• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.19-26
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• 1986

A titanium oxide thin films were prepared by air oxidation and vapour oxidation and a $TiO_2$ single crystal was reduced by heating in an argon atmosphere. All the electrode characteristics of the Ti$O_{2-x}$, thin films are not different from those of slightly reduced single crystal rutile. In cyclic voltammogram of oxygen containing electrolyte solution at Ti$O_{2-x}$ electrodes, cathodic peaks were observed at between -0.8V and -1.0V vs. SCE. The cathodic current near 0V vs. SCE in saturated solution with nitrogen was observed to be greater than in saturated solution with air. The chronoamperogram was represented by the equation of i = $i_0e^{-kt}$, when the rate constant k was represented by the equation of k =$k_0{[H^+]}^nexp(A{\eta}+E_a/RT)$ The values of activation energy $E_a $were found to be 4.6~4.8kcal/mole in overpotential range of 0.035∼0.145 V and 1.6kcal/mole in overpotential range of 0.2∼0.5V. The values of n and A were found to be 0. 1 and 5.4~5.6/V in range of 0.035~0.145V, and in range of 0.2~0.5V, to be 0.04 and 1.3/V, respectively. This can be interpreted as an totally irreversible reduction of oxygen.

• Korean Journal of Remote Sensing
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• v.34 no.6_1
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• pp.1025-1032
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• 2018

Snow Cover is a form of precipitation that is defined by snow on the surface and is the single largest component of the cryosphere that plays an important role in maintaining the energy balance between the earth's surface and the atmosphere. It affects the regulation of the Earth's surface temperature. However, since snow cover is mainly distributed in area where human access is difficult, snow cover detection using satellites is actively performed, and snow cover detection in forest area is an important process as well as distinguishing between cloud and snow. In this study, we applied the Normalized Difference Snow Index (NDSI) and the Normalized Difference Vegetation Index (NDVI) to the geostationary satellites for the snow detection of forest area in existing polar orbit satellites. On the rest of the forest area, the snow cover detection using $R_{1.61{\mu}m}$ anomaly technique and NDSI was performed. As a result of the indirect validation using the snow cover data and the Visible Infrared Imaging Radiometer (VIIRS) snow cover data, the probability of detection (POD) was 99.95 % and the False Alarm Ratio (FAR) was 16.63 %. We also performed qualitative validation using the Himawari-8 Advanced Himawari Imager (AHI) RGB image. The result showed that the areas detected by the VIIRS Snow Cover miss pixel are mixed with the area detected by the research false pixel.

• Economic and Environmental Geology
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• v.46 no.4
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• pp.339-344
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• 2013

Water vapor isotopes can be excellent tools for understanding complex mechanisms in the water cycle and atmospheric hydrological cycle and they can be applied to various fields of paleoclimatology, atmospheric science, hydrogeology, oceanography, and ecohydrology. Thus, studies of global or local transport of water vapor may be able to provide a very useful clue to better understand the movements of water and energy in the atmosphere, hydrosphere and biosphere. In this study, the isotopic compositions of water vapor have been observed for moisture transport during the passage of Typhoon Bolaven at Korea Polar Research Institute (KOPRI), Incheon, in the western part of Korea, from August 27 to August 29, 2012. In the clear sky, the isotopic compositions of water vapor at KOPRI exhibited relatively higher isotopic ratios, which were near isotopic equilibrium with sea surface water (${\delta}^{18}O$=-14‰). On the other hand, a largely depleted isotopic ratios in surface water vapor were observed in association with the passage of Typhoon Bolaven (approximately 10‰ depleted compared to the clear sky). The fact that the isotopic minima in water vapor are encountered during the onset period of the Typhoon Bolaven with increases of relative humidity, which is consistent with, so called, "the amount effect".

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.1
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• pp.1-9
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• 2005

A stoichiometric mixture of evaporating materials for AgGaS₂ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, AgGaS₂ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were 590℃ and 440℃, respectively. The temperature dependence of the energy band gap of the AgGaS₂ obtained from the absorption spectra was well described by the Varshni's relation, E/sub g/(T) = 2.7284 eV - (8.695×10/sup -4/ eV/K)T²/(T + 332 K). After the as-grown AgGaS₂ single crystal thin films was annealed in Ag-, S-, and Ga-atmospheres, the origin of point defects of AgGaS₂ single crystal thin films has been investigated by the photoluminescence (PL) at 10 K. The native defects of V/sub Ag/, V/sub s/, Ag/sub int/, and S/sub int/ obtained by PL measurements were classified as a donors or accepters type. And we concluded that the heat-treatment in the Ag-atmosphere converted AgGaS₂ single crystal thin films to an optical n-type. Also, we confirmed that Ga in AgGaS₂/GaAs crystal thin films did not form the native defects because Ga in AgGaS₂ single crystal thin films existed in the form of stable bonds.

• Journal of the Korean Institute of Gas
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• v.16 no.4
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• pp.38-43
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• 2012

The purpose of this study is to carry out the consequence analysis of an accident related to the release of Hydrogen chloride occurred in a petrochemical company in Korea and suggest the measures to prevent similar accidents from happening again. The total amount released through the safety valve of HCl Column was calculated based on the rated capacity of the safety valve, the ideal gas equation and mechanical energy balance, respectively. As a result of the calculation, we found that the amount of HCl released through the safety valve was at least 76.8 kg. Also, we predicted the dispersion concentration at the position of the injured workers(more than 350 m away from the accident location) using simulation programs such as PHAST. The results of ALOHA and K-CARM are 304 ppm and 1,700 ppm respectively. However, PHAST calculation indicated that the concentration is less than l ppm. From these results, we can understand that workers were injured by HCl gas released from the safe valve and the concentration of gas might be less than 1 ppm. Also, it is important for toxic gases such as HCl to be vented safely to the atmosphere after scrubbing.

• Analytical Science and Technology
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• v.28 no.5
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• pp.353-360
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• 2015

Boiling is an efficient removal method to reduce radon in groundwater when ventilating indoor air. 13 groundwater samples with various radon concentrations were used to evaluate the reduction rate of radon with heating temperature and time. The groundwater samples were obtained by Bladder pump and on-situ measurements such as dissolved oxygen (DO) and hydrogen concentration (pH) and so on were carried out by a flow cell system isolated from the ambient atmosphere environment. All samples for measuring radon in groundwater were analyzed by liquid scintillation counter (LSC). The experiment result showed that increasing groundwater temperature enhanced radon removal rate but the initial radon concentration with high level lowered the removal rate. This means that radon reduction in groundwater by heating needs more heating energy and longer heating time with radon concentrations. Radon removal rate in groundwater, therefore, mainly depends on the initial radon concentration, heating temperature, and heating time.

• Korean Journal of Materials Research
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• v.8 no.7
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• pp.648-652
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• 1998

TIG remelting was performed to harden the surface of automobile earn shaft. Multipass remelting was conducted in longitudinal direction under argon gas atmosphere. The microstructure of as-east earn shaft was gray iron which consisted of flake graphite and pearlitic matrix. The remelted area had microstructue of both fine pearlite and ledeburite structure that consisted of globular austenite and $Fe_3C$. Hardness for as-cast earn shaft had HRc 25~28, however it increased at remelted area to HRc 53~55. Black line was found at heat affected zone next to the fusion line, that is remelt area of previous pass, during multipass remelting. Black line was identified as graphite, which was transformed from $Fe_3C$. in the ledeburite structure. It is observed that all graphites were nucleated at $Fe_3C$. and matrix interface. High density energy laser remelting process was also applied to verify whether black line could be eliminated. However, black line was still existed as observed in TIG remelting process. Regraphitization was simulated on the ledeburitic structure specimen using Gleeble 1500 with conditions of 1100 and 100$0^{\circ}C$ for 0.5, I, 3, 5 and 1Osee. From the fact that graphite was formed even at the simulation condition of 100$0^{\circ}C$ for 0.5sec, it is seen that regraphitization is an inevitable phenomenon generated whatever processes used during multipass overlap remelting.

• Journal of the Korean Magnetics Society
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• v.17 no.2
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• pp.65-70
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• 2007

In this paper, we composed the $LiFePO_4$ for the reversible use as the replacement material of the Li ion batteries and confirmed the good quality of the structure of the samples with the sintering temperature $675^{\circ}C,\;750^{\circ}C,\;and\;800^{\circ}C$ for 30 hours at nitrogen atmosphere. We also investigated the size of the particles through SEM picture and the change of the sintering temperature and the $Fe^{+3}$ content after charging the materials with 1 V, 160 mA and 3 V, 40 mA for 3 hours by Mossbauer spectroscopy. Also we can observe the increase on the $Fe^{+3}$ content at the charge condition and the increase of the amount ratio of the $Fe^{+3}$ ion only in sintering temperature $675^{\circ}C$ according to the increase of the electric charge. We cannot observe the change of the $Fe^{+3}$ ion in sintering temperature $800^{\circ}C$ after charging.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.5
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• pp.189-197
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• 2006

A stoichiometric mixture of evaporating materials for $AgGaSe_2$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $AgGaSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy(HWE) system. The source and substrate temperatures were $630^{\circ}C\;and\;420^{\circ}C$, respectively. The temperature dependence of the energy band gap of the $AgGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=1.9501eV-(8.79x10^{-4}eV/K)T^2(T+250K)$. After the as-grown $AgGaSe_2$ single crystal thin films was annealed in Ag-, Se-, and Ga-atmospheres, the origin of point defects of $AgGaSe_2$ single crystal thin films has been investigated by the photoluminescence (PL) at 10K. The native defects of $V_{Ag},\;V_{Se},\;Ag_{int},\;and\;Se_{int}$ obtained by PL measurements were classified as a donors or accepters type. And we concluded that the heat-treatment in the Ag-atmosphere converted $AgGaSe_2$ single crystal thin films to an optical p-type. Also, we confirmed that Ga in $AgGaSe_2$/GaAs did not form the native defects because Ga in $AgGaSe_2$ single crystal thin films existed in the form of stable bonds.

• 한국해양학회지
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• v.28 no.3
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• pp.241-258
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• 1993

To investigate the sedimentary environments on the coastal areas of Imja to Nakweol islands which show very complex shorelines and several zonal sand ridges in NE-SW direction, southwestern coast of Korea, a total of forty samples were taken by a grab sampler and sedimentological and micropaleontological studies on those samples were carried out. The present study area are classified into muddy sandy gravel, sand, city sand, sandy silt and silt facies. With statistical moment parameters such as mean, sorting, skewness and ketosis for the sediments in the study area, the sediments are generally categorized as shallow sedimentary facies. The characters that are observed in quartz grains among the sandy sediments of the study area imply the existence of high energy environments, temporal exposures in atmosphere and the mixing of clastic sediments of the several different origins. In the sediments of the study area, one genera belonging to six silicoflagellata species and five genera belonging to five nannoplankton species were detected. On the basis of the micro-organism assemblage, the study area seems to be influenced by active reworking dominantly under warm water masses. In addition, organic matter ad carbonate contents in the sediments did not show a definite relation with the occurrences of the micro-organisms in the study area.