• 한국분무공학회지
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• 제19권2호
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• pp.55-63
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• 2014

Pyrolysis oil (PO), also known as Bio crude oil (BCO), has the potential to displace significant amounts of fuels that are currently derived from petroleum sources. PO has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of PO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the PO. One of the easiest way to adopt PO to diesel engine without modifications is emulsification of PO with the fuels that has higher cetane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel. Thus, to stabilize a homogeneous phase of diesel-PO blends, a proper surfactant should be used. In this study, a DI diesel engine operated with diesel and diesel-PO emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by diesel-PO emulsions were examined. Results showed that stable engine operation was possible with the emulsions and engine output power was comparable to diesel operation.

• 대한기계학회논문집B
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• 제39권3호
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• pp.237-243
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• 2015

본 논문은 에멀젼연료(Diesel/$H_2O_2$)에 있어 과산화수소의 혼합비가 혼합연료 액적증발 및 분무거동 특성에 미치는 영향을 연구하였다. 연료혼합을 위한 계면활성제는 span 80, tween 80을 9:1로 혼합하여 에멀젼연료 총 부피의 3%로 고정 혼합하였다. 또한 과산화수소의 혼합비율은 계면활성제의 혼합비를 고려하여 EF (Emulsified Fuel)0, EF2, EF12, EF22, EF32 및 EF42로 설정하였다. 에멀젼연료 액적의 증발특성을 관찰하기 위해 가열판에 액적 방울을 투하시켜 액적이 증발하는 현상을 산란광 및 쉴리렌기법을 통하여 촬영하였다. 또한 혼합비 변화에 따른 혼합연료의 분무거동특성을 해석하기 위하여 혼합연료 EF0~EF22를 선택하여 $150^{\circ}C$로 유지된 정적용기에서 증발자유분무 거동해석 실험을 실시하였다. 그 결과 과산화수소의 혼합비율이 EF0보다 높은 EF22 에멀젼연료의 자유분무성장이 연료 속에 혼합된 과산화수소의 증발촉진으로 인하여 보다 신속하였다.

• 한국분무공학회지
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• 제8권2호
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• pp.38-45
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• 2003

This study was carried on the combustion characteristics of a pure light oil and emulsified fuels at high-pressure injection in a spray combustion installation, The volume fractions of water in an emulsion were varied up to 30% and the injection pressures were 7.5, 100, 200, and $300kg_f/cm^2$. The concentrations of NOx and the average temperatures of flame were measured. And Images of OH radical using ICCD camera and instantaneous schlieren photography of flames were photographed. It was found that the temperature distribution of axial distance in the emulsified fuels was increased in the upstream and decreased in the down stream. The temperature distribution of radial distance was high at the peripheral regions of the spray in the upstream and at the central regions of spray in the downstream, The intensity of OH radical was denser at the water content 10% than at the pure light oil over the injection pressure $200kg_f/cm^2$.

• 한국자동차공학회논문집
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• 제20권5호
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• pp.102-112
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• 2012

The vast stores of biomass available in the worldwide have the potential to displace significant amounts of fuels that are currently derived from petroleum sources. Fast pyrolysis of biomass is one of possible paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO), also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is emulsification of BCO with diesel and bio diesel. In this study, a diesel engine operated with diesel, bio diesel (BD), BCO/diesel, BCO/bio diesel emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by BCO emulsions were examined. Results showed that stable engine operation was possible with emulsions and engine output power was comparable to diesel and bio diesel operation. However, in case of BCO/diesel emulsion operation, THC & CO emissions were increased due to the increased ignition delay and poor spray atomization and NOx & Soot were decreased due to the water and oxygen in the fuel. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion and clogging especially in the injection system.

• 대한기계학회논문집B
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• 제26권12호
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• pp.1756-1762
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• 2002

To effectively meet current regulations on the exhaust emissions of diesel engine required to control the deterioration of air pollution in the whole world, this study is to investigate the effects of water induction through the air intake system on the characteristics of combustion and exhaust emissions in IDI diesel engine. A method fur supplying water through the air intake system to reduce the exhaust emissions has been considered with other methods such as water introduction in the form of water-in-fuel emulsion or water injection directly into the combustion chamber, but it has not been studied about the effects of water on the combustion concepts and the characteristics of exhaust emissions in detail until now. In this study, the formation of NOx was significantly suppressed by decreasing the gas peak temperature during the initial combustion process because the water play a role as a heat sink during evaporating in the combustion chamber, but the smoke was slightly increased by increasing water amount.

• 항공우주시스템공학회지
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• 제13권5호
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• pp.39-48
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• 2019

회전-고정자 혼합기 내의 난류 유동은 고속으로 회전하는 회전자와 고정자의 상호작용에 의해 발생되는 전단특성을 기반으로 한다. 본 연구에서는 유화연료 관련 회전-고정자 혼합기 시제품 모델에서 회전자와 고정자간의 상호작용에 의한 비정상상태 유동 특성 분석을 ANSYS FLUENT $k-{\varepsilon}$ (RKE) 난류 모델을 MRF 및 SMM에 적용하여 수행하였다. 회전자와 고정자의 경계에서 발생하는 유동 입자들의 거동과 전단 특성 그리고 설계 파라미터에 따른 속도분포와 난류와류소산 등의 경향을 전산유체역학 해석을 통해 예측 비교하여 모델의 효율성을 검증하였다.

• 한국자동차공학회논문집
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• 제22권5호
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• pp.116-125
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• 2014

Pyrolysis oil (PO), derived from biomass through fast pyrolysis process have the potential to displace significant amounts of petroleum fuels. The PO derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine is very limited due to its poor properties like low energy density, low cetane number, high acidity and high viscosity of PO. Therefore, one of the easiest way to adopt PO to diesel engine without modifications is blended with other fuels that have high centane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel or biodiesel. Thus, to stabilize a homogeneous phase of diesel/biodiesel-PO blends, a proper surfactant should be used. Nevertheless, PO which was produced from different biomass type have varied characteristics and this complicates the selection of a suitable additive for a specific PO-diesel emulsion. In this regard, a more simple approach such as the use of a co-solvent like ethanol or butanol to induce a more stable phase of the PO-diesel mixture could be a promising alternative. In this study, a diesel engine operated with diesel/biodiesel-PO-butanol blends was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine were examined under the engine loads of IMEP 0.2 ~ 0.8MPa.

• 방사성폐기물학회지
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• 제9권1호
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• pp.1-11
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• 2011

에멀션 기반의 계면활성제를 이용한 주형합성법을 이용하여 산촉매로서 염산과 실리카의 전구체인 테트라에톡시실란을 사용함으로써 메조다공성 실리카 마이크로스피어를 합성하였다. 테트라에톡시실란의 농도 증가에 의해 구형의 입자 형태가 파괴되었고, 기공구조도 크게 변하였다. 산촉매 농도 증가에 의한 구형의 입자형태 파괴 현상은 적었지만 상대적으로 작은 크기의 구형의 마이크로입자가 더 많이 생성되었다. 하지만, 산성조건에서 입자들 간의 강한 응집현상이 나타남에 따라 낱개의 분리되어 있는 단일입자를 얻기 위해서는 초음파 등의 후처리 과정이 필요하였다.

• 한국건설순환자원학회논문집
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• 제6권3호
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• pp.199-206
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• 2018

아스팔트의 재활용 기술은 화석연료 감소, 탄소 저감, 포장 성능 개선 등의 장점으로 인해 지난 20년간 선진국의 도로 건설 및 유지관리를 위해 개발되고 적용되고 있다. 상온 재생 아스팔트 혼합물은 상온에서 폐아스콘 순환골재를 물과 유화 아스팔트와 함께 혼합하는 역청재료이다. 본 논문은 폐아스콘 순환골재 혼입율에 따라 알칼리 활성화 채움재를 사용한 상온 재생 아스팔트 혼합물의 특성을 검토하고자 하였다. 그 결과 폐아스콘 순환골재의 혼입율이 증가할수록 상온 재생 아스팔트 혼합물의 마샬 안정도가 감소하고 공극률이 증가하였다. 또한, GR에서 정하고 있는 상온 재생 아스팔트 혼합물의 입도 기준을 모든 골재 혼합 조건에서 만족하였다.

• 자원리싸이클링
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• 제13권4호
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• pp.32-38
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• 2004

중유의 대체연료로서 관심을 받고있는 오리멀젼회로부터 바나듐을 회수하기 위한 기초연구로서 오리멀젼회의 물성과 침출특성에 관한 연구를 수행하였다. 오리멀젼회는 16%의 바나듐, 4%의 니켈 그리고 9%의 황을 함유하고 있으며 $d_{50}$이 5.9$mu extrm{m}$로 미세한 분말이었다. 오리멀젼회 중의 금속성분이 황산염 형태로 존재하기 때문에 바나듐은 수 침출이 용이하고 침출시간도 10분 이하로 짧았다. 수침출 시 반응온도가 높으면 침출율이 감소하는데 이는 V(V)이 가수분해되어 $V_2$$O_{5}$로 침전되기 때문이다. 한편 황산을 첨가하면 바나듐의 침출율을 높일 수 있었다. 바나듐의 선택적 침출을 위한 알카리 침출의 경우 침출율을 높이기 위하여는 산화제의 사용이 필요하며 과산화수소가 적당하였다.