• Journal of Electrical Engineering and Technology
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• 제13권2호
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• pp.918-927
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• 2018

Based on the actual operating environment of transformer, the aging tests of nitrile butadiene rubber (NBR) were conducted systematically under four conditions: in air, in transform oil, under compression in air and under compression in transform oil to studythe effect of high temperature, transform oil and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber and predict the lifetime. The effects of liquid media and compression stress simultaneously on the thermal aging behaviors of nitrile butadiene rubber were studied by using characterization methods such as IR spectrosc-opy, thermogravimetric measurements, Differential Scanning Calorimetry (DSC) measurements and mechanical property measurements. The changes in physical properties during the aging process were analyzed and compared. Different aging conditions yielded materials with different properties. Aging at $70^{\circ}C$ under compression stress in oil, the change in elongation at break was lower than that aging in oil, but larger than that aging under compression in air. The compression set or elongation at break as evaluation indexes, 50% as critical value, the lifetime of NBR at $25^{\circ}C$ was predicted and compared. When aging under compression in oil, the prediction lifetime was lower than in air and under compression in air, and in oil. It was clear that when predicting the service lifetime of NBR in oil sealing application, compression and media liquid should be involved simultaneously. Under compression in oil, compression set as the evaluation index, the prediction lifetime of NBR was shorter than that of elongation at break as the evaluation index. For the life prediction of NBR, we should take into account of the performance trends of NBR under actual operating conditions to select the appropriate evaluation index.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.179-182
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• 2002

XLPE compound have used for insulation of 22.9(kV) power cable. But tree retardant power cable has developed and is going to br used commonly. TR XLPE compound retard production and growth of water tree. In this paper, tensile strength, elongation at break, degree of crosslinking, lightning impulse test, AC breakdown test, cyclic aging for 14days and accelerated water treeing test of TR XLPE insulated power cable were examined according to the KEPCO buying spec. & AEIC CS 5-94 standards. before and after As the result, tensile strength, elongation at break and degree of crosslinking test results of TR XLPE insulation were higher than requirement values. After accelerated water treeing test for 120 days, 240 days and 360 days, AC breakdown voltages were not decreased for accelerated water treeing aging duration

• 한국염색가공학회지
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• 제33권3호
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• pp.120-130
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• 2021

The condition of covering process using thermoplastic polyetherester elastomeric fibers(TPEE) was established. Two types of core yarn(TPEE, Spandex) and one type of effect yarn(PET) were used as materials to confirm the change in physical properties of covering yarn under various covering conditions. In addition, the effects of the treatment temperature on the elongation at break of covering yarn after heat treatment was analyzed. Through this analysis, it was confirmed that the elastic recovery of TPEE which is used as the core yarn was increased with the draw ratio, but decreases when it exceeds 1:2.5. And the elongation at break of the covering yarn could be increased by increasing the twist per meter of it. Additionally, it was confirmed that the elastic recovery of TPEE which is used as a core yarn, could be increased by applying heat treatment.

• 한국염색가공학회지
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• 제33권4호
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• pp.327-337
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• 2021

The uniformly dispersed Aramid and Poly (phenylene benzobisoxazole) (PBO) in a variety of rubber was investigated. The mechanical properties of rubber were characterized by hardness, tensile strength, elongation at break, heat resistance, oil resistance, cold resistance, ozone resistance measurements. The 3mm Aramid chopped fiber better tensile strength than the other Chopped fiber. The Aramid of 3mm chopped fiber showed excellent reinforcing in rubber composite because of homogeneous dispersion. Consequently, the best 3mm Aramid chopped fiber and rubber improved the tensile strength and elongation at break of the composite. Also, 3mm Aramid chopped fiber improved the oil-resistant, ozone resistant and cold resistant.

• Elastomers and Composites
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• 제46권2호
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• pp.138-143
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• 2011

EPDM에 카본블랙과 더불어 무기 충전제인 탈크, 탄산칼슘, 혹은 클레이를 함께 혼합하여 EPDM 배합물과 가황물을 제조하여, 무기 충전제가 EPDM 배합물과 가황물의 특성에 미치는 영향을 조사하였다. 무기 충전제를 추가해도 결합 고무 함량(bound rubber content)에는 큰 차이가 없었다. 무기 충전제 함량이 높을수록 큰 입자로 존재함을 확인하였다. 무기 충전제를 추가하면 가교 시간은 전반적으로 증가하는 경향을 보였으며, 델타 토크(delta torque)는 감소하였다. 무기 충전제를 추가하면 모듈러스는 전반적으로 감소하였으나, 신율과 인장강도 그리고 인열강도는 증가하였다. 모듈러스의 감소와 신율의 증가는 가교밀도의 감소로 설명하였으며, 인장강도와 인열강도의 증가는 신율의 증가로 설명하였다. 무기 충전제의 첨가에 의해 보강성은 증가하지 않았고 가교밀도는 감소하였다.

• Elastomers and Composites
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• 제46권2호
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• pp.132-137
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• 2011

본 연구는 H-NBR 함량 변화에 따른 H-NBR/NBR 블렌드의 열노화 거동에 대하여 살펴보았다. 이 때 가교제로는 dicumyl peroxide와 황 혼합물을 사용하였으며, 열노화에 따른 H-NBR/NBR 블렌드의 인장강도, 파괴신율, 경도 그리고 내마모성의 변화를 살펴보았다. H-NBR을 첨가함에 따라 인장강도는 증가하였으나 내마모성은 감소하는 현상을 나타내었다. 파괴신율과 경도는 H-NBR의 영향을 받지 않았다. 노화가 진행된 모든 시편은 초기 시편보다 낮은 인장강도, 파괴신율, 경도를 나타내었다. 그러나 H-NBR의 함량이 증가함에 따라 이러한 물성저하 속도가 감소함을 알 수 있었다. 즉 H-NBR 첨가에의해 열노화 특성이 향상됨을 알 수 있었다. 모든 NBR/H-NBR 블렌드는 노화시간이 증가함에 따라 내마모성이 감소하였으며, H-NBR을 첨가한 경우 내마모성의 저하가 상대적으로 낮음을 알 수 있었다.

• Macromolecular Research
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• 제15권4호
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• pp.315-323
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• 2007

The present manuscript deals with the prediction of the lifetime of NBR compound based rubber gaskets for use as fuel cells. The material was investigated at 120, 140 and $160^{\circ}C$, with aging times from 3 to 600 h and increasing $H_2SO_4$ concentrations of 5, 6, 7 and 10 vol%. Both material and accelerated acid-heat aging tests were carried out to predict the useful life of the NBR rubber gasket for use as a fuel cell stack. To investigate the effects of acid-heat aging on the performance characteristics of the gaskets, the properties of the NBR rubber, such as crosslink density and elongation at break, were studied. The hardness of the NBR rubber was found to decrease with decreasing acid concentration at both $120\;and\;140^{\circ}C$, but at $160^{\circ}C$, the hardness of the NBR rubber increased abruptly in a very short time at different acid concentrations. The tensile strength and elongation at break were found to decrease with increases in both the $H_2SO_4$ concentration & temperature. The observed experimental results were evaluated using the Arrhenius equation.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.47-51
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• 2007

The present paper reports the life time prediction of Acrylonitrile-Butadiene rubber (NBR) fuel cell gasket materials as a function of operational variables like acid concentration, ageing time and temperature. Both material and accelerated acid-heat aging tests were carried out to predict the useful life of the NBR rubber gasket for use as a fuel cell stack. The acid ageing of the gasket compounds has been investigated at 120, 140 and $160^{\circ}C$, with aging times from 3 to 600 h and increasing acid ($H_2SO_4$) concentrations of 5, 6, 7 and 10 vol%. Material characteristics the gas compound such as cross-link density, tensile strength and elongation at break were studied. The hardness of the NBR rubber was found to decrease with decreasing acid concentration at both 120 and $140^{\circ}C$, but at $160^{\circ}C$ interestingly the hardness of the NBR rubber increased abruptly in a very short time at different acid concentrations. The tensile strength and elongation at break were found to decrease with increase in both the acid concentrate ion & temperature. The life time of the compounds were evaluated using the Arrhenius equation.

• 한국환경과학회지
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• 제19권3호
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• pp.365-370
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• 2010

In this study, we carried out the evaluation of EPDM(Ethylene Propylene Diene Monomer) reclaimed rubber mixing with natural rubber at various mixing ratio to reuse as rubber filler. The scorch time and moony viscosity was analyzed to evaluate the effect of cure behavior. And also, we analyzed the tensile strength, the elongation at break and cure time to evaluate the variation of cure behavior. As the results, the scorch time and optimal cure time was decreased according to the increasing of EPDM reclaimed rubber. However, the moony viscosity was increased at each mixing ratio. In case of the added EPDM reclaimed rubber was 20 phr(parts by weight per 100 parts by weight of rubber), the hardness and specific gravity was increased a little. The hardness and specific gravity was increased in rapidly under 40 phr of the added EPEM reclaimed rubber. The tensile strength and elongation at break of the compound of natural and EPDM reclaimed rubber was rapidly decreased compared with its natural rubber when the ratio of adding EPDM reclaimed rubber was over 40 phr.

• Elastomers and Composites
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• 제58권3호
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• pp.128-135
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• 2023

To improve the adhesive strength of natural rubber (NR) for a seismic isolation damper, citraconic acid-g-NR (CCA-g-NR) was synthesized via the melt grafting of citraconic acid (CCA) onto NR using an azobisisnomerobutyronitrile (AIBN) initiator. Subsequently, the influence of CCA and AIBN concentrations on the graft ratio G/R (%) and graft efficiency G/E (%) of the CCA-g-NR was investigated. The optimum CCA and AIBN concentrations required to achieve the desired G/R (3.49%) and G/E (49.8%) were found to be 7 phr and 0.13 phr, respectively. Additionally, we studied the influence of CCA-g-NR concentration on the mechanical properties (tensile strength, elongation at break, and modulus at 300%), adhesive strength, and cure characteristics of the rubber compound in the seismic isolation damper. As the concentration of CCA-g-NR increased, the elongation at break and adhesive strength of the compound increased, whereas its tensile strength and modulus at 300% decreased. Moreover, as the concentration increased, the maximum torque decreased and the scorch time was delayed to obtain an optimal vulcanization time.