• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.85-95
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• 2024

Direct air capture (DAC) technology plays a crucial role in mitigating climate change. Reports from the International Energy Agency and climate change emphasize its significance, aiming to limit global warming to 1.5 ℃ despite continuous carbon emissions. Despite initial costs, DAC technology demonstrates potential for cost reductions through research and development, operational learning, and economies of scale. Recent advancements in high-permeance polymer membranes indicate the potential of membrane-based DAC technology. However, effective separation of CO₂ from ambient air requires membranes with high selectivity and permeability to CO₂. Current research is focusing on membrane optimization to enhance CO₂ capture efficiency. This study underscores the importance of direct air capture, evolving cost trends, and the pivotal role of membrane development in climate change mitigation efforts. Additionally, this research delved into the theoretical background, conditions, composition, advantages, and disadvantages of permeance and selectivity in membrane-based DAC.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.1
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• pp.30-39
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• 2017

Interests in fuel cell based power generation systems are on the steady rise owing to various advantages such as high efficiency, ultra low emission, and potential to achieve a very high efficiency by a synergistic combination with conventional heat engines. In this study, the performance of a hybrid system which combined a molten carbonate fuel cell (MCFC) and an indirectly fired micro gas turbine adopting carbon dioxide capture technologies was predicted. Commercialized 2.5 MW class MCFC system was used as the based system so that the result of this study could reflect practicality. Three types of ambient pressure hybrid systems were devised: one adopting post-combustion capture and two adopting oxy-combustion capture. One of the oxy-combustion based system is configured as a semi-closed type, while the other is an open cycle type. The post-combustion based system exhibited higher net power output and efficiency than the oxy-combustion based systems. However, the semi-closed system using oxy-combustion has the advantage of capturing almost all carbon dioxide.

• Journal of the Korean Society of Radiology
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• v.2 no.3
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• pp.33-35
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• 2008

In the neutron capture experiment and calculation, the neutron absorption and scattering are very important. Especially these effects are conspicuous in the resonance energy region and below the thermal energy region. In the present study, we obtained energy dependent neutron absorption ratios of natural rhodium in energy region from 0.003 to 100 eV by MCNP-4B Code. The coefficients for neutron absorption was calculated for several types of thickness. In the lower energy region, neutron absorption is larger than higher region, because of large capture cross section (1/v). Furthermore it seems very different neutron absorption in the large resonance energy region. These results are very useful to decide the thickness of sample and shielding materials.

• Nuclear Engineering and Technology
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• v.38 no.8
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• pp.803-808
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• 2006

The neutron induced nuclear cross section data for Ir-191 and Ir-193 were calculated and evaluated from unresolved resonance energy to 20MeV. The energy-dependent optical model potential parameters were determined based on the experimental data and applied up to 20MeV. A spherical optical model, a statistical model in an equilibrium energy region, and a multistep direct and multistep compound model in a pre-equilibrium energy region were used in the calculations. The direct capture model enhanced the fast neutron capture in the pre-equilibrium energy. The theoretically calculated cross sections were compared with the experimental data and the evaluated files. The calculations were found to be in good agreement with the experiment data. The evaluated cross section results were compiled with the ENDF-6 format. The fast energy results will be merged with the resonance parts to create a full evaluation library. The improvement of the neutron-induced cross section data will contribute to an increase in the efficiency of the production of Ir-192 as a radiation source.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2017.05a
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• pp.81-82
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• 2017

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.140-146
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• 2010

This paper addresses recent status and trends of carbon dioxide capture technologies using dry sorbents in the flue gas. The advantages of dry sorbent $CO_2$ capture technology are broader operating temperature range, less energy loss, less waste water, less corrosion problem, and natural properties of solid wastes. Recently, U.S.A. and Korea have been developing processes capturing $CO_2$ from real coal flue gas as well as sorbents improving sorption capacity to decrease total $CO_2$ capture cost. New class of dry sorbents have been developed such as chemisorbents with alkali metals of which material cost is low, amines physically adsorbed on silica supports, amines covalently tethered to the silica support, carbon-supported amines, polymer-supported amines, amine-containing solid organic resins and metal-organic framework. The breakthrough is needed in the materials on dry sorbents to decrease capture cost.

• Korean Chemical Engineering Research
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• v.43 no.4
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• pp.537-541
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• 2005

A bubbling fluidized bed reactor was used to study $CO_2$ capture from flue gas using a sodium-based dry regenerable sorbent, sorbA which was manufactured by Korea Electric Power Research Institute. A dry sorbent, sorbA, consists of $Na_2CO_3$ for absorption and supporters for mechanical strength. $CO_2$ capture was effective in the lower temperature range of $50-70^{\circ}C$, while regeneration occurred in the range of $120-300^{\circ}C$. To increase initial $CO_2$ removal, some amount of steam was absorbed in the sorbents before injecting simulated flue gas. It was possible to remove most $CO_2$ for 1-2 minutes at $50^{\circ}C$ and residence time of 2 seconds with steam pretreatment. Little or no reduction in initial reaction rate and capture capacity was observed in multicycle tests. The carbonated and regenerated sorbent samples were analyzed by NMR to confirm the extent of reaction. The results obtained in this study can be used as basic data for the scale-up design and operation of the $CO_2$ capture process with two fluidized bed reactors.

• Proceedings of the Korean Nuclear Society Conference
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• 2003.05a
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• pp.61.2-61.2
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• 2003

• Proceedings of the Korean Nuclear Society Conference
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• 2005.05a
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• pp.135-136
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• 2005

• Proceedings of the Korean Nuclear Society Conference
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• 1999.10a
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• pp.68-68
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• 1999