgB_2$ and to achieve homogeneous carbon (C) incorporation into the $MgB_2$, respectively. Four kinds of B powders of as-received, glycerin treated, 2 h milled, and 2 h milled + glycerin treated were prepared. $MgB_2$ bulks were fabricated by in situ process using the prepared B powders. The mechanical ball milling was effective for a grain refinement, and a lattice disorder was easily achieved by glycerin addition. It was found that the critical current density ($J_c$) values were enhanced in the samples with milled B or glycerin treated B only. In the $MgB_2$ bulk prepared with both milled and glycerin treated B, the $J_c$ was further increased due to a higher grain boundary density and a greater C substitution.

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The Effects of Fabrication Variable on the Characteristics of Simulated Spent Fuel (모의 사용후핵연료의 특성에 미치는 제조변수의 영향)

  • 강권호;류호진;배정현;송기찬;양명승
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.278-285
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    • 2001
  • In this study, the effects of the variables on sintering of simulated fuel to simulate the spent fuel are described. Mainly, the effects of compaction pressure, sintering temperature and time on the density of pellet are described. The experimental is performed with compaction pressure of 1 ton/$\textrm{cm}^2$~4 ton/$\textrm{cm}^2$, sintering temperature of 167$0^{\circ}C$, 173$0^{\circ}C$ and 178$0^{\circ}C$ and sintering time of 4 hr, 8 hr and 24 hr. The green density of simulated fuel is proportional to the one third power of compaction pressure and the sintered density is 90.5~99.6% of theoretical density. The grain growth exponent and activation energy of simulated fuel is 2.5 and 287.97 kJ/mol, respectively.

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Measurement of the fast Neutron Flux Density in the Bulk Shielding Experimental Tank of the TRIGA Mark-II Reactor Using Solid State Track Detector

  • Ro, Seung-Gy;Jun, Jae-Shik;Cho, Sae-Hyung
    • Nuclear Engineering and Technology
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    • v.5 no.4
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    • pp.334-338
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    • 1973
  • The horizontal distribution of the fast neutron flux density in the Bulk Shielding Experimental Tank of the TRIGA Mark-II reactor at the steady power of 250 KW has been measured using a solid state track detector which is natural mica placed in contact with $^{232}$ Th fissile foil. The neutron flux density was calculated on the assumption that the fast neutron spectrum is similar to that from the thermal-induced $^{235}$ U fission. The resulting flux density distribution along the horizontal line from the center of the thermalizing column door is presented in tabular and graphical forms.

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Analysis of Inductively Coupled Plasma using Electrostatic Probe and Fluid Simulation (정전 탐침법과 유체 시뮬레이션을 이용한 유도결합 Ar 플라즈마의 특성 연구)

  • Cha, Ju-Hong;Lee, Ho-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.7
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    • pp.1211-1217
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    • 2016
  • Discharge characteristics of inductively coupled plasma were investigated by using electrostatic probe and fluid simulation. The Inductively Coupled Plasma source driven by 13.56 Mhz was prepared. The signal attenuation ratios of the electrostatic probe at first and second harmonic frequency was tuned in 13.56Mhz and 27.12Mhz respectively. Electron temperature, electron density, plasma potential, electron energy distribution function and electron energy probability function were investigated by using the electrostatic probe. Experiment results were compared with the fluid simulation results. Ar plasma fluid simulations including Navier-Stokes equations were calculated under the same experiment conditions, and the dependencies of plasma parameters on process parameters were well agreed with simulation results. Because of the reason that the more collision happens in high pressure condition, plasma potential and electron temperature got lower as the pressure was higher and the input power was higher, but Electron density was higher under the same condition. Due to the same reason, the electron energy distribution was widening as the pressure was lower. And the electron density was higher, as close to the gas inlet place. It was found that gas flow field significantly affect to spatial distribution of electron density and temperature.

Compaction and Sintering Characteristics of High Energy Ball Milled Mn-Zn Ferrite Powders

  • Lee, Hyunseung;Rhee, Hoseong;Lee, Sangsoo;Chang, Si Young
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.677-681
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    • 2021
  • The Mn-Zn ferrite powders were prepared by high energy ball milling, then compacted and sintered at various temperatures to assess their sintering behavior and magnetic properties. The initial ferrite powders were spherical in shape with the size of approximately 70 ㎛. After 3 h of ball milling at 300 rpm, aggregated powders ~230 nm in size and composed of ~15 nm nanoparticles were formed. The milled powders had a density of ~70 % when compacted at 490 MPa for 3 min. In the samples subsequently sintered at 1,273 K ~ 1,673 K for 3 h, the MnZnFe2O4 phase was detected. The density of the sintered samples had a tendency to increase with increasing sintering temperature up to 1,473 K, which produced the highest density of 98 %. On the other hand, the sample sintered at 1,373 K had the highest micro-hardness of approximately 610 Hv, which is due to much finer grains.

Characterization of Electrochemical Ammonia Electrolysis Using a Platinum Electrode for Anodic Reaction (Pt포일 양극을 이용한 전기화학적 암모니아 수전해 특성 연구)

  • CHOI, JEONGMIN;KIM, HAKDEOK;SONG, JUHUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.337-342
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    • 2022
  • In this study, a water electrolysis was studied to investigate the effect of ammonia on current density and H2 gas production. A H type cell with three electrodes was used and KOH solution was used as electrolyte. The conventional platinum foil was used for working electrode, whereas nickel foam was used for counter electrode. CV experiment was performed to see the activity of ammonia oxidation reaction. In addition, CP experiment was done to examine the dependence of Faraday efficiency of hydrogen on current density and NH3 concentration. The CV result shows the 0.5M NH3 concentration required for highest current density and reliable operation. The CP result shows the increased current density leads to higher H2 generation. The higher H2 production and subsequent energy efficiency was observed for 0.5M NH3 using a Pt/13%Rh coil for a cathode as compared to those in water electrolysis.