• 제목/요약/키워드: Emission wavelength

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Excimer and Aggregate Formations in Poly(fluorene)s

  • Lee, Jeong-Ik;Lee, Victor Y.;Miller, Robert D.
    • ETRI Journal
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    • v.24 no.6
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    • pp.409-414
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    • 2002
  • This paper investigates the absorption and emission changes in poly(di-n-hexylfluorene)s. We prepared the poly(di-n-hexylfluorene)s end capped with 2-bromofluorene, 2-bromo-9,9-di-n-hexylfluorene, and 9-bromoanthracene through Ni (0) mediated polymerization. In addition, we also synthesized a structurally distorted copolymer of 2,7-dibromo- 9,9-di-n-hexylfluorene and 9,9-bis(4-bromophenyl) fluorene end capped with 2-bromofluorene through the same polymerization method. The absorption and emission changes of these polymers between before and after thermal annealing in a nitrogen atmosphere clarify the role of aggregate/excimer formation in poly(fluorene)s. The large absorption changes must be attributed to aggregate formation (ground state interaction), which causes only a slight red shift of the vibronically structured emission bands. We assign the additional long wavelength emission as an excimer band (excited state interaction), which is preferably formed at chain ends.

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IGRINS Exposure Time Calculator

  • Le, Huynh Anh Nguyen;Pak, Soojong;Sim, Chae Kyung;Jaffe, Daniel T.
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.62.1-62.1
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    • 2013
  • We present the Exposure Time Calculator of IGRINS (Immersion Grating Infrared Spectrograph). The noises of IGRINS and the simulated emission line can be calculated from the combination of Telluric background emission and absorptions, the emission and transmission of the telescope and instrument optics, and the dark noise and the read noise of the infrared arrays. For the atmospheric transmissions, we apply the simulated spectra depending on the Precipitable Water Vapor (PWV) values. In case of calculation of noises, the user needs to input the expected target magnitude, the weather conditions, and the desired exposure time. In addition to the simulated emission line, the parameters of rest wavelength, line-flux, Doppler shift and line-width are needed. The output would be the expected signal-to-noise for each spectral resolution element. The source-code of IGRINS-ETC v2.1.1 is available to be downloaded on the World Wide Web.

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Measurement of Electrical Insulating Oil Oxidation by Evaluating the UV Fluorescence Emission Ratio (자외선 형광 방출비 평가에 의한 전기 절연유의 산화측정)

  • Wicaksono, Britantyo;Kong, Hosung;Han, Hung-Gu
    • Tribology and Lubricants
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    • v.29 no.1
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    • pp.51-55
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    • 2013
  • In this work, a new fluorescence emission measurement technology was introduced and experimentally compared with other measurement methods, such as the titration method and IR spectroscopy, to validate it for the oil oxidation measurement of electrical insulating oil. The oxidation characteristics of insulating oil were found to be fairly represented by the titration method and IR spectroscopy, and the results are comparable to a change in the fluorescence emission ratio that is defined as the shift in fluorescence intensity in the measured wavelength range. The result also shows that by the measurement of fluorescence emission ratio, it is possible to detect the oxidation of oil relatively earlier than by other methods. This study suggests that the developed technology can provide sufficient information for evaluating the insulating oil quality, and that the developed FER sensor can be used as an effective condition monitoring device of electrical insulating oil oxidation.

Optically Pumped Stimulated Emission from Column-III Nitride Semiconductors. (III족 질화물반도체의 광여기 유도방출)

  • 김선태;문동찬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.50-53
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    • 1994
  • In this study. we report the properties of optically pumped stimulated emission at room temperature (RT) from column-III nitride semiconductors of GaN, GaInN, AlGaN/GaN double hetero-structure (DH) and AlGaN/GaInN DH which grown by low pressure metal-organic vapor phase epitaxy on sapphire substrate using an AIN buffer-layer. The peak wavelength of the stimulated emission at RT from AlGaN/GaN DH is 370nm and the threshold of excitation pumping power density (P$\_$th/) is about 89㎾/$\textrm{cm}^2$, and they from AlGaN/GaInN DH are 403nm and 130㎾/$\textrm{cm}^2$, respectively. The P$\_$th/ of AlGaN/GaN and AlGaN/GaInN DHs are lower than the bulk materials due to optical confinement within the active layers of GaN and GaInN. The optical gain and the polarization of stimulated emission characteristics are presented in this article.

UV Emission Characterization of ZnO Thin Films Depending on the Variation of Oxygen Pressure (분위기 산소압변화에 따른 ZnO박막의 UV발광 특성분석)

  • Baek, Sang-Hyeok;Lee, Sang-Yeol;Jin, Beom-Jun;Im, Seong-Il
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.2
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    • pp.103-106
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    • 2000
  • ZnO is a wide-bandgap II-IV semiconductor and has a variety of potnetial applications. ZnO exhibits good piezoelectric, photoelectric and optical properties, and is a good candidate for an electroluminescence device. ZnO films have been deposited on (001) sapphire by PLD technique. Nd:YAG pulsed laser was operated at a wavelength of $\lambda=355nm$. The ZnO films were deposited at oxygen pressures from base to 500 mTorr. The substrate temperatures was increased from $200^{\circ}C\; to\;700^{\circ}C$ films showed strong UV emission by increasing the partial oxygen pressure. We have investigated the relationship between partial oxygen pressure and the intensity of UV emission.

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Recent Progress on Voltage Drop Compensation in Top Emission Organic Light Emitting Diodes (OLED)

  • Jeong, Byoung-Seong
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.1
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    • pp.49-54
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    • 2020
  • The voltage drop due to the thin cathode film at the large size top emission OLED panel was successfully compensated with making electrical contact between thin cathode and anode auxiliary electrode by 355nm wavelength of laser. It was found that the luminance uniformity dramatically increased from around 15% to more than 80% through this electrical compensation between thin cathode and anode auxiliary electrode. Moreover, the removing process for EL materials on the anode auxiliary electrode process by laser was very reliable and stable. Therefore, it is thought that the EL removal method using laser to make electrical contacts is very appropriate to mass production for such a large size top emission OLEDs to obtain high uniformity of luminance.

A Compact Tunable VCSEL and a Built-in Wavelength Meter for a Portable Optical Resonant Reflection Biosensor Reader

  • Ko, Hyun-Sung;Kim, Bong-Kyu;Kim, Kyung-Hyun;Huh, Chul;Kim, Wan-Joong;Hong, Jong-Cheol;Park, Seon-Hee;Yang, Seong-Seok;Jang, Ho-Jin;Sung, Gun-Yong
    • Journal of the Optical Society of Korea
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    • v.14 no.4
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    • pp.395-402
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    • 2010
  • This study reports a portable and precision photonic biosensor reader that can measure the concentration of a particular antigen using an optical resonant reflection biosensor (ORRB). To create a compact biosensor reader, a compact tunable vertical-cavity surface-emitting laser (VCSEL) and a compact built-in wavelength meter were manufactured. The wavelength stability and accuracy of the compact built-in wavelength meter were measured to be less than 0.02 nm and 0.06 nm, respectively. The tunable VCSEL emission wavelength was measured with the compact built-in wavelength meter, it has a fast sweep time (~ 10 seconds) and a wide tuning range (> 4 nm) that are sufficient for biosensor applications based on ORRB. The reflection spectrum of a plastic based ORRB chip was measured by the fabricated portable photonic biosensor reader using the VCSEL and wavelength meter. Although the reader is the size of a palmtop device, it could make a precise measurement of the peak wavelength on equal terms with a conventional bulky optical spectrometer.

Characteristic ependences of High Power Semiconductor Laser on AR Coating (AR Coating에 따른 고출력 반도체 레이저의 특성변화)

  • 오윤경;곽계달
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.11
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    • pp.29-34
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    • 1995
  • Mirror coating is applied to laser facets to improve properties of edge emitting laser diodes. In this experiment, InGaAsP/GaAs high power laser diodes were studied with respect to different degrees of anti-reflective coating. Sputterred $Al_{2}$O$_{3}$ was used as the coating material and the HR coating was kept constant at 90%. Threshold current density, differential quantum efficiency, emission wavelength and the operating current at 500mW were measured for a range of AR coating and compared with theoretically calculated values; that showed good agreements. Precise wavelength control is important for laser diodes for solid state pumping because of small absorption bandwidth. In addition, since these lasers operate under CW condition, a lowest possible operating current for a given power is desired in order to minimize the heat produced. From the results of this experiment, we were able to obtain a optimum range of AR coatings for minimum operating current. The wavelength can be varied up to 4nm within this range.

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Qualitative Analysis of the Component Materials of Nuclear Power Plant Using Time-Resolved Laser Induced Breakdown Spectroscopy (시간분해 레이저 유도 파열 분광분석에 의한 원자력발전소 계통재질의 성분 정성분석)

  • Chung, Kun-Ho;Cho, Yeong-Hyun;Lee, Wanno;Choi, Geun-Sik;Lee, Chang-Woo
    • Analytical Science and Technology
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    • v.17 no.5
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    • pp.416-422
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    • 2004
  • Time-resolved laser induced breakdown spectroscopy (TRELIBS) has been developed and applied to the qualitative analysis of the component materials of nuclear power plant. The alloy samples used in this work were carbon steels (A106 Gr. B; A336 P11; A335 P22), stainless steels (type 304; type 316) and inconel alloys (Inconel 600; Inconel 690; Inconel 800). Carbon steels can be individually distinguished by the intensity ratio of chromium to iron and molybdenum to iron emission lines observed at the wavelength raging from 485 to 575 nm. Type 316 stainless steel can be easily differentiated from type 304 by identification of the molybdenum emission lines at an emission wavelength ranging from 485 to 575 nm: type 304 does not give any molybdenum emission lines, but type 316 does. The inconel alloys can be individually distinguished by the intensity ratio of Cr/Fe and Ni/Fe emission lines at the wavelength raging from 420 to 510 nm. TRELIBS has been proved to be a powerful analytical technique for direct analysis of alloys due to its non-destructivity and simplicity.

Emission Characteristics of Blue Fluorescence Tandem OLED with Materials of CGL (CGL의 재료에 따른 청색 형광 Tandem OLED의 발광 특성)

  • Kwak, Tea-Ho;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.47 no.4
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    • pp.210-214
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    • 2014
  • We investigated emission characteristics of tandem organic light emitting devices (OLEDs) with p-type materials as charge generation layer. The tandem OLEDs were fabricated by using $MoO_x$, $WO_x$, C60 and HATCN as p-type material or not using p-type material for charge generation. When HATCN was used as p-type material, it showed high current density at low applied voltage, but increase of efficiency was small because of charge unbalance in emitting layer. In case of tandem OLED not using p-type material, applied voltage increased remarkably because of difficulty of hole injection. In case of $MoO_x$, $WO_x$ or C60 as p-type material, current emission efficiency increased greatly. In particular, current emission efficiency of tandem OLED using $MoO_x$ as p-type material increased up to 3 times than current emission efficiency of single OLED. The Commission Internationale de l'Eclairage (CIE) 1931 color coordinates were changed by overlapping of 504 nm emission wavelength. As a result, emission efficiency of tandem OLED improved compared with single OLED, but driving voltage also increased by increase of organic layer thickness.