• Title/Summary/Keyword: Emission wavelength

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Preparations of (Yl-xGdx)2O3:Eu3+ Phosphors Particles by. Solvothermal Synthesis Using the 2-Methoxy Ethanol (2-메톡시에탄올을 사용한 용매열 합성법에 의해 합성되어진 (Yl-xGdx)2O3:Eu3+ 형광체입자)

  • Shin, Su-Cheol;Cho, Tae-Hwan
    • Korean Journal of Materials Research
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    • v.13 no.8
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    • pp.537-542
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    • 2003
  • ($Y_{l-x}$ $Gd_{x}$ )$O_2$$_3$: $Eu^{ 3+}$ red phosphors were prepared with the solvothermal synthesis using the 2-methoxy-ethanol solvents and the emission intensity was investigated that applied with the 254 nm wavelength and the maximum excitation wavelength for energy source. The used solvents for the solvothermal synthesis were made of nitrate salt solutions of Y, Gd and Eu. These solutions dropped in autoclave have be reacted with the solvothermal synthesis at $200^{\circ}C$ for 5hrs and the red phosphors prepared here in were showed the pure cubic phase after annealing at $1000∼1200^{\circ}C$. The brightness of ($Y_{l-x}$ $Gd_{x}$)$_2$$O_3$: $Eu^{3+}$ phosphors particles was increased as an increase of Gd ratio. The maximum excitation wavelengths of ($Y_{l-x}$ $Gd_{x}$ )$_2$$O_3$: $Eu^{3+}$ / phosphors particles were increased according to increasing Gd ratio from 253 nm to 259 nm wavelength. The maximum emission intensity of $Gd_2$$O_3$: $Eu^{3+}$ (Y/Gd = 1/0) phosphors particles under UV 259 nm was found to be higher than the commercial product of $Y_2$$O_3$: $Eu^{3+}$ phosphors.

Preparation and Characterization of Swallow-Tail Terrylene Bisimide as Organic Phosphor (Swallow-Tail Terrylene Bisimide 적색 유기 형광체 제조 및 특성 연구)

  • Jung, Sung Bong;Jeong, Yeon Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.194-200
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    • 2020
  • Perylene bisimide derivatives are developed for red organic phosphor because of their advantages, such as excellent luminous efficiency and high thermal stability. Despite these advantages, they have poor solubility characteristics in organic solvents and short emission wavelength as red organic phosphor for hybrid light-emitting diodes (LEDs). In this study, we prepared terrylene bisimide using a coupling reaction and swallow-tail imide group, which has excellent solubility. The structures and properties of swallow-tail terrylene bisimide (9C) were analyzed using 1H-nuclear magnetic resonance (1H-NMR), Fourier-transform infrared (FT-IR), UV/Vis spectroscopy, and thermal gravimetric analysis (TGA). The maximum absorption wavelength of (9C) in the UV/Vis spectrum was 647 nm, and the maximum emission wavelength was 676 nm. In the TGA, (9C) demonstrated good thermal stability with less than 5 wt% weight loss up to 415℃. In the solubility test, (9C) has a good solubility of more than 5 wt% in chloroform and dichloromethane. When the compounds (9C) were mixed with PMMA (polymethly methacrylate), the films showed peaks at 680 nm in the PL spectra. The results verify the suitability of (9C) as a red organic phosphor for hybrid LEDs.

Synthesis of Organic EL Materials with Cyano Group and Evaluation of Emission Characteristics in Organic EL Devices (시안기를 가진 유기 EL 물질들의 합성 및 유기 EL 소자에서의 발광특성평가)

  • Kim, Dong Uk
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.315-320
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    • 1999
  • Novel electroluminescent materials, polymer material, PU-BCN and low molar mass material, D-BCN with the same chromophores were designed and synthesized. A molecular structure of chromophore was composed of bisstyrylbenzene derivative with cyano groups as electron injection and transport and phenylamine groups as hole injection and transport. Device structures with PU-BCN and D-BCN as an emission layer were fa-bricated, which were a single-layer device(SL), Indium-tin oxide(ITO)/emission layer/MgAg, and two kinds of double-layer devices which were composed of ITO/emission layer/oxadiazole derivative/MgAg as a DL-E device and ITO/triphenylamine derivative/emission layer/MgAg as a DL-H device. The two emission materials, PU-BCN and D-BCN with the same emission-chromophore were evaluated as having excellent performance of charge injection and transport and revealed almost the same emission characteristics in high current density. EL emission maximum peaks of two material were detected at about 640 nm wavelength of red emission region.

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Effects of $ B_2O_3$ composition for the photoluminescence and after-glow charcteristics of $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphors ($SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ 장잔광 형광체에 있어서 발광 및 장잔광특성에 미치는$B_2O_3$의 영향)

  • 이영기;엄기석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.3
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    • pp.123-128
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    • 2004
  • Both photoluminescence and the long-phosphorescent properties for $SrAl_2O_4$ : Eu$^{+2}$, $Dy^{+3}$ phosphor powder synthesized by the solid phase reaction were investigated as a function of $B_2O_3$ composition (0-10 wt%). The highest emission wavelength (520nm) of photoluminescence spectra was not affected by $B_2O_3$concentration. The highest emission intensity was obtained by the concentration of 3 wt% $B_2O_3$.After the removal of the Xenon lamp excitation (360nm), also, the excellent long-phosphorescent property of the phosphors was obtained by the concentration of 3 wt% $B_2O_3$ although the decay times for all phosphors decreased exponentially.

SMALL-SCALE STRUCTURE OF THE ZODIACAL DUST CLOUD OBSERVED IN FAR-INFRARED WITH AKARI

  • Ootsubo, Takafumi;Doi, Yasuo;Takita, Satoshi;Matsuura, Shuji;Kawada, Mitsunobu;Nakagawa, Takao;Arimatsu, Ko;Tanaka, Masahiro;Kondo, Toru;Ishihara, Daisuke;Usui, Fumihiko;Hattori, Makoto
    • Publications of The Korean Astronomical Society
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    • v.32 no.1
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    • pp.63-65
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    • 2017
  • The zodiacal light emission is the thermal emission from the interplanetary dust and the dominant diffuse radiation in the mid- to far-infrared wavelength region. Even in the far-infrared, the contribution of the zodiacal emission is not negligible at the region near the ecliptic plane. The AKARI far-infrared all-sky survey covered 97% of the whole sky in four photometric bands with band central wavelengths of 65, 90, 140, and $160{\mu}m$. AKARI detected the small-scale structure of the zodiacal dust cloud, such as the asteroidal dust bands and the circumsolar ring, in far-infrared wavelength region. Although the most part of the zodiacal light structure in the AKARI far-infrared all-sky image can be well reproduced with the DIRBE zodiacal light model, there are discrepancies in the small-scale structures. In particular, the intensity and the ecliptic latitude of the peak position of the asteroidal dust bands cannot be reproduced precisely with the DIRBE models. The AKARI observational data during more than one year has advantages over the 10-month DIRBE data in modeling the full-sky zodiacal dust cloud. The resulting small-scale zodiacal light structure template has been used to subtract the zodiacal light from the AKARI all-sky maps.

luminescent Characteristics of $Ca_{1-x}$Sr$_{x}$S:CuCl Thin-film Electroluminescent(TFEL) Device (Ca$_{1-x}$Sr$_{x}$S:CuCl 박막 전계발광소자의 발광 특성)

  • 이순석;김미혜
    • The Journal of the Korea Contents Association
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    • v.2 no.3
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    • pp.146-151
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    • 2002
  • The $Ca_{1-x}$Sr$_{x}$S:CuCl TFEL devices were fabricated by electron-beam deposition system and luminescent characteristics of the TFEL devices were studied. The SrS and CaS powders were mixed to form $Ca_{1-x}$Sr$_{x}$S host materials and 0.2 at% of CuCl was added as the activator. The luminance(lao) and peak emission wavelength of CaS:CuCl TFEL devices were 9.5 cd/m$^2$ and 492 nm, respectively. The luminance(L$_{30}$) and peak emission wavelength of SrS:CuCl TFEL devices were 633 cd/m$^2$ and 500 nm, respectively. It seems that the addition of CaS into the SrS host material generates blue shift of the EL emission characteristics but reduces the luminance and the luminous efficiency of the $Ca_{1-x}$Sr$_{x}$S:CuCl TFEL devices drastically.

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Multi-wavelength Study of Blazars Using Variability as a Tool

  • Baliyan, Kiran S.;Kaur, Navpreet;Chandra, Sunil;Sameer, Sameer;Ganesh, Shashikiran
    • Journal of Astronomy and Space Sciences
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    • v.33 no.3
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    • pp.177-183
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    • 2016
  • Active galactic nuclei (AGN) are too compact to be resolved by any existing optical telescope facility, making it difficult to understand their structure and the emission processes responsible for their huge energy output. However, variability, one of their characteristic properties, provides a tool to probe the inner regions of AGN. Blazars are the best candidates for such a study, and hence a considerable amount of effort is being made to investigate variability in these sources across the electromagnetic spectrum. Here, using the Mt. Abu infrared observatory (MIRO) blazar monitoring program, we present intra-night, inter-night, and long term aspects of the variability in S5 0716+71, 3C66A, and OJ 287. These stars show significant variability on short (a few tens of mins, to a few hours, to a few days) to long term (months to years) timescales. Based on the light travel time argument, the shortest variability timescales (micro-variability) provide upper limits to the size of the emission region. While S5 0716 shows a very high duty cycle of variability (> 80 %), 3C66A shows a much lower intra day variability (IDV) duty cycle (< 20 %). All three show rapid variations within 2.5 to 3.5 hr, which, perhaps, are generated near the vicinity of black holes. Assuming this, estimates of the masses of the black holes are made at ~109, 8×108, and 2.7×109 M for S5 0716+71, 3C66A, and OJ 287, respectively. Multi-wavelength light-curves for the blazar PKS 1510-089 are discussed to infer the emission processes responsible for the recent flaring episodes in this source.

Fabrication and Characterization of Blue OLED using GDI Host-Dopant Phosphors (GDI 호스트-도펀트 형광체를 이용한 청색 OLED의 제작과 특성 평가)

  • Jang, Ji-Geun;Shin, Se-Jin;Kang, Eui-Jung;Kim, Hee-Won;Chang, Ho-Jung;Oh, Myung-Hwan;Kim, Young-Seop;Lee, Jun-Young;Gong, Myoung-Seon;Lee, Young-Kwan
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.253-256
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    • 2006
  • The blue emitting OLEDs using GDI host-dopant phosphors have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)- triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, blue color emission layer was deposited using GDI602 as a host material and GDI691 as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/GDI602:GDI691/Alq3/LiF/Al were obtained by in-situ deposition of Alq3, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Blue OLEDs fabricated in our experiments showed the color coordinate of CIE(0.14, 0.16) and the maximum power efficiency of 1.1 lm/W at 11 V with the peak emission wavelength of 464 nm.

Fabrication and Characterization of Yellow OLED using GDI602:Rubrene(10%) Material (GDI 602/Rubrene을 이용한 황색 OLED의 제작과 특성 분석)

  • Jang, Ji-Geun;Kim, Hee-Won
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.4
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    • pp.71-75
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    • 2006
  • The yellow emitting OLED using GDI602:Rubrene(10%) material has been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenyl-amine] as a hole injection material and NPB[N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl -4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, yellow emission material was deposited using GDI602 as a host material and Rubrene(10%) as a dopant. Finally, small molecular OLED with the structure of $ITO/2-TNATA/NPB/GDI602:Rubrene(10%)/Alq_{3}/LiF/Al$ was obtained by in-situ successive deposition of $Alq_{3}$, LiF and Al as the electron transport material, electron injection material and cathode. The yellow OLED fabricated in our experiments showed the color coordinate of CIE(0.50, 0.49), the luminance of $2300\;Cd/m^{2}$ and the power efficiency of 0.7 lm/W at 10 V with the peak emission wavelength of 562 nm.

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Fabrication and Characterization of Blue OLED using TMP-BiP Host and DJNBD-1 Dopant (TMP-BiP 호스트와 DJNBD-1 도펀트를 이용한 청색 OLED의 제작과 특성평가)

  • Chang, Ji-Geun;Ahn, Jong-Myoung;Shin, Sang-Baie;Chang, Ho-Jung;Gong, Su-Choel;Shin, Hyun-Kwan;Gong, Myung-Sun;Lee, Chil-Won
    • Journal of the Semiconductor & Display Technology
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    • v.6 no.2 s.19
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    • pp.19-23
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    • 2007
  • The blue emitting OLEDs using TMP-BiP[(4'-Benzoylferphenyl-4-yl)phenyl-methanone-Diethyl(biphenyl-4-ymethyl) phosphonate] host and DJNBD-1 dopant have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4"-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium tin oxide)/glass substrate by vacuum thermal evaporation method. Followed by the deposition, blue color emission layer was deposited using TMP-BiP as a host material and DJNBD-1 as a dopant. Finally, small molecule OLEDs with structure of $ITO/2-TNATA/NPB/TMP-BiP:DJNBD-l/Alq_3/LiF/Al$ were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. The effect of dopant into host material of the blue OLEDs was studied. The blue OLEDs with DJNBD-1 dopant showed that the maximum current and luminance were found to be about 34 mA and $8110\;cd/m^2$ at 11 V, respectively. In addition, the color coordinate was x=0.17, y=0.17 in CIE color chart, and the peak emission wavelength was 440 nm. The maximum current efficiency of 2.15 cd/A at 7 V was obtained in this experiment.

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