• Title/Summary/Keyword: Emission Reduction

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Influences of Plasma Treatment on the Electrical Characteristics of rf-magnefrom sputtered $BaTa_2O_6$ Thin Films (플라즈마 표면 처리가 $BaTa_2O_6$박막의 전기적 특성에 미치는 효과에 관한 연구)

  • Kim, Young-Sik;Lee, Yun-Hi;Ju, Byeong-Kwon;Sung, Mang-Young;Oh, Myung-Hwan
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.319-325
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    • 1999
  • Direct current(d.c.)leakage current voltage characteristics of radio-frequencymagnetron sputtered BaTa\sub 2\O\sub 6\ film capacitors with aluminum(A1) top and indium tin oxide (ITO) bottom electrodes have been investigatedas a function of applied field and temperature. In order to study surfacetreatment effect on the electrical characteristics of as-deposited film weperformed exposure of oxygen plasma on $BaTa_2O_6$ surface. d. c.current-voltage (I-V), bipolar pulse charge-voltage (Q-V), d. c. current-time (I-t) andcapacitance-frequency (C-f) analysis were performed on films. All ofthe films exhibita low leakage current, a high breakdown field strength (3MV/cm-4.5MV/cm), and high dielectric constant (20-30). From the temperature dependence of leakage current,we can conclude that the dominant conduction mechanism is ascribed toSchottky emission at high electric field (>1MV/cm) and hopping conduction at lowelectric field (<1MV/cm). According to our results, the oxide plasma surfacetreatmenton as-deposited $BaTa_2O_6$ resulted in lowering interfacebarrier height and thus, leakage current when a negative voltage applied to the A1 electrode. This can be explained by reduction of surface contamination via etching surface and filling defects such as oxygen vacancies.

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A Study on Estimation Model of Strength Development of Concrete Using Fly Ash and Ground Granulated Blast-Furnace Slag (플라이애시 및 고로슬래그 미분말을 사용한 콘크리트의 강도 발현 예측 모델식 연구)

  • Choi, Yun-Wang;Park, Man-Seok;Jeong, Jae-Gwon;Choi, Byung-Geol;Kim, Kyung-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.87-93
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    • 2013
  • Recently, the amount of the mineral admixture including fly ash and ground granulated blast-furnace slag was increased for the purpose of $CO_2$ gas emission reduction in the concrete industry. However, in the case of korea, estimation model of strength development in concrete structural design code was prescribed a constant value according to cement type and curing method about the portland cement. therefore, the properties of strength development according to time of concrete using fly ash and ground granulated blast-furnace slag does not reflected estimation model of strength development. Accordingly, this paper was evaluated strength according to time on the concrete strength range using fly ash and ground granulated blast-furnace Slag and the strength development constant ${\beta}_{sc}$ of concrete according to the kind of the mineral admixture and mixing ratio was proposed.

NOx Formation Characteristics on Heat Loss Rate for CH4/Air Premixed Flames in a Perfectly Stirred Reactor (완전혼합 반응기에서 CH4/Air 예혼합화염의 열손실율에 따른 Nox 생성특성)

  • Hwang, Cheol-Hong;Lee, Kee-Man;Kum, Sung-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.7
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    • pp.1465-1472
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    • 2009
  • The effect of heat loss rate on NOx formation of $CH_4/air$premixed flame were examined numerically in a perfectly stirred reactor. The following conclusions were drawn. Under the adiabatic wall condition, an increase in the residence time causes a remarkable increases in NOx emission. Under the heat loss conditions, however, NOx decreases significantly as the heat transfer coefficient and residence time increase. As the heat loss rate increases, Thermal NO mechanism and Re-burning NO mechanism play an important role in the NOx reduction, but Prompt NO mechanism and $N_2O$-intermediate NO mechanism lead to the increase in NOx production. Although the NOx formation is actually related to complex NOx mechanism with the changes in the heat transfer coefficient and residence time, it was found that NOx concentration can be represented by independent Thermal NO mechanism. From these results, new NOx correlation combined with the heat loss rate and residence time was suggested for predicting the NOx concentration in a practical $CH_4/air$premixed combustor.

Strength Properties of Mortar According to Types of Binders for Reducing Curing Process of Concrete Secondary Products for Reduction CO2 (CO2 절감을 위한 콘크리트 2차제품 양생단계저감용 결합재 종류에 따른 모르타르 강도특성)

  • Kim, Ha-Seog;Baek, Dae-Hyun;Lee, Sea-Hyun
    • Resources Recycling
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    • v.23 no.4
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    • pp.37-46
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    • 2014
  • Carbon dioxide generated from construction materials and construction material industry among the fields of construction is approximately 67 million tons. It is about 30% of the carbon dioxide generated in the fields of construction. In order to reduce carbon dioxide in the fields of construction, it is necessary to control the use of fossil fuel consumed and decrease carbon emission by reducing the secondary and tertiary curing generating carbon dioxide in construction material industry. Therefore, this study manufactured mortar by having cement as the Plain and substituting three binding materials up to 50% and then adopted different curing methods to analyze congelation and strength characteristics. Test results for strength property by changing binding materials showed that specimens with blast furnace slag, CSA 15% and CAMC 5% resulted in positive effect for strength.

Low Dielectric Constant of MeV ion-Implanted Poly(vinylidene fluoride)

  • Lee, Sang-Yun;Kim, Bo-Hyun;Park, Soung-Kyu;Jinsoo Joo;Beag, Yowng-Whoan;Koh, Seok-keun
    • Macromolecular Research
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    • v.11 no.1
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    • pp.9-13
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    • 2003
  • Poly (vinylidene fluoride) (PVDF) samples were implanted by using high energy (MeV)F$^{2+}$ and Cl$^{2+}$ ions. We observed that AC dielectric constant of the ion-implanted PVDF samples decreased from 10.5 to 2.5 at 1 kHz as the ion dosage increased from 10$^{11}$ to 3 $\times$ 10$^{14}$ ions/$\textrm{cm}^2$. From differential scanning calorimetry experiments, we observed that PVDF samples become more disordered state through the ion implantation. The decrease of the number of bonding of C-H and C-F and the increase of unsaturated bonding were observed from X-ray photoelectron spectroscopy experiments. The emission of HF and H$_2$ molecules during the ion implantation was detected by residual gas analyzer spectrum. Based upon the results, we analyzed that the low AC dielectric constant of the MeV ion-implanted PVDF samples originated from the reduction of polarization due to the structural change of the CF$_2$ molecules in the MeV ion-implanted PVDF samples.les.

Study on Fuel Economy Characteristics by Cumulative Distance of Vehicle (차량 누적거리에 의한 연비 특성 연구)

  • Lim, Jae-Hyuk;Kim, Ki-Ho;Lee, Min-Ho
    • Journal of Power System Engineering
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    • v.21 no.4
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    • pp.57-61
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    • 2017
  • The vehicle label fuel economy is used as an energy management indicator nationwide. It induces technology development of automobile manufacturers and plays a role of providing information when purchasing a consumer vehicle. However, consumers who purchase a new vehicle continued to complain that the label fuel economy is different from the mandatory fuel economy rate. The domestic fuel economy measurement method is the same as the North American measurement method. The results of the two test modes (urban (FTP-75 mode), highway (HWFET mode)) are calculated in five test modes reflecting various environmental conditions and driving patterns 5-cycle correction formula is used which is equivalent to the fuel efficiency value. In this study, to solve the consumers' curiosity about the fuel economy of new vehicle, we use domestic fuel economy measurement method to measure the new car condition within 150 km of driving distance and the cumulative driving distance condition of domestic label fuel economy test vehicle. A comparative evaluation of fuel economy was carried out for a durability vehicle of $6,500{\pm}1,000km$. A result, mean value of the fuel economy of the four gasoline vehicles increased by 2.7 % in the city center mode and by 2.5 % in the highway mode in the durable vehicle compared new vehicle. And in the case of the diesel vehicle it increased by 2.5 % and 3.9 % respectively. The harmful exhaust gas emitted from the vehicle also resulted in more emissions of both gasoline and diesel vehicles in new vehicles. It is considered that the increase of the frictional force of the vehicle driving system and the lubricating oil system would have an effect on the reduction of the fuel economy of the new vehicle, and it was found that the fuel economy and the exhaust gas were improved by proper cumulative distance (domesticate) to the new vehicle.

Study on the Reduction of NPS Pollution and GHG Emission from Paddies with SRI Methods (SRI 방법을 적용한 논에서의 비점오염원 및 온실가스 저감효과)

  • Park, Woon-Ji;Lee, Su-In;Yun, Dong-Koun;Kim, Gun-Yeob;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.440-440
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    • 2012
  • 본 연구에서는 수질관리 및 기후변화(온실가스 저감) 등에 부응할 수 있는 SRI 벼재배 방법을 국내 논에 적용하여 농업비점오염원과 온실가스 저감효과를 측정하고 비교하여 SRI의 환경개선효과를 평가하고자 하였다. 시험포는 대조구인 상시담수처리구(관행, 재식거리 $30{\times}15cm$)와 SRI 물관리 처리구로 조성하였다. 각 시험포에는 관개배수시설 및 관개량을 측정할 수 있는 수도계량기, 유출량 측정을 위한 플륨 및 수위계 그리고 온실가스(메탄 및 이산화질소)를 측정하기 위한 아크릴재질의 Chamber를 설치하였다. 관행 및 SRI 시험포에 이앙할 모의 재배품종으로 오대벼를 공시하고 모든 시험포의 경우 1주당 3-5본씩 기계이앙을 실시하였으며, 물관리를 제외한 시비와 제초 등의 영농관리는 동일하게 수행하였다. 메탄($CH_4$)과 아산화질소($N_2O$)는 주 2회, 오전 9시 12시에 60 mL 주사기로 주기적으로 시료를 채취하여 GC로 분석하였다. 그리고 관개기간동안 관개량, 강우량 그리고 강우 유출량을 측정하고 수질시료를 채취하여 오염부하를 산정하였다. SRI 시험포의 SS, $COD_{Cr}$, $COD_{Mn}$, BOD, TN, TP의 총 오염부하량은 각각 583 kg/ha, 210.8 kg/ha, 70.1 kg/ha, 30.7 kg/ha, 56.1 kg/ha, 3.55 kg/ha로서 관행 시험포의 오염부하량에 비해 27.1~46.0%의 오염물질 저감 효과를 보였다. 그리고 각 시험포별 온실가스 메탄과 아산화질소의 총 배출량을 지구온난화잠재력(GWP)으로 환산하여 이산화탄소($CO_2$) 기준으로 산정한 결과, 관행은 14.2 톤/ha 그리고 SRI 물관리 처리구 4.0 톤/ha로 관행 대비 SRI 처리구에서 71.8%의 온실가스 감축효과를 나타내었다. 따라서 SRI 벼재배기술은 논 비점오염부하 및 온실가스 저감을 위한 효과적인 최적영농관리방법인 것으로 판단된다.

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The diagnosis of Plasma Through RGB Data Using Rough Set Theory

  • Lim, Woo-Yup;Park, Soo-Kyong;Hong, Sang-Jeen
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.413-413
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    • 2010
  • In semiconductor manufacturing field, all equipments have various sensors to diagnosis the situations of processes. For increasing the accuracy of diagnosis, hundreds of sensors are emplyed. As sensors provide millions of data, the process diagnosis from them are unrealistic. Besides, in some cases, the results from some data which have same conditions are different. We want to find some information, such as data and knowledge, from the data. Nowadays, fault detection and classification (FDC) has been concerned to increasing the yield. Certain faults and no-faults can be classified by various FDC tools. The uncertainty in semiconductor manufacturing, no-faulty in faulty and faulty in no-faulty, has been caused the productivity to decreased. From the uncertainty, the rough set theory is a viable approach for extraction of meaningful knowledge and making predictions. Reduction of data sets, finding hidden data patterns, and generation of decision rules contrasts other approaches such as regression analysis and neural networks. In this research, a RGB sensor was used for diagnosis plasma instead of optical emission spectroscopy (OES). RGB data has just three variables (red, green and blue), while OES data has thousands of variables. RGB data, however, is difficult to analyze by human's eyes. Same outputs in a variable show different outcomes. In other words, RGB data includes the uncertainty. In this research, by rough set theory, decision rules were generated. In decision rules, we could find the hidden data patterns from the uncertainty. RGB sensor can diagnosis the change of plasma condition as over 90% accuracy by the rough set theory. Although we only present a preliminary research result, in this paper, we will continuously develop uncertainty problem solving data mining algorithm for the application of semiconductor process diagnosis.

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Synthesis and Luminescent Characteristics of BaGa2S4:Eu2+ Green Phosphor for Light Emitting Diode (LED용 BaGa2S4:Eu2+ 녹색 형광체의 합성 및 발광특성)

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • Korean Journal of Materials Research
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    • v.16 no.12
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    • pp.761-765
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    • 2006
  • [ $II-III_2-(S,Se)_4$ ] structured of phosphor has been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, the europium doped $BaGa_2S_4$ was prepared by solid-state method and had high potential application due to an emissive property of UV region. Also, the common sulfide phosphors were synthesized by using injurious $H_2S\;or\;CS_2$ gas. However, in this study $BaGa_2S_4:Eu^{2+}$ phosphor in addition to excess sulfur was prepared under at 5% $H_2/95%\;N_2$ reduction atmosphere. Thus, this process could be considered as large scale synthesis because of non-harmfulness and simplification. The photoluminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than that of commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

Effect of Ca Ion on the SCR Reaction over VOx/TiO2 (Ca 이온이 VOx/TiO2 SCR 반응에 미치는 영향 연구)

  • Kim, Geo Jong;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.165-170
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    • 2016
  • In this study, we investigated the cause of the decrease in activities of $VO_x/TiO_2$ SCR catalyst used for the burner reactor at a scale of $150000Nm^3/hr$ using X-ray diffraction (XRD), brunauer-emmett-teller (BET), atomic emission spectroscopy inductively coupled plasma (AES ICP), $H_2$ temperature programmed reduction ($H_2$-TPR), and $NH_3$ temperature programmed desorption ($NH_3$-TPD) analysis. Since the crystallization of the $VO_x$ and phase transition of $TiO_2$ did not occur, it was concluded that the catalyst was not deactivated by the thermal effect. In addition, from the elemental analysis showing that a large quantity of calcium was detected but not sulfur, the deactivation process of the $VO_x/TiO_2$ SCR catalyst was mainly caused by Ca but not by $SO_2$. The calcium was also found to decrease the catalytic activity by means of reducing $NH_3$ adsorption.