• 제목/요약/키워드: Electron transport

검색결과 989건 처리시간 0.026초

전자수송층과 발광층 사이의 Ph3PO 혹은 BCP가 유기발광다이오드의 구동전압에 미치는 영향 (Effect of Ph3PO or BCP Between Electron Transport and Emission Layers on the Driving Voltage of Organic Light Emitting Diode)

  • 하미영;문대규
    • 한국전기전자재료학회논문지
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    • 제24권8호
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    • pp.678-681
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    • 2011
  • We have investigated the effect of organic thin film on the driving voltage of OLED (organic light emitting diode) by inserting a 5 nm thick 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) or triphenylphosphineoxide ($Ph_3PO$) between tris-(8-hydroxyquinoline)aluminum ($Alq_3$) electron transport layer and 4,4'-bis(2,2'-diphyenylvinyl)-1,1'-biphenyl (DPVBi) emission layer. The device with 5 nm thick $Ph_3PO$ layer exhibited higher maximum current efficiency and lower driving voltage than the device with BCP layer, resulting from better electron injection from $Alq_3$ to DPVBi in the device with $Ph_3PO$ layer.

시뮬레이션에 의한 $SF_6-N_2$ 혼합기체의 전자수송특성 (Electron Transport Characteristic in $SF_6-N_2$ Mixture Gases by MCS-BEq Simulation)

  • 김상남
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.507-508
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    • 2006
  • $SF_6$ gas is widely used in industrial of insulation field. In this paper, $N_2$ is mixed to improve pure $SF_6$ gas characteristics. Electron transport coefficients in $SF_6-N_2$ mixture gases are simulated in range of E/N values from 70 to 400 [Td] at 300K and 1 Torr by using Boltzmann equation method. The results have been obtained by using the electron collision cross sections by TOF, PT, SST sampling, compared with the experimental data determined by the other author. It also proved the reliability of the electron collision cross sections and shows the practical values of computer simulation. The result of Boltzmann equation and Monte Carlo Simulation has been compared with experimental data by Ohmori, Lucas and Carter. The swarm parameter from the swarm study are expected to sever as a critical test of current theories of low energy scattering by atoms and molecules.

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무기 전자 수송층으로 TiO2 나노입자를 사용한 다양한 양자점 전계발광 소자의 특성 비교 연구 (A Comparison Study on Various Quantum Dots Light Emitting Diodes Using TiO2 Nanoparticles as Inorganic Electron Transport Layer)

  • 김문본;윤창기;김지완
    • 마이크로전자및패키징학회지
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    • 제26권3호
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    • pp.71-74
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    • 2019
  • 본 연구는 발광층으로의 전자 주입을 억제하기 위해 ZnO 나노입자보다 낮은 전자 이동도를 갖는 $TiO_2$ 나노입자를 무기 전자 수송층으로 사용하여 standard와 inverted 두 가지 구조의 양자점 전계발광 소자를 제작하고 그 특성을 비교하였다. Standard 구조의 소자에서는 전류 밀도가 낮은 것에 비해 inverted 구조의 소자에서는 전류 밀도가 매우 높은 것을 확인하였다. 휘도의 경우 inverted 구조의 소자가 standard 구조의 소자보다 더 높았지만 높은 전류 밀도로 인해 낮은 전류 효율을 나타냈다. 또한 전류 밀도가 높은 만큼 구동 전압이 높았으며, 방출 파장 스펙트럼에서 적색 편이를 확인하였다. Standard 구조의 소자에서 나타난 낮은 전류 밀도를 통해, $TiO_2$ 나노입자가 양자점 전계발광 소자에서 전자 주입을 억제할 수 있는 가능성을 확인하였다.

Electron transport in core-shell type fullerene nanojunction

  • Sergeyev, Daulet;Duisenova, Ainur
    • Advances in nano research
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    • 제12권1호
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    • pp.25-35
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    • 2022
  • Within the framework of the density functional theory combined with the method of non-equilibrium Green's functions (DFT + NEGF), the features of electron transport in fullerene nanojunctions, which are «core-shell» nanoobjects made of a combination of fullerenes of different diameters C20, C80, C180, placed between gold electrodes (in a nanogap), are studied. Their transmission spectra, the density of state, current-voltage characteristics and differential conductivity are determined. It was shown that in the energy range of -0.45-0.45 eV in the transmission spectrum of the "Au-C180-Au" nanojunction appears a HOMO-LUMO gap with a width of 0.9 eV; when small-sized fullerenes C20, C80 are intercalation into the cavity C180 the gap disappears, and a series of resonant structures are observed on their spectra. It has been established that distinct Coulomb steps appear on the current-voltage characteristics of the "Au-C180-Au" nanojunction, but on the current-voltage characteristics "Au-C80@C180-Au", "Au-(C20@C80)@C180-Au" these step structures are blurred due to a decrease in Coulomb energy. An increase in the number of Coulomb features on the dI/dV spectra of core-shell fullerene nanojunctions was revealed in comparison with nanojunctions based on fullerene C60, which makes it possible to create high-speed single-electron devices on their basis. Models of single-electron transistors (SET) based on fullerene nanojunctions "Au-C180-Au", "Au-C80@C180-Au" and "Au-(C20@C80)@C180-Au" are considered. Their charge stability diagrams are analyzed and it is shown that SET based on C80@C180-, (C20@C80)@C180- nanojunctions is output from the Coulomb blockade mode with the lowest drain-to-source voltage.

1차원 구조를 가지는 육티탄산 나트륨의 염료감응형 태양전지 음극재 사용 가능성 평가 (Feasibility Test of One-Dimensional Sodium Hexatitanate as an Anode Material in Dye-Sensitized Solar Cells)

  • 바더마;오광중;조국
    • 한국전기전자재료학회논문지
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    • 제28권5호
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    • pp.338-343
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    • 2015
  • Dye sensitized solar cells (DSSCs), which is one of the contending renewable energy sources, have the problem of low efficiency. To improve the efficiency, the fast electron transport and long electron lifetime are required. In this study, one-dimensional sodium hexatitanate, which is expected to have an advantageous structure for electron transports, was synthesized and the feasibility of the material on DSSC was tested. Its physical properties were characterized by the SEM, XRD, and BET method. The dye adsorption and solar cell properties were also characterized. In addition to the expectation of fast electron transport, sodium hexatitanate showed longer electron lifetime: This means sodium hexatitanate can improve the DSSC efficiency. However, it showed low current and voltage because of the low surface area leading to the low amount of dye adsorbed. Therefore, it should be mixed with titanium oxide with high surface area for the optimal performance.

전자군 방법에 이용되는 2항근사와 다항근사 볼츠만 방정식의 적용 (An Application of Two-term and Multi-term Approximation of Boltzmann Equation to Electron Swarm Method)

  • 하성철;전병훈
    • 한국전기전자재료학회논문지
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    • 제15권1호
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    • pp.79-84
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    • 2002
  • An accurate cross sections set is necessary for the quantitatively understanding and modeling of plasma phenomena. By using the electron swarm method, we determine an accurate electron cross sections set for objective atoms or molecule at low electron energy range. It is general calculation that used in this method to an two-term approximation of Boltzmann equation. But it may give erroneous transport coefficients for CF$_4$ molecule treated in this paper having \`C2v symmetry\`, therefore, multi-term approximation of the Boltzmann equation analysis which can consider anisotropic scattering exactly is carried out. It is necessary to require understanding of the fundamental principle of analysis method. Therefore, in this paper, we compared the electron transport coefficients(W and ND$\_$L/) in pure Ar, O$_2$, and CF$_4$ gas calculated by using two-term approximation of the Boltzmann equation analysis code uses the algorithm proposed by Tagashira et al. with those by multi-term approximation by Rubson and Ness which was developed at James-Cook university, and discussed an application and/or validity of the calculation method by comparing these calculated results.

$SF_6$ 가스의 전리 및 부착계수에 관한 연구 (A study on the electron ionization and attachment coefficients ins $SF_6$ gas)

  • 서상헌;유회영;김상남;하성철
    • 한국조명전기설비학회지:조명전기설비
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    • 제10권6호
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    • pp.96-103
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    • 1996
  • 본 논문은 저자들에 위해 결정된 전자충돌단면적을 사용하여 몬테칼로 시뮬레이션 볼쯔만 방정식법에 의해 E/N:150∼180[Td] 범위에서 계산된 {{{{ { SF}_{ 6} }}}}가스의 전자수송 특성과 TOF법에서 구한 전자군 파라미터 값들을 나타냈다. 전자이동 속도 전자전력 또는 부착계숙, 종·횡방향 확산계수 등의 전자군 파라미터 값들은 E/N범위에서 실험치와 이론치가 일치하였다. 전자사태의 특성은 전자에너지의 비평형영역에서 고려되었다. 전자에너지 분포함수 는 평균에너지의 평형영역에 대하여 E/N:150∼180[Td]에서 해석하였다. 그 결과의 타당성은 TOF법에 의해 입증되었다.

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Performance of Three-Layered Organic Light-Emitting Diodes Using the Hole-Transport and Injection Layer of TPD and Teflon-AF, and the Electron-Injection Layer of Li2CO3 and LiF

  • Shin, Jong Yeol;Kim, Tae Wan;Kim, Gwi Yeol;Lee, Su Min;Hong, Jin Woong
    • Transactions on Electrical and Electronic Materials
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    • 제18권2호
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    • pp.89-92
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    • 2017
  • The performance of three-layered organic light-emitting diodes (OLEDs) was investigated using TPD hole-transport and injection layers, Teflon-AF, and the electron-injection layer of $Li_2CO_3$ and LiF. The OLEDs were manufactured in a structure of TPD/$Alq_3$/LiF, TPD/$Alq_3$/$Li_2CO_3$, and AF/$Alq_3$/LiF using low-molecular organic materials. In three different three-layered OLEDs, it was found that the device with the TPD/$Alq_3$/LiF structure shows higher performance in maximum luminance, and maximum external quantum efficiency compared to those of the device with TPD/$Alq_3$/$Li_2CO_3$ and TPD/$Alq_3$/LiF by 35% and 17%, and 193% and 133%, respectively. It is thought that the combined LiF/Al cathode contributes to a reduced work function and improves an electrical conduction mechanism due to the electron injection rather than the hole transport, which then increases a recombination rate of charge carriers.

EFFECTS OF NOVEL DITHIOL MALONATE DERIVATIVES ON LIVER LIPID PEROXIDATION AND ON MICROSOMAL ELECTRON TRANSPORT SYSTEM

  • Park, Keun-Hee;Lee, Jong-Wook
    • Toxicological Research
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    • 제3권2호
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    • pp.97-110
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    • 1987
  • The effects of 5 novel hepatotrophic agents, dithiol malonate derivatives (DMDs; DMD1-DMD5), on the liver microsomal lipid peroxidation induced by carbon tetrachloride $(CCl_4)$ and the correlations with the changes of microsomal electron transport system were investigated. All DMDs were found to inhibit the lipid peroxidation induced by $CCl_4$ in mice and rats as well in vitro liver microsomal system. Therefore, each DMD seemed to have direct mode of action on liver microsomes to inhibit the lipid peroxidation. As an ex vivo study, the induced lipid peroxidation by $CCl_4$ and the changes in electron transport system were determined with liver microsomes obtained from rats chronically treated with DMDs for 7 days. The induced lipid peroxide contents in liver microsomal system were lower in DMD1, DMD2 and DMD3 treated group, but higher in DMD4 and DMD5 group when compared to the control group. Cyt. p.450 contents in the microsomes were decreased by the treatment with DMD1, DMD2 and DMD3, but increased significantly by DMD4 with great extent and by DMD5 with less extent. The cyt. p-450 isozymes induced by treatment of DMD4 and DMD5 were identified as 3-methylcholanthrene (MC) type. The NADPH cyt. -C reductase activities of the microsomes treated with DMD1, DMD2, DMD4 and DMD5 were increased in the range of around 20% to 50%, but decreased with DMD3, All DMDs increased dyt. $-b_5$ content and did not alter NAdH-cyt, $-b_5$ reductase activities in the microsomes. In summary, the 5 novel hepatotrophic agents (DMDs) markedly protected against lipid peroxidation induced by $CCl_4$ in vivo and in vitro possibly through the mechanism of direct action on the liver microsomes. The degree of inhibition produced by DMDs on lipid peroxidation induced by $CCl_4$ seemed to coincide rather with cyt. p-450 contents than with other components of liver microsomal electron transport system including NADPH-cyt, -C reductase.

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