• Title/Summary/Keyword: Energy Transition

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An Exploratory Study on the Applicability of Thin-Film Photovoltaic Cells for Auxiliary Power Supply of a Personal Rapid Transit (PRT) Vehicle (PRT 차량의 보조 전력공급을 위한 유연소재 태양전지의 적용 가능성 연구)

  • Kang, Seok-Won;Han, Soo-Jin;Jeong, Rag-Gyo;Oh, Hyuck Keun;Ko, Sangwon;Choi, Dooho
    • Journal of the Korean Society for Railway
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    • v.17 no.2
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    • pp.94-99
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    • 2014
  • Recently, trends in new transportation system development have been primarily focused on sustainable and ecofriendly mobility solutions. The personal rapid transit (PRT) system has been considered a promising candidate in this category; its competitiveness is being improved through convergence with cutting-edge electric vehicle (EV) technologies. However, battery-powered vehicles pose difficult technical challenges in attempts to achieve reliable and efficient operation. In this study, a design approach for a solar-power assisted PRT system is presented with small-scale demonstrations aimed at circumventing challenges facing its adoption, as well as helping speed the transition to electric-powered ground transportation. From the results, it is expected that flexible photovoltaic (PV) cells will be able to supply 11% of the power required by the service equipment installed in a prototype vehicle. In particular, flexible photovoltaic (PV) cells are advantageous in terms of cost, weight, and design considerations. Most importantly, the cells' flexibility and attach-ability are expected to give them great potential for extended application in various areas.

Molecular Orbital Studies on the Reaction Path and Reactivity of $S_N2$ Reactions. Determination of Reactivity by MO Theory (Part 69) (SN2 반응의 반응경로 및 반응성에 관한 분자궤도함수 이론적 연구)

  • Lee, Ik Choon;Cho, Jeoung Ki;Lee, Hae Hwang;O, Hyeok Geun
    • Journal of the Korean Chemical Society
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    • v.34 no.3
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    • pp.239-247
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    • 1990
  • The gas-phase S_N2$ reactions can be classified into neutral bimolecular, solvated, and ionic reactions; the neutral bimolecular reaction proceeds via retention mechanism whereas the ionic reaction produces inversion products. In the reaction of solvated nucleophile with one solvent molecule, a six-center transition state (TS) is formed and the two processes i.e., retention and inversion, are found to compete with a favored path depending on the electronic effect of the nucleophile and substituents in the substrate and on the steric requirement. In the ionic reaction, the difference in the energy barrier between the two processes reduces to a small value when the substrate methyl group is made bulky, leaving ability of the leaving group is improved and at the same time the negative charge of the nucleophile is dispersed. When the reaction center atom in the $S_N2$ reaction is changed to a larger sized second row elements, the activation barrier decreases since the steric crowding in the penta-coordinated TS is relieved. However within the same row, the barrier was found to increase as the atomic size decreased. For the boron, B, the barrier height was the least since in addition to the relatively large atomic size compared to C and N, it forms tetra-coordinated TS so that the steric crowding becomes nearly negligible.

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Synthesis and Photoalignment of Soluble Polyimides with Styrylpyridine Side Groups (스티릴피리딘 곁사슬기를 가지는 용해성 폴리이미드의 합성과 광배향)

  • Kim, Jin-Woo;Kim, Min-Woo;Ahn, Deuk-Kyoon;Kim, Woo-Sik
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.207-212
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    • 2009
  • The precursor polyimide of the photoreactive polyimides(PI-SP6 and PI-SP12) was prepared from a derivative of 2, 2, 2-trifluoroethane dianhydride and 3,3'-dihydroxy-4,4'-diaminobiphenyl. PI-SP6 and PI-SP12 were then prepared by the polymer reactions of the precursor polyimide with photoreactive 2-styrylpyridine alkylene (hexylene and dodecylene) derivatives, respectively. The photoreactive polymers were soluble in organic solvents. The polymers showed the initial decomposition temperatures around $350^{\circ}C$. The glass transition temperatures of PI-SP6 and PI-SP12 were found to be $130^{\circ}C$ and $85^{\circ}C$, respectively. This result means that the latter polymer is more flexible than the former polymer. Their transmittance in the film state was 90% at $250^{\circ}C$, which indicates that the photosensitive polyimides with thermal stability have high optical transparency even at the high temperature. The respective dichroic ratios of PI-SP6 and PI-SP12 were found to be 0.01 and 0.03 at an exposure energy of $1.5\;J/cm^2$. This result suggests that the latter polymer with larger flexibility compared to the former polymer is more effective for the photoalignment.

Effect of V and Sb on the Corrosion Behavior and Precipitate Characteristics of Zr-based Alloys for Nuclear Fuel Cladding (핵연료 피복관용 Zr합금의 부식거동 및 석출물 특성에 미치는 V, Sb 첨가의 영향)

  • Jeon, Chi-Jung;Kim, Seon-Jin;Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1099-1109
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    • 1998
  • To investigate the effect of V and Sb on the corrosion behavior of Zr- based alloys, corrosion tests were performed on 6 kinds of Zr alloys in an autoclave at $360^{\circ}C$ for 100 days. The transition of the corrosion rate occurred in the sample containing 0.1wt.%V after 10 days but did not occur in the samples containing 0.2wt.%V and 0.4wt.%V. The corrosion resistance of V containing alloys increased with increasing V contents from 0.1 to 0.4wt.% and the alloys containing 0.4wt.%V showed the best corrosion resistance. In the ternary alloys containing 0.1wt.%Sb and 0.4wt.%Sb, the corrosion rate increased significantly from the short exposure time. It was observed that the optimal Sb content for corrosion resistance was 0.2wt.%. The size and volume fraction of precipitates increased with increasing V and Sb contents. The superior corrosion resistance was observed in the Zr alloy having precipitate size of 0.11-0.13$\mu\textrm{m}$. From the result of corrosion behavior and the obserbation of precipitates, the optimal size of the precipitate appear to control the electron conduction in the cathodic reaction and play an important role in maintaining a stable oxide microstructure.

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Sedimentary Facies and Environmental Changes of the Nakdong River Estuary and Adjacent Coastal Area (낙동강 하구와 주변 연안역의 표층 퇴적상 및 퇴적환경 변화)

  • KIM Seok-Yun;HA Jeong-Su
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.3
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    • pp.268-278
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    • 2001
  • To investigate sedimentary facies and environmental changes of the Nakdong River Estuary and its adjacent coastal area, the grain size analysis and measurement of organic matter, calcium carbonate, clay mineral and metallic elements were carried out for forty surface sediment samples. Based on regional distribution pattern and characteristics of the surface sediments, sedimentary facies in the study area can be divided into sand facies (TYPE I), mud facies (TYPE II) and sand-mud mixed facies (TYPE III). TYPE III is the transition of TYPE I and TYPE II in every aspects of sediment characteristics. It suggests that TYPE III may have been formed by the mixture of two different source of sediment : one derived from Nakdong River and the other resuspended fine-grained sediments from the Jinhae Bay by winnowing action during floods or storms. Among many aspects of environmental change after the construction of the Nakdong Barrage, the most significant is the increase of sand content off the sand barrier region. It could be explained by several reasons including decreased input of fine-grained sediment from river, increased hydrodynamic energy level off the sand barrier region and artificial effects such as dredging and dumping.

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Thermal and Mechanical Properties of Epoxy Composites Using Silica Powder (실리카 파우더를 이용한 에폭시 복합소재의 열적/기계적 특성)

  • Lee, Hye Ryeon;Song, JeeHye;Kim, Daeyeon;Lim, Choong-Sun;Seo, BongKuk
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.7-14
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    • 2016
  • Epoxy composites with concentrations of 5-70 wt% of silica particles were prepared in order to improve mechanical property and poor thermal stability. The mechanical and thermal properties were investigated and compared to the corresponding properties of neat epoxy composite. Furthermore, the effects of silane compound treatment on silica particles were observed by the experimental results of the tensile strength, glass transition temperature, and thermal stability of epoxy composite. Tensile strength of epoxy composites was measured by universal testing machine (UTM) and after that, the structure and morphology analysis of epoxy nanocomposites were analyzed by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). The increased solid content of CA0030 particle improved the tensile strength of epoxy/ modified composites to give 30-50 MPa. The thermal expansion coefficients (CTE) of neat epoxy resin and epoxy/silica composites measured with a thermomechanical analyzer (TMA) showed that the incorporation of silica particles was helpful to reduce the CTE of neat epoxy resin.

Quality Characteristics of Domestic Strong Wheat Flour (시판 강력분 우리밀의 품질 특성)

  • Kwak, Han Sub;Kim, Mi Jeong;Kim, Oui-Woung;Kim, Sang Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.5
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    • pp.616-621
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    • 2017
  • The objective of this study was to investigate the physicochemical properties of domestic strong wheat flour (DSWF). Three commercial DSWFs (D1, D2, and D3) were compared with imported strong wheat flour (ISWF). DSWFs had higher moisture content, crude protein content, lightness, and whiteness than ISWF. DSWFs showed lower solvent retention capacity and water absorption index than ISWF. DSWFs also showed significantly higher water solubility index than ISWF (P<0.05). Setback values by rapid visco analysis were significantly higher in D1 and D2 than in ISWF and D3, which means ISWF and D3 were better in retarding retrogradation. Differential scanning calorimetry results showed that ISWF required 6.2 J/g of energy for phase transition, whereas DSWFs needed 6.67~7.13 J/g. The farinograph results showed that ISWF had higher water absorption, longer dough stability time, and significantly higher softening of dough at 20 min than DSWF (P<0.05). Dough resistance and extensibility were higher in ISWF than in DSWFs.

EVALUATION MODEL OF GROWTH AND DEVELOPMENT IN PEDIATRIC DENTISTRY (한국인 소아의 성장 발육 평가 자료 제작에 관한 연구)

  • Kim, Young-Jae;Lee, Shin-Jae;Kim, Jung-Wook;Jang, Ki-Taeg;Lee, Sang-Hoon;Hahn, Se-Hyun;Kim, Chong-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.33 no.2
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    • pp.173-180
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    • 2006
  • Knowledge of growth and development is essential for pediatric dentistry treating growing patients. The data from the pediatric growth curve being used today does not reflect the growth transition of modern times, nor does it match the age range required for dental purposes. The present study, therefore, aims to introduce the process of producing a growth curve and growth rate curve based on data which represents a more accurate description of the present situation. The original data used in this study were from the 5th nationwide survey, SIZE KOREA 2004 study carried out by the Technology and Standards Policy Division, Department of Technology and Standards Planning, Ministry of Commerce, Industry. and Energy. Processing and rearranging the produced data with variations divided into the three quartiles and the 1st, 5th, 95th and 99th percentiles were included to produce a growth observation chart according to sex, height and weight differences. In the same way, a growth rate curve based on the geometric mean value was produced. The resulting growth charts can be used as an index for growth and development, and used for better communication between the pediatric dentist, patients or their parents.

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Effects of Port Shape on Steady Flow Characteristics in an SI Engine with Semi-Wedge Combustion Chamber (1) - Velocity Distribution (1) (반 쐐기형 연소실을 채택한 SI 기관에서 포트형상이 정상유동 특성에 미치는 영향 (1) - 유속분포 (1))

  • Kim, Hyeongsig;Ohm, Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.7
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    • pp.417-427
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    • 2016
  • This paper is the first investigation of the steady flow characteristics of an SI engine with a semi-wedge combustion chamber as a function of the port shape. For this purpose, the planar velocity profiles were measured at the 1.75B position by particle image velocimetry. The flow patterns were examined with both a straight and a helical port. Two swirls were observed up to 4 mm valve lift with the straight port and up to 2 mm with the helical one; however, only one swirl was present after these lifts. The flow characteristics changed suddenly between 4 and 5 mm lift in the straight port; on the other hand, the change with lift was gradual with the helical port - the transition points between flow regimes were different with the port shapes. In addition, the centers of the swirls were relatively far from the cylinder center so that the effect of eccentricity may not be negligible at 1.75B, regardless the shape. The eccentricity values with the straight port were especially high - over 0.5 for all lifts. Finally, real velocities were found to be much lower than those predicted by the assumption of ISM evaluation, with the profiles differing qualitatively as well.

Effect of Alcohols Toward the Transphosphatidylation Activity in Phospholipase D Catalyzed Reaction (포스포리파제 D 촉매반응에서 포스파티딜 전달반응 활성에 미치는 알코올의 영향)

  • Koh, Eun-Hie
    • Journal of the Korean Chemical Society
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    • v.54 no.2
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    • pp.208-214
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    • 2010
  • In the presence of alcohol, phospholipase D (PLD) is known to perform transphosphatidylation activity, during which the overall reaction rate of PLD increased. To elucidate the reaction mechanism of transphosphatidylation further, we investigated rate constants of transphosphatidylation reaction of the purified ${\alpha}$-type PLD from cabbage in the presence of various alcohols. The second-oder rate constants of PLD transphosphatidylation showed a large increase with the primary alcohols examined as expected. In the case of butanol we observed the second-oder rate constant of $33.33{\pm}1.33M^{-1}sec^{-1}$. This second-order rate constant of transphosphatidylation was as 400 times greater as the second-order hydrolysis rate constant of $0.078M^{-1}sec^{-1}$ which was adjusted for the water concentration. A linear free energy relationship between the $pK_a$ of alcohol and transphosphatidylation rate gives a Br${\o}$nsted slope of ${\beta}_{nu}$ = 0.12 ${\pm}$ 0.03. This small ${\beta}_{nu}$ value implicates that the transition state of break down of phosphatidyl-enzyme intermediate (E-P) is likely dissociative. Finally, a reaction mechanism of cabbage PLD is suggested on the basis of our results presented here and the histidine residue known to be located in the active site of cabbage PLD.