• Title/Summary/Keyword: End-forming

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Conjugated Oligomers Combining Fluorene and Thiophene Units : Towards Supramolecular Electronics

  • Leclere, Ph.;Surin, M.;Sonar, P.;Grimsdale, A.C.;Mllen, K.;Cavallini, M.;Biscarini, F.;Lazzaroni, R.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.228-228
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    • 2006
  • Conjugated oligomers, used as models for fluorene-thiophene copolymers, are compared in terms of the microscopic morphology of thin deposits and the optical properties. The AFM images and the solid-state absorption and emission spectra are interpreted in line with the structural data, in terms of the assembly of the conjugated molecules. The compound with a terthiophene central unit and fluorene end-groups shows well-defined monolayer-by-monolayer assembly into micrometer-long strip-like structures, with a crystalline herringbone-type organization within the monolayers. Polarized confocal microscopy indicates a strong orientation of the crystalline domains within the stripes. In contrast, the compound with a terfluorene central unit and thiophene end groups forms no textured aggregates. The difference in behavior between the two compounds most probably originates from their different capability of forming densely-packed assemblies of ${\pi-pi}$ interacting molecules. These assemblies are used as active elements in organic field effect transistors designed by using soft lithography technique.

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Studies on the Clostridium bovis sp. nov., the predominant species isolated from the feces of Holstein cattle (홀스타인 젖소의 분변에서 우세균종으로 분리되는 새로운 Clostridium bovis 에 관한 연구)

  • Lee, Wan-kyu
    • Korean Journal of Veterinary Research
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    • v.34 no.1
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    • pp.99-105
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    • 1994
  • Clotridium bovis sp. nov, is described on the basis of 5 strains isolated from the feces of Holstein cattle. The isolate are gram-positive, motile, strict anaerobic spore forming rods. They differ from all the validly described related species of the genus Clostridium in carbohydrate fermentation pattern, G+C mol% and DNA homologies. Acid is produced from arabinose, xylose, glucose, mannose, fructose, galactose, sucrose, maltose, cellobiose, lactose, trehalose, melibiose, raffinose, inulin and salicin. Major end products in PYFG broth are large amounts of butyric acid and lactic acid, and trace amounts of acetic and succinic acids. The G+C mol% of DNA from the type strain is 26 mol%. The type strain of Clostridium bovis is Catt $66^T$ strain.

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Charge-Transfer Complex Formation between Stilbenes and 7,7,8,8-Tetracyanoquinodimethane

  • Jin, Jung-Il;Kim, Joon-Seop;Kim, Jeong-Deuk
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.167-171
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    • 1988
  • Formation of intermolecular charge-transfer complexes between 7,7,8,8-tetracyanoquinodimethane (TCNQ) and two different series of stilbene derivatives has been studied spectroscopically at $25^{\circ}$C in 1,2-dichloroethane. The compounds of Series I include stilbene and derivatives which have fused phenyl rings on one end of the central ethylene structure and a phenyl ring on the other end. The other Series, II, is comprised of stilbenes which have various para substituents on one of the two phenyl rings. The equilibrium constant, $K_c^{AD}$ and the molar extinction coefficient, ${\varepsilon}_{\lambda}^{AD}$, were determined using the Scott equation. The values of the charge-transfer transition frequency, ${\vu}_AD$ and $K_c{AD}$ correlated well respectively with the ionization potentials of the fused rings of Series Ⅰ or of the compounds of Series II and with the values of ${\sigma}_p$, the Hammett constants of the Series II substituents. trans-4-N,N-Dimethylaminostilbene and trans-4-nitrostilbene were found to be able to participate in electron transfer reaction with TCNQ forming the corresponding anion radical, TCNQ$^-$:

A Study on the Cutting Forces and Tool Deformation when Flat-ended Pocket Machining (평엔드밀 포켓가공시 절삭력과 공구변형에 관한 연구)

  • Choi, Sung-Yun;Kwon, Dae-Gyu;Park, In-Su;Wang, Duck-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.2
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    • pp.28-33
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    • 2017
  • Recently, the operation of precision pocket machining has been studied for the high speed and accuracy in industry to increase production and quality. Moreover, the demand for products with complex 3D free-curved surface shapes has increasing rapidly in the development of computer systems, CNC machining, and CAM software in various manufacturing fields, especially in automotive engineering. The type of aluminum (Al6061) that is widely used in aerospace fields was used in this study, and end-mill down cutting was conducted in fillet cutting at a corner with end-mill tools for various process conditions. The experimental results may demonstrate that the end mill cutter with four blades is more advantageous than that of the two blades on shape forming in the same condition precise machining conditions. It was also found that cutting forces and tool deformation increased as the cutting speed increased. When the tool was located at $45^{\circ}$ (four locations), the corner was found to conduct the maximum cutting force rather than the start point of the workpiece. The experimental research is expected to increase efficiency when the economical precision machining methods are required for various cutting conditions in industry.

Research on Science DMZ scalability for the high performance research data networking (연구데이터의 고성능 네트워킹을 위한 Science DMZ 확장성 연구)

  • Lee, Chankyun;Jang, Minseok;Noh, Minki;Seok, Woojin
    • KNOM Review
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    • v.22 no.2
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    • pp.22-28
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    • 2019
  • A Science DeMilitarized Zone (DMZ) is an optimized network technology tailored to research data nature. The Science DMZ guarantees end-to-end network performance by forming a closed research network without redundant networking and security devices for the authorized researchers. Data Transfer Node (DTN) is an essential component for the high performance and security of the Science DMZ, since only transfer functions of research data are allowed to the DTN without any security- and performance-threatening functions such as commercial internet service. Current Science DMZ requires per-user DTN server installation which turns out a scalability limitation of the networks in terms of management overhead, entry barrier of the user, and networks-wise CAPEX. In order to relax the aforementioned scalability issues, this paper suggests a centralized DTN design where end users in a group can share the centralized DTN. We evaluate the effectiveness of the suggested sharable DTN design by comparing CAPEX against to that of current design with respect to the diverse network load and the state-of-the-art computing machine.

Modular Design of Analog Hopfield Network (아날로그 홉필드 신경망의 모듈형 설계)

  • Dong, Sung-Soo;Park, Seong-Beom;Lee, Chong-Ho
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.189-192
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    • 1991
  • This paper presents a modular structure design of analog Hopfield neural network. Each multiplier consists of four MOS transistors which are connected to an op-amp at the front end of a neuron. A pair of MOS transistor is used in order to maintain linear operation of the synapse and can produce positive or negative synaptic weight. This architecture can be expandable to any size neural network by forming tree structure. By altering the connections, other nework paradigms can also be implemented using this basic modules. The stength of this approach is the expandability and the general applicability. The layout design of a four-neuron fully connected feedback neural network is presented and is simulated using SPICE. The network shows correct retrival of distorted patterns.

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The Effect of the Organizational Leadership and Corporate Culture Types, ISO 9001:2000 System, the Quality Culture Formation on the Corporate Performance (리더십과 기업문화 유형, ISO 9001:2000 시스템, 품질문화 형성이 기업성과에 미치는 영향)

  • 김영수;윤재홍
    • Journal of Korean Society for Quality Management
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    • v.32 no.2
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    • pp.37-58
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    • 2004
  • This study examines the effects of ISO 9001:2000 Quality Management System(QMS). Before accrediting it, it is affected by the top management leadership and corporate culture. After finishing the accreditation, some companies form quality culture, but some companies do not. That affects the corporate performance. If quality culture forms, companies performance will be good. But if not, companies performance will be bad. The accreditation of ISO QMS is not the end goal for the companies but forming the quality culture will enhance the corporate performance.

Demonstration of Adaptive Analogue Beam Forming in the E-Band

  • Dyadyuk, Val;Stokes, Leigh;Nikolic, Nasiha;Weily, Andrew R.
    • Journal of electromagnetic engineering and science
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    • v.10 no.3
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    • pp.138-145
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    • 2010
  • In this paper, we report the test results of a small-scale prototype that implements an analogue-beam-formed phased antenna array in the E-band. A four-channel dual-conversion receive RF module for 71~76 GHz frequency band has been developed and integrated with a linear end-fire antenna array. Measured performance is very close to the simulated results. An ad-hoc wireless communication system has also been demonstrated. Low BER was measured for an 8PSK data stream at 1.5 Gbps with the receive array beam formed in the direction of arrival of the transmitted signal. To our knowledge this is the first steerable antenna array reported to date in the E-band.

Expert System for Process Design of Cold Forging with Redesigning Scheme (재설계 기능을 갖는 냉간단조 공정설계용 전문가시스템 개발)

  • 김홍석;임용택
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.8
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    • pp.2039-2052
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    • 1994
  • In this study, an expert system for multi-stage cold forging process design of axisymmetric parts is developed. The available geometries are axisymmetric shape and cylinder with a hold in one end. The overall system is composed of knowledge-based system for process sequence design, output module interfaced with CAD system and material data-base. In the developed system, designed process can be modified in order to reduce the number of processes and make the distribution of forming load be almost equal at various deforming stages within the machine capacity. After process sequence design is completed, results can be stored as a text file or a commercial CAD system file. The capabilities of the developed system are illustrated through various examples of process design.

The Impact of Information Systems Integration on Organization

  • Juhn, Sung-Hyun
    • Asia pacific journal of information systems
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    • v.7 no.2
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    • pp.225-266
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    • 1997
  • A Causal Transition Model of the IT impact on organization is proposed. The model is based upon the premise that the IT impact is a multi-phase, multi-realm phenomenon, and that the IT impact in one organizational realm logically transpires to another realm, thus forming complex causal webs among them. Two exploratory research studies, the one qualitative and the other quantitative, were conductea to validate the model in a setting involving major structural reorganization of the organizations' IT function. The research results provide support for the general theory structure of the model. The findings include: ⅰ) the IT impact manifests on multiple organizational realms, with different degrees of strength, ⅱ) the impact on the realms follow a particular causal transition path among them, and ⅲ) the IT impact manifests on and through the information processing aspect of work. The results, however, indicate that people's perception of the IT impact is strongly mitigated by the IT relevance of work, and that the organization is affected as much by the structural arrangement surrounding and accompanying the IT as by the technology itself, suggesting that the IT impact is an organizational phenomenon as well as a technological phenomenon. The implications of the research results are discussed at the end.

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