• 제목/요약/키워드: Electronic Conductivity

검색결과 1,033건 처리시간 0.022초

Mg2Si0.6Sn0.4 열전재료의 열전특성과 미세조직 (Thermoelectric properties and microstructures of Mg2Si0.6Sn0.4-based thermoelectric materials)

  • 장정인;류병기;이지은;박수동;이호성
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.53-53
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    • 2018
  • Thermoelectric materials can convert directly waste heat to electricity and vice versa. The improvement of the thermoelectric efficiency strongly depends on the dimensionless figure of merit, $ZT=S^2{\sigma}T/{\kappa}$, where S is the Seebeck coefficient, ${\sigma}$ is the electrical conductivity, T is the absolute temperature, and ${\kappa}$ is the thermal conductivity. The thermal conductivity consists of the electronic contribution (${\kappa}_e$) and phonon contribution (${\kappa}_{ph}$). It is very challenge to increase the power factor, $S^2{\sigma}$ and to reduce the thermal conductivity simultaneously because the power factor and electronic thermal conductivity are coupled. One strategy is to decrease the phonon thermal conductivity. The phonon thermal conductivity can be decreased by controlling the grain size and structural defects such as dislocations and twinning. In order to achieve enhancements in thermoelectric efficiency, microstructures that can form numerous interfaces have been investigated intensively for controlling the transport of charge carriers and heat carrying phonons. In this presentation, we report the heterogeneous microstructure of $Mg_2Si_{0.6}Sn_{0.4}$ thermoelectric materials and investigation of its influence on thermoelectric properties.

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고온초전도 선재용 피복합금의 열전도도 측정 및 특성평가 (Thermal conductivity and properties of sheath alloy for High-$T_c$ superconductor tape)

  • 박형상;지봉기;김중석;임준형;오승진;오승진;주진호;나완수;유재무
    • 한국전기전자재료학회논문지
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    • 제13권8호
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    • pp.711-717
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    • 2000
  • Effect of alloying element additions to Ag on thermal conductivity electrical conductivity and mechanical properties of sheath materials for BSCCO tapes has been characterized. The thermal conductivity at low temperature range(10~300K) of Ag alloys were evaluated by both direct and indirect measurement techniques and compared with each other. It was observed that thermal conductivity decreased with increasing the content of alloying elements such as Au, Pd and Mg. Thermal conductivity of pure Ag at 30 K was measured to be 994.0 W/m.K on the other hand the corresponding values of A $g_{0.9995}$/M $g_{0.0005}$, A $g_{0.974}$/A $u_{0.025}$/M $g_{0.001}$, A $g_{0.973}$/Au.0.025//M $g_{0.002}$, and A $g_{0.92}$/P $d_{0.06}$/M $g_{0.02}$ were 342.6, 62.1, 59.2, 28.9 W/m.K respectively indicating 3 to 30 times lower than that of pure Ag. In addition alloying element additions to Ag improved mechanical strength while reduced elongation probably due to the strengthening mechanisms by the presence of additive atoms.s.

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The Influence of Aniline to Acid Composition on the Electrical Conductivity of PANI-PAAMPSA

  • Yoo, Joung Eun;Bae, Joonho
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3825-3828
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    • 2013
  • In this study, the influences of aniline to acid composition were investigated on the electrical conductivity of PANI-PAAMPSA. The ratio of aniline to sulfonic acid groups was optimized for the maximum conductivity of PANI-PAAMPSA. The conductivity is strongly correlated with the electronic structure of PANI-PAAMPSA; the highest conductivity of PANI-PAAMPSA was observed when PANI has the longest conjugation length.

LB법을 이용한 viologen-diTCNQ 박막의 광학적 및 전기적 특성 (Optical and Electrical Characteristics of viologen-diTCNQ thin film prepared by Langmuir-Blodgett Technique)

  • 이용수;신동명;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.45-48
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    • 1997
  • Enhancing the electrical conductivity of the ultrathin organic films is one of the important factors for the development of molecular electronic devices. The Langmuir-Blodgett(LB) technique has recently been attracted interest as the a method of deposition ultrathin films. We have fabricated N-docosyl-N'-methyl viologen-diTCNQ(DMVT) anion radical LB film and investigated the optical and electrical conductivity. We have measured UV/visible and FT-lR spectrum. In ESR spectrum, we confirmed that a half-amplitude linewidth is clearly dependent on both temperature and incident angle, which indicates conducting species change. The in-plane electrical conductivity of 21 layers is approximately 1.37$\times$10$^{-6}$ (S/cm).

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Normal-state charge dynamics of ternary platinum germanide superconductor La2Pt3Ge5

  • Song, S.J.;Sung, N.H.;Cho, B.K.;Moon, S.J.
    • 한국초전도ㆍ저온공학회논문지
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    • 제17권4호
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    • pp.12-15
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    • 2015
  • We report on the infrared spectroscopic studies of the normal-state electronic response of rare-earth ternary platinum germanide superconductor $La_2Pt_3Ge_5$. We analyzed the temperature-dependent optical conductivity spectra using the Drude-Lorentz oscillator model. We found that the two Drude responses with distinct scattering rates are required to explain the charge dynamics at 10 K while a single Drude mode could reproduce the far-infrared conductivity at higher temperatures. Our results indicated the two-band character of the electronic structure and highlighted the disparate temperature evolution of the electrodynamics of the two electronic states.

탄성형 에폭시의 열전도율 및 기계적 특성에 대한 연구 (Study of Thermal Conductivity and Mechanical Property of Elastic Epoxy)

  • 이관우;이경용;최용성;박복기;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.319-322
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    • 2004
  • In this paper, we studied on the thermal conductivity and a mechanical property of the elastic epoxy. According to industrial development, insulation materials have various properties. They are solid, liquid, gas state, there are various type. Epoxy, a kind of insulation material, demand of not only high hardness but also elastic property. When the electric current flows into the conductor and the place where the heat occurs, this heat becomes the cause which shortens the life of the electrical appliance. Therefore, for the heat occurred transmit quickly, thermal conductivity of the insulation material is highly demanded. We studied on the thermal conductivity of elastic epoxy on the high voltage. In this result, thermal conductivity confirmed that it followed thermal property of mixed epoxy and addictives. Hardness is decreased when addictives increased.

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Connectivity and Electrical Conductivity of YSZ-NiO Composite

  • Park, Young-Min;Park, Gyeong-Man
    • The Korean Journal of Ceramics
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    • 제4권2호
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    • pp.141-145
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    • 1998
  • The electrical properties of the mixed conducting yttria(8 mol%) stabilized zirconia(YSZ)-nickel oxide(NiO) composites were examined by a.c. impedance, 4-probe d.c. conductivity between 400 and $1000^{\circ}C$. The oxygen partial pressure dependence of conductivity, and electromotive force measurement of galvanic cell enabled to determine the electronic contribution to the conduction. Up to 6 vol% NiO addition, the conductivity decreased since the electronic NiO acted as an insulator in ionic matrix. However the ionic transport was dominant until NiO content reaches 26 vol%. Mixed conduction was observed between 26 and 68 vol% of NiO. The effect of composition on the electrical property was explained by the microstructure and thus by the distribution of two phases.

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화학적기상증착법에 의한 구리박막의 전기전도도 개선에 관한 연구 (A Study on the Enhancement of Electrical Conductivity of Copper Thin Films Prepared by CVD Technology)

  • 조남인;김용석;김창교
    • 한국전기전자재료학회논문지
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    • 제13권6호
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    • pp.459-466
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    • 2000
  • For the applications in the ultra-large-scale-integration (ULSI) metallization processing copper thin films have been prepared by metal organic chemical vapor deposition (MOCVD) technology on TiN/Si substrates. The films have been deposited with varying the experimental conditions of substrate temperatures and copper source vapor pressures. The films were then annealed in a vacuum condition after the deposition and the annealing effect to the electrical conductivity of the films was measured. The grain size and the crystallinity of the films were observed to be increased by the post annealing and the electrical conductivity was also increased. The best electrical property of the copper film was obtained by in-situ annealing treatment at above 40$0^{\circ}C$ for the sample prepared at 18$0^{\circ}C$ of the substrate temperature.

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산화물유리에서의 $Na^+$이온과 $Ag^+$이온 교환에 따른 전기전도도 변화 (Electrical conductivity in oxide glasses subjected to $sodium \leftrightarrow silver$ ion exchange treatment)

  • 한준수;강원호;이효경
    • E2M - 전기 전자와 첨단 소재
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    • 제9권3호
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    • pp.284-290
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    • 1996
  • The electrical properties of bulk galsses in the system Na$_{2}$O-CaO-Al$_{2}$O$_{3}$-B$_{2}$O$_{3}$-SiO$_{2}$ containing 20 to 30mol% sodium which have been subjected to a sodium .tautm. silver ion exchange reaction for 24, 36 and 48 hrs. were analysed by impedance spectroscopy method. Ion exchanged glasses exhibit activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion exchanging time. In this experiment the electrical conductivity exhibits a manximum value of 1.78*10$^{-4}$ S/cm at 200.deg. C which contains 30mol% sodium and subjects ion exchange reaction for 48hrs.

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고방열 특성을 갖는 복합체 시트의 제조와 그 특성 (Preparation and Characteristics of the Excellent Heat-releasing Composite Sheet Containing AlN and Graphite Powder)

  • 김상문;이석문
    • 한국전기전자재료학회논문지
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    • 제25권6호
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    • pp.462-466
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    • 2012
  • In this paper, heat-releasing composite sheets made of AlN, graphite, Al powder and acryl binder as thermoset were prepared using tape casting method. The crystal structure, morphology, thermal conductivity of heat-releasing composite sheet were measured by using X-ray diffractometer, field emission-scanning electron microscopy and laser flash instrument. It was found thermal conductivity of sheet was decided by solid content, composition including AlN, graphite, Al in heat-releasing composite sheets. As a result, 4.56 W/mK of thermal conductivity could be obtained by using LFA 447.