• Title/Summary/Keyword: Electronic conductivity

Search Result 1,035, Processing Time 0.031 seconds

Geometric structure and electronic behavior of Rh decorating effect on zigzag CNTs (n=7-12): A DFT study

  • Cui, Hao;Zhang, Xiaoxing;Zhou, Yongjian;Zhang, Jun
    • Carbon letters
    • /
    • v.26
    • /
    • pp.61-65
    • /
    • 2018
  • Comprehensive calculations of the Rh decoration effect on zigzag CNTs with n ranging from 7 to 12 were conducted in this work to understand the effect of Rh doping on geometric structures and electronic behaviors upon metallic and semiconducting CNTs. The obtained results indicated that Rh dopant not only contributes to the deformation of C-C bonds on the sidewall of CNTs, but also transforms the electron distribution of related complexes, thereby leading to a remarkable increase of the conductivity of pure CNTs given the emerged novel state within the energy gap for metallic CNTs and the narrowed energy gap for semiconducting CNTs. Our calculations will be meaningful for exploiting novel CNT-based materials with better sensitivity to electrons and higher electrical conductivity compared with pure CNTs.

The research of one-step emulsion polymerization of aniline and its conducting blends with polystyrene (에멀젼중합법으로 제조된 폴리아닐린과 폴리스타이렌과의 전도성블렌드에 대한 연구)

  • 이보현;김태영;김종은;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.259-262
    • /
    • 2001
  • Stable polyaniline-dodecylbenzenesulfonic acid (PANI-DBSA) fully dissolved in toluene was obtained by a direct one-step emulsion polymerization technique. The polymerization of aniline was carried out in an emulsion comprising water, toluene and DBSA acting both as a surfactant and a dopant for PANI. After the proper washing process was performed, the conductivities of obtained PANI-DBSA complexes increased with increase APS/Aniline molar ratio and DBSA/Aniline molar ratio. The UV-Vis absorption spectra and TGA thermograms of PANI-DBSA complexes also supported these results. PANI-DBSA/PS blends were prepared by mixing PANI-DBSA complexes with PS in toluene. These blends exhibited electrical conductivity of 0.371S/cm at a low PANI-DBSA content (7 wt.%)

  • PDF

Polyamic Acid Alkylamine Salts(PAAS) (Langmuir-Blodgett(LB) Films의 광학적 및 전기적 특성)

  • 이승엽;강도열;김태완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.04a
    • /
    • pp.277-280
    • /
    • 1997
  • It is important to investigate the molecular arrangement and the orientational distribution in the study of LB films. Polarized UV/visible absorption spectra make it possible to reveal the molecular arrangement and the orientational distribution. It is clarified that the PAAS LB films have specific directions in the molecular arrangement and the orientational distribution, which art different in intensity corresponding to the surface pressure. Unpolarized UV/visible absorption spectra reveal that the surface pressure is proportional to the finn thickness and is related to the molecular orientation. Current-Voltage(I-V) measurements provide that the current decreases as the surface pressure increases and there are certain phenomena called switching phenomena. Switching effort indicates that the current flows in high conductivity during on-state and suddenly decreases into low conductivity during off-state.

  • PDF

Electrical Properties of Sintered $HoSi_2$ ($HoSi_2$소결체의 전기적 특성 연구)

  • 이우선;김형곤;김남오
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.14 no.10
    • /
    • pp.792-795
    • /
    • 2001
  • we present a electrical transport(resistivity, Hall effect) measurements in varying temperature ranges between 78K and 300K on HoSi$_2$ composites by hot-pressed sintering. It has been found that this sintered HoSi$_2$ has a orthorhombic structure, and lattices constant is a=9.8545$\AA$, b=7.7935$\AA$, c=7.8071$\AA$. The measured electrical resistivity is about 1.608$\Omega$ cm and carrier mobility is about 6.9$\times$10$^{1}$cm $^{2}$V.sec at low room temperature. The Hall effect shows a n-type conductivity in the sintered HoSi$_2$.

  • PDF

Crystallization and Electrical Conductivity of $CuO-P_{2}O_{5}-V_{2}O_{5}$ Glass for Solid-state Electrolyte (고체전해질용 $CuO-P_{2}O_{5}-V_{2}O_{5}$유리의 결정화와 전기전도도)

  • 손명모;이헌수;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.1018-1021
    • /
    • 2001
  • 1018-1021 The CuO-P$_2$O$_{5}$ containing P$_2$O$_{5}$ as glass-former were prepared by press-quenching method on the copper plate. By post-heat treatment of these glasses, the CuO-P$_2$O$_{5}$ -V$_2$O$_{5}$ -g1ass ceramics was obtained and the crystallization behavior and dc conductivities were investigovted. The heat-treated glass-ceramics decreased in electrical conductivity by the order of 10$^1$ compared to amorphous glass. The linear relationship between In($\sigma$T) and T$^{-1}$ indicated that electrical conduction in CuO-P$_2$O$_{5}$ -V$_2$O$_{5}$ -gass occurred by a small polaron hopping.

  • PDF

A Study on Advanced Lithium-Ion Battery with Polyurethane-Based Gel Polymer Electrolyte (Polyurethane기 겔폴리머전해질을 이용한 Advanced Lithium-Ion Battery에 관한 연구)

  • 김현수;문성인;윤문수;김상필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.07a
    • /
    • pp.252-254
    • /
    • 2002
  • In this study, polyurethane acrylate macromer was synthesized and it was used in a gel polymer electrolyte, and then its electrochemical performances were evaluated. LiCoO$_2$/GPE/MCF cells were also prepared and their performances depending on discharge currents and temperatures were evaluated. ionic conductivity of the gel polymer electrolyte with PUA at room temperature and -20$^{\circ}C$ was ca. 4.5 x 10$\^$-3/ S/cm and 1.7${\times}$10$\^$-3/ S/cm, respectively. GPE was stable electrochemically up to 4.5 V vs. Li/Li$\^$+/. LiCoO$_2$/GPE/MCF cell showed a good high-rate and a low-temperature performance.

  • PDF

Analysis of Heat-transfer on Winding composed with Epoxy-resin (에폭시수지로 몰딩된 권선의 열전달 특성 연구)

  • 이현진;허창수;조한구;이기택;서유진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.07a
    • /
    • pp.402-405
    • /
    • 2002
  • This paper presented the characteristic of Heat-transfer on the winding composed with Epoxy-resin in a 50 kVA cast-resin dry type transformer The resin cast transformer is used widely in supplying electricity systems. However, to know the thermal characteristics of that is very useful in designing, manufacturing, and maintaining, there is no pertinent method to calculate this. In this paper, Based on the results of the physical characteristics and the simulation by commercial software using FEM method, we established the Prototype Model for this. According to that Model, an analysis on a variation of the hottest spot temperature was discussed as a function of thermal conductivity for the individual windings composed with Epoxy-resin. The thermal conductivity of the individual windings with reference to upper way was discussed.

  • PDF

Synthesis and Characterization of Transformer Oil containing Nanoparticles (나노분말이 첨가된 변압기 절연유 제조 및 정적열전특성 평가)

  • Song, Hyun-Woo;Choi, Cheol;Choi, Kyung-Shik;Oh, Je-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.11a
    • /
    • pp.49-52
    • /
    • 2004
  • New hydrophobic alumina nanoparticles were synthesized from alumina powders which were hydrophilic nano-agglomerates with diameters from ${\mu}m$ to mm by surface modification. The synthesized hydrophobic alumina nanoparticles which were retreated with Oleic acid were analyzed by Fourier transform infrared spectrophotometer and transmission electron microscopy. Then transformer oil containing surface-modified alumina naonparticles were synthesized. The synthesized hydrophobic alumina nanoparticles were well-dispersed in transformer oil. The coefficient of viscosity and dielectric strength of the Nano-transformer oil were investigated with viscometer and high voltage experiment device. In this study, the thermal conductivity of Nano-transformer oil was investigated to reduce the oil temperature of transformer by transient hot-wire method.

  • PDF

Effects of Alternating Magnetic Field Assisted Annealing of Pentacene Film for Organic Thin Film Transistor Applications

  • Park, Jae-Hoon;Choi, Jong-Sun
    • Transactions on Electrical and Electronic Materials
    • /
    • v.8 no.1
    • /
    • pp.32-35
    • /
    • 2007
  • In this article, a novel annealing technique using alternating magnetic field (AMF) is adopted to improve the electrical characteristics of pentacene film, thereby enhancing the performance of pentacene-based organic thin film transistors (OTFTs). According to the investigation results, the electrical conductivity in the pentacene film could be increased from 0.32 to 1.18 S/cm by annealing the pentacene film using AMF. And also, OTFTs with the pentacene film annealed by AMF exhibited an improved performance compared to the device without annealing. These results suggest that an annealing using AMF can be an effective method to improve the performance of devices based on organic semiconductors.

Electrical Properties of the LDPE mixed with Dodecyl Alcohol (도데실알콜이 첨가된 LDPE의 전기적 특성)

  • Kim, S.J.;Lee, C.H.;Kim, J.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1992.11a
    • /
    • pp.110-113
    • /
    • 1992
  • This paper presents the results on experiments of relative dielectric constant dielectric loss, conductivity change and breakdown voltage of the L.D.P.E. mixed with Dodecyl Alcohol. The frequency range is 0.1 - 20 MHz and temperature, 20 - 80 $^{\circ}C$. Dielectric properties were similar to those of nonpolar polymers. Until $60^{\circ}C$ the conductivity value of compound was decreased with temperature increasment. And, its breakdown voltage was measured higher, about 3-4KV, than that of the pure L.D.P.E.. Also the amount of remnants of DA in the compounds were considered.

  • PDF