• Title/Summary/Keyword: Energy confinement

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1차원 무기 반도체 신 물질 재료의 연구 개발 동향

  • Ryu, Hak-Gi
    • Ceramist
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    • v.21 no.2
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    • pp.29-37
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    • 2018
  • In order to overcome the problems of existing low-dimensional materials (carbon nanotubes, graphene, transition metal dichalcogenides, etc) researches on new 1D materials have been studied. In the case of $LiMo_3Se_3$ and $Mo_6S_{9-x}I_x$, continuous researches have been carried out for 3D bulk synthesis and atomic scale dispersion. Recently, quantum confinement effect of $LiMo_3Se_3$ and bio-stability of $Mo_6S_{9-x}I_x$ have been proven and various applications have started to be studied. In addition, device application results using new 1D materials such as $Sb_2Se_3$ (optoelectronic devices using the property of effectively reducing exciton decay due to no dangling bond) and $VS_4$ (electrochemical energy storage using the space between 1-D nanostructures) have been reported very importantly. Therefore, it can be claimed that it has reached a very important time to find and synthesize new 1D materials and to report various characteristics not existing.

Rehabilitation and strengthening of exterior RC beam-column connections using epoxy resin injection and FRP sheet wrapping: Experimental study

  • Marthong, Comingstarful
    • Structural Engineering and Mechanics
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    • v.72 no.6
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    • pp.723-736
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    • 2019
  • The efficacy of a technique for the rehabilitation and strengthening of RC beam-column connections damaged due to cyclic loading was investigated. The repair mainly uses epoxy resin infused under pressure into the damaged region to retrieved back the lost capacity and then strengthening using fiber reinforced polymer (FRP) sheets for capacity enhancement. Three common types of reduced scale RC exterior beam-column connections namely (a) beam-column connection with beam weak in flexure (BWF) (b) beam-column connections with beam weak in shear (BWS) and (c) beam-column connections with column weak in shear (CWS) subjected to reversed cyclic loading were considered for the experimental investigation. The rehabilitated and strengthened specimens were also subjected to similar cyclic displacement. Important parameters related to seismic capacity such as strength, stiffness degradation, energy dissipation, and ductility were evaluated. The rehabilitated connections exhibited equal or better performance and hence the adopted rehabilitation strategies could be considered as satisfactory. Confinement of damaged region using FRP sheet significantly enhanced the seismic capacity of the connections.

Localizd Failure and Fracture energies in Concrete under Compression (압축 응력 하에서의 콘크리트의 파괴거동)

  • 최석환
    • Magazine of the Korea Concrete Institute
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    • v.9 no.6
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    • pp.165-174
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    • 1997
  • 고강도 및 보통강도 콘크리트의 압축파괴 거동에 영향을 미치는 요소들 (재료의 강도, 시편의 세장비, 전단구속, 실험장치의 강성, 피드백 신호)에 관한 연구가 수행되었다. 피드백 신호로 자동 조절되는 유압 실험기계항에서 원주변형 피드백 신호를 사용하여 연화곡선을 구했다. 재하장치로부터의 단부 전단 구속을 줄이면 제한된 영역 안에서 재하방향 균형이 형성되고, 또한 연화곡선의 경사가 급해지고 파괴에너지도 작아진다. 이때 길이가 큰 시편에서 파괴에너지가 커지는 것은 안장과는 달리 단순균열이 형성되는 것이 아니고 , 파괴가 용적을 가진다는 것을 의미한다. 압축응력하의 국부 파괴는 재료특성이 아니므로, 단부 전단구속이 없더라도 재료적 특성으로서의 응력-변형도 곡선은 정하기 어렵다.

Rehabilitation of exterior RC beam-column connections using epoxy resin injection and galvanized steel wire mesh

  • Marthong, Comingstarful
    • Earthquakes and Structures
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    • v.16 no.3
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    • pp.253-263
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    • 2019
  • The efficacy of a galvanized steel wire mesh (GSWM) as an alternative material for the rehabilitation of RC beam-column connections damaged due to reversed cyclic loading was investigated. The repair mainly uses epoxy resin infused under pressure into the damaged zone and then confined using three types of locally available GSWM mesh. The mesh types used herein are (a) Weave type square mesh with 2mm grid opening (GWSM-1) (b) Twisted wire mesh with hexagonal opening of 15 mm (GSWM-2) and (c) welded wire mesh with square opening of 25 mm (GSWM-3). A reduced scale RC beam-column connection detailed as per ductile detailing codes of Indian Standard was considered for the experimental investigation. The rehabilitated specimens were also subjected to similar cyclic displacement. Important parameters related to seismic capacity such as strength, stiffness degradation, energy dissipation, and ductility were evaluated. The rehabilitated connections exhibited equal or better performance and hence the adopted rehabilitation strategies could be considered as satisfactory. Confinement of damaged region using GSWM-1 significantly enhanced the seismic capacity of the connections.

Optical Properties of a Proton-implanted Nd:CNGG Planar Waveguide

  • Zhu, Qian-Lin;Lin, Ming-Fu;Chen, Jing-Yi;Wang, Zhong-Yue;Liu, Chun-Xiao
    • Current Optics and Photonics
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    • v.3 no.2
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    • pp.172-176
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    • 2019
  • The work reports on the fabrication of an optical planar waveguide in the Nd:CNGG crystal by the 0.4-MeV hydrogen ion implantation with a fluence of $8.0{\times}10^{16}ions/cm^2$. The nuclear energy loss of the implanted hydrogen ions was derived by using SRIM 2013 code. The microscope image of the proton-implanted Nd:CNGG crystal cross section was captured by a metallographic microscope. The transmittance spectra were recorded before and after the ion implantation. The light intensity distribution of the planar waveguide at 632.8 nm was experimentally measured to validate its effect on one dimension confinement. The investigation shows that the proton-implanted Nd:CNGG waveguide is a candidate for an optoelectronic integrated device.

Numerical method for the strength of two-dimensional concrete struts

  • Yun, Y.M.
    • Computers and Concrete
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    • v.28 no.6
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    • pp.621-634
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    • 2021
  • For the reliable strut-and-tie model (STM) design of disturbed regions of concrete members, structural designers must accurately determine the strength of concrete struts to check the strength conditions of a selected STM el and the anchorage of reinforcing bars in nodal zones. In this study, the author proposed a consistent numerical method for strut strength, applicable to all two-dimensional STMs. The proposed method includes the effects of a biaxial stress state associated with tensile strains in reinforcing bars crossing a strut, deviation angle between strut orientation and compressive principal stress flow, and degree of confinement provided by reinforcement. The author examined the method's validity through the STM prediction of the ultimate strengths of 517 reinforced concrete (RC) deep beams, 24 RC panels, and 258 RC corbels, all tested to failure.

Energy separation and carrier-phonon scattering in CdZnTe/ZnTe quantum dots on Si substrate

  • Man, Min-Tan;Lee, Hong-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.191.2-191.2
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    • 2015
  • Details of carrier dynamics in self-assembled quantum dots (QDs) with a particular attention to nonradiative processes are not only interesting for fundamental physics, but it is also relevant to performance of optoelectronic devices and the exploitation of nanocrystals in practical applications. In general, the possible processes in such systems can be considered as radiative relaxation, carrier transfer between dots of different dimensions, Auger nonradiactive scattering, thermal escape from the dot, and trapping in surface and/or defects states. Authors of recent studies have proposed a mechanism for the carrier dynamics of time-resolved photoluminescence CdTe (a type II-VI QDs) systems. This mechanism involves the activation of phonons mediated by electron-phonon interactions. Confinement of both electrons and holes is strongly dependent on the thermal escape process, which can include multi-longitudinal optical phonon absorption resulting from carriers trapped in QD surface defects. Furthermore, the discrete quantized energies in the QD density of states (1S, 2S, 1P, etc.) arise mainly from ${\delta}$-functions in the QDs, which are related to different orbitals. Multiple discrete transitions between well separated energy states may play a critical role in carrier dynamics at low temperature when the thermal escape processes is not available. The decay time in QD structures slightly increases with temperature due to the redistribution of the QDs into discrete levels. Among II-VI QDs, wide-gap CdZnTe QD structures characterized by large excitonic binding energies are of great interest because of their potential use in optoelectronic devices that operate in the green spectral range. Furthermore, CdZnTe layers have emerged as excellent candidates for possible fabrication of ferroelectric non-volatile flash memory. In this study, we investigated the optical properties of CdZnTe/ZnTe QDs on Si substrate grown using molecular beam epitaxy. Time-resolved and temperature-dependent PL measurements were carried out in order to investigate the temperature-dependent carrier dynamics and the activation energy of CdZnTe/ZnTe QDs on Si substrate.

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Eutectic Temperature Effect on Au Thin Film for the Formation of Si Nanostructures by Hot Wire Chemical Vapor Deposition

  • Ji, Hyung Yong;Parida, Bhaskar;Park, Seungil;Kim, MyeongJun;Peck, Jong Hyeon;Kim, Keunjoo
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.63-68
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    • 2013
  • We investigated the effects of Au eutectic reaction on Si thin film growth by hot wire chemical vapor deposition. Small SiC and Si nano-particles fabricated through a wet etching process were coated and biased at 50 V on micro-textured Si p-n junction solar cells. Au thin film of 10 nm and a Si thin film of 100 nm were then deposited by an electron beam evaporator and hot wire chemical vapor deposition, respectively. The Si and SiC nano-particles and the Au thin film were structurally embedded in Si thin films. However, the Au thin film grew and eventually protruded from the Si thin film in the form of Au silicide nano-balls. This is attributed to the low eutectic bonding temperature ($363^{\circ}C$) of Au with Si, and the process was performed with a substrate that was pre-heated at a temperature of $450^{\circ}C$ during HWCVD. The nano-balls and structures showed various formations depending on the deposited metals and Si surface. Furthermore, the samples of Au nano-balls showed low reflectance due to surface plasmon and quantum confinement effects in a spectra range of short wavelength spectra range.

Experimental investigation of a frame retrofitted with carbon textile reinforced mortar

  • Sinan M., Cansunar;Kadir, Guler
    • Earthquakes and Structures
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    • v.23 no.5
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    • pp.473-491
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    • 2022
  • The research investigates experimentally the effect of confinement on structural behavior at the ends of beam-column in reinforced concrete (RC) frames. In the experimental study, five specimens consisting of 1/3-scaled RC frames having single-bay, representing the traditional deficiencies of existing buildings constructed without receiving proper engineering service is investigated. The RC frame specimens were produced to represent most of the existing buildings in Turkey that have damage potential. To decrease the probable damage to the existing buildings exposed to earthquakes, the carbon Textile Reinforced Mortar (TRM) strengthening technique (fully wrapping) was used on the ends of the RC frame elements to increase the energy dissipation and deformation capacity. The specimens were tested under reversed cyclic lateral loading with constant axial loads. They were constructed satisfying the weak column-strong beam condition and consisting of low-strength concrete, such as compressive strength of 15 MPa. The test results were compared and evaluated considering stiffness, strength, energy dissipation capacity, structural damping, ductility, and damage propagation in detail. Comprehensive investigations of these experimental results reveal that the strengthening of a brittle frame with fully-TRM wrapping with non-anchored was effective in increasing the stiffness, ductility, and energy dissipation capacities of RC bare frames. It was also observed that the frame-only-retrofitting with an infill wall is not enough to increase the ductility capacity. In this case, both the frame and infill wall must be retrofitted with TRM composite to increase the stiffness, lateral load carrying, ductility and energy dissipation capacities of RC frames. The presented strengthening method can be an alternative strengthening technique to enhance the seismic performance of existing or moderately damaged RC buildings.

Exploiting Natural Diatom Shells as an Affordable Polar Host for Sulfur in Li-S Batteries

  • Hyean-Yeol Park;Sun Hyu Kim;Jeong-Hoon Yu;Ji Eun Kwon;Ji Yang Lim;Si Won Choi;Jong-Sung Yu;Yongju Jung
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.198-206
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    • 2024
  • Given the high theoretical capacity (1,675 mAh g-1) and the inherent affordability and ubiquity of elemental sulfur, it stands out as a prominent cathode material for advanced lithium metal batteries. Traditionally, sulfur was sequestered within conductive porous carbons, rooted in the understanding that their inherent conductivity could offset sulfur's non-conductive nature. This study, however, pivots toward a transformative approach by utilizing diatom shell (DS, diatomite)-a naturally abundant and economically viable siliceous mineral-as a sulfur host. This approach enabled the development of a sulfurlayered diatomite/S composite (DS/S) for cathodic applications. Even in the face of the insulating nature of both diatomite and sulfur, the DS/S composite displayed vigorous participation in the electrochemical conversion process. Furthermore, this composite substantially curbed the loss of soluble polysulfides and minimized structural wear during cycling. As a testament to its efficacy, our Li-S battery, integrating this composite, exhibited an excellent cycling performance: a specific capacity of 732 mAh g-1 after 100 cycles and a robust 77% capacity retention. These findings challenge the erstwhile conviction of requiring a conductive host for sulfur. Owing to diatomite's hierarchical porous architecture, eco-friendliness, and accessibility, the DS/S electrode boasts optimal sulfur utilization, elevated specific capacity, enhanced rate capabilities at intensified C rates, and steadfast cycling stability that underscore its vast commercial promise.