• Title/Summary/Keyword: Energy Fuels

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Mechanochemical Approach for Oxide Reduction of Spent Nuclear Fuels for Pyroprocessing

  • Kim, Sung-Wook;Han, Seung Youb;Jang, Junhyuk;Jeon, Min Ku;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.255-266
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    • 2021
  • Solid-state mechanochemical reduction combined with subsequent melting consolidation was suggested as a technical option for the oxide reduction in pyroprocessing. Ni ingot was produced from NiO as a starting material through this technique while Li metal was used as a reducing agent. To determine the technical feasibility of this approach for pyroprocessing, which handles spent nuclear fuels, thermodynamic calculations of the phase stabilities of various metal oxides of U and other fission elements were made when several alkaline and alkali-earth metals were used as reducing agents. This technique is expected to be beneficial, not only for oxide reduction but also for other unit processes involved in pyroprocessing.

A surrogate model for the helium production rate in fast reactor MOX fuels

  • D. Pizzocri;M.G. Katsampiris;L. Luzzi;A. Magni;G. Zullo
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3071-3079
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    • 2023
  • Helium production in the nuclear fuel matrix during irradiation plays a critical role in the design and performance of Gen-IV reactor fuel, as it represents a life-limiting factor for the operation of fuel pins. In this work, a surrogate model for the helium production rate in fast reactor MOX fuels is developed, targeting its inclusion in engineering tools such as fuel performance codes. This surrogate model is based on synthetic datasets obtained via the SCIANTIX burnup module. Such datasets are generated using Latin hypercube sampling to cover the range of input parameters (e.g., fuel initial composition, fission rate density, and irradiation time) and exploiting the low computation requirement of the burnup module itself. The surrogate model is verified against the SCIANTIX burnup module results for helium production with satisfactory performance.

Chemical Looping Combustion Characteristics of Coal and Char in a Batch Type Fluidized Bed Reactor (회분식 유동층 반응기에서 석탄과 촤의 매체순환연소 특성)

  • Ryu, Ho-Jung;Hyun, Ju-Soo;Kim, Young-Joo;Park, Yeong-Seong;Park, Moon-Hee
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.884-894
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    • 2011
  • Effects of temperature, volatile content, particle diameter and solid input weight were investigated in the batch fluidized bed reactor using OCN703-1100 particle as oxygen carrier and Roto coal and char as fuels. Two solid fuels represented the best reactivity at different temperature, $900^{\circ}C$ for Roto coal and $950^{\circ}C$ for char, respectively. However, we selected $900^{\circ}C$ as the best operating temperature because the improvement of reactivity of char at $950^{\circ}C$ was negligible. Char represented better reactivity than Roto coal because char contains low volatile than Roto coal. For both solid fuels, reactivities were improved with increasing of the particle diameter. These results were explained by solid mixing tests in a transparent fluidized bed using two char particles having different particle size ranges and OCN703-1100 particle. The bigger particle showed better solid mixing with OCN703-1100 particle, and therefore, represented better reactivity. For both solid fuels, reactivities were improved with increasing of the solid input weight within the experimental conditions of this study because the weight of coarse particles increased with the solid input weight increased, and therefore, these coarse particles can mix well with the oxygen carrier.

Patent Analysis of Oil Sands Bitumen Upgrading Technologies (오일샌드 역청 개질 기술의 특허정보 분석)

  • Lee, Ki Bong;Jeon, Sang Goo;Nho, Nam Sun;Kim, Kwang Ho;Shin, Dae Hyun;Kim, Seon Wook;Kim, Yong Heon
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.592-599
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    • 2008
  • Oil sands had not received enough attention due to high production cost. However, as oil price significantly increases, oil sands are receiving more and more interest as unconventional crude oil. The value and applicability of oil sands can be enhanced by upgrading oil sands bitumen to produce synthetic crude oil (SCO). This study analyzed 213 oil sands upgrading patents applied between 1969 and 2006 in US, Canada, Japan, Europe, and Korea. The upgrading technologies could be classified into 9 detailed technologies; hydrocracking, coking, thermal cracking, deasphalting, supercritical technology, bio-technology, hydrotreating, gasification, and others. The number of patents applied for oil sands upgrading increased after 1970, reached a maximum in the early 1980, and slowly increases again in recent years. Korea has a lack of technologies for oil sands. Therefore, the technologies for oil sands production and application, specially, upgrading technologies based on accumulated oil refinery technologies need to be developed to increase self-development ratio of energy resource.

Correlation Analysis on $CO_2$ Emission and Cost of Energy Resources and Life Cycle Assessment (에너지자원의 이산화탄소 배출량과 비용의 상관관계 분석과 전과정평가)

  • Kim, Heetae;Kim, Eun Chul;Ahn, Tae Kyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.153-153
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    • 2010
  • The world is moving towards a post-carbon society and needs clean and renewable energy for sustainable development. There are many methodological approaches which are helping this shift based on analyzed data about energy resources and which focus on limited types of energy including liquid fossil, solid fossil, gaseous fossil, and biomass (e.g. IPCC Guidelines, ISO 14064-1, WRI Protocol, etc.). We should also consider environmental impact (e.g. greenhouse gas emissions, water use, etc.) and the economic cost of the renewable energy to make a better decision. Recently, researchers have addressed the environmental impact of new technologies which include photovoltaics, wind turbines, hydroelectric power, and biofuel. In this work, we analyze the environmental impact with a carbon emission factor to present a correlation between $CO_2$ emission and the cost of energy resources standardized by the energy output. In addition, we reviewed Life Cycle Assessment (LCA) as another methodology. Researchers who are studying energy systems have ignored the impacts of entire energy systems, e.g. the extraction and processing of fossil fuels. In power sector, the assessment should include extraction, processing, and transportation of fuels, building of power plants, production of electricity, and waste disposal. Therefore LCA could be more suitable tool for energy cost and environmental impact estimation.

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