• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.25-26
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• 2005

This study suggested the occurrence source of weld-defects and its solution methods in a welding of Electrolyte injection hole by pulsed Nd:YAG laser. In experiment, the ramp down was used in order that solidification crack was removed. Furthermore, shrinkage stress and heat input were reduced by changing of weld trajectory and defocused distance. As a results of a experiment, a sound weld bead shape and crack-free weld bead can be obtained.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.6
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• pp.740-745
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• 2006

This study suggested the occurrence source of weld-defects and its solution methods in a welding of Electrolyte injection hole by pulsed Nd:YAG laser. In experiment, the ramp down was used in order that solidification crack was removed. Furthermore. shrinkage stress and heat input were reduced by changing of weld trajectory and defocused distance. As a results of a experiment, a sound weld bead shape and crack-free weld bead can be obtained. In conclusion this show that the welding stability is greatly affected by modulation of laser pulse shape for the same laser energy and welding parameters.

• Proceedings of the Korean Society of Laser Processing Conference
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• 2005.06a
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• pp.45-47
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• 2005

• Proceedings of the Korean Society of Laser Processing Conference
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• 2005.11a
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• pp.42-45
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• 2005

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.88.2-88.2
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• 2010

Dye-sensitized solar cells (DSSCs) have attracted considerable attention on account of their high solar energy-to-conversion efficiencies and low cost processes compared to conventional p-n junction solar cells. The mechanism of DSSC is based on the injection of electrons from the photo excited dyes into the conduction band of the semiconductor electrode. The oxidized dye is reduced by the hole injection into either the hole conductor or the electrolyte. Thus, the light harvesting effect of dye plays an important role in capturing the photons and generating the electron/hole pair, as well as transferring them to the interface of the semiconductor and the electrolyte, respectively. We used the organic fluorescence materials which can absorb short wavelength light and emit longer wavelength region where dye sensitize effectively. In this work, the DSSCs were fabricated with fluorescence materials added $TiO_2$ photo-electrode which were sensitized with metal-free organic dyes. The photovoltaic performances of fluorescence aided DSSCs were compared, and the recombination dark current curves and the incident photon-to-current (IPCE) efficiencies were measured in order to characterize the effects of the additional light harvesting effect in DSSC. Electro-optical measurements were also used to optimize the fluorescence material contents on TiO2 photo-electrode surface for higher conversion efficiency (${\eta}$), fill factor (FF), open-circuit voltage (VOC) and short-circuit current (ISC). The enhanced light harvesting effect by the judicious choice/design of the fluorescence materials and sensitizing dyes permits the enhancement of photovoltaic performance of DSSC.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.5
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• pp.623-628
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• 2006

Laser material processing is a very fast advancing technology for various industrial applications. because of many advantages. Its major advantage of less and controlled heat input has been exploited successfully for the very critical application of aluminium alloy welding. This study suggested the occurrence source of weld-defects and its solution methods in a welding of lithium ion battery by pulsed Nd:YAG laser. In experiment. battery case has changed over joint geometry from welding of side position to flat one. In the case of a electrolyte injection hole in order to seal it. welding is carried out after pressing Al ball. At this time. an eccentric degree. contact length and gap are worked as a major parameters. As improving the method of Al ball pressing. it was able to reduce an eccentricity. increase the contact length and decrease gap. As a results of a experiment. a sound weld bead shape and crack-free weld bead can be obtained.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.339-343
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• 2005

Laser material processing is a very fast growing technology for various industrial applications, because of many advantages. Its major advantage of less and controlled heat input has been exploited successfully for the very critical application of aluminium alloy welding. This study suggested the occurrence source of weld-defects and its solution methods in a welding of lithium ion battery by pulsed Nd:YAG laser. In experiment, battery case has changed over joint geometry from welding of side position to flat one. In case of a electrolyte injection hole in order to seal it, welding is carried out after pressing Al ball. At this time, an eccentric degree, contact length and gap are worked as a major parameters. As improving the method of Al ball pressing, it was able to reduce an eccentricity, increase the contact length and decrease gap. As a results of a experiment, a sound weld bead shape and crack-free weld bead can be obtained.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.89.1-89.1
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• 2010

Since Gratzel and co-workers developed a new type of solar cell based on the nanocrystalline $TiO_2$ electrode, dye-sensitized solar cells (DSSCs) have attracted considerable attention on account of their high solar energy-to-conversion efficiencies (11%), their easy manufacturing process with low cost production compared to conventional p-n junction solar cells. The mechanism of DSSC is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline $TiO_2$. The oxidized dye is reduced by the hole injection process from either the hole counter or electrolyte. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO gap, of dye molecule in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. To date, high performance and good stability of DSSC based on Ru-dyes as a photosensitizer had been widely addressed in the literatures. DSSC with Ru-bipyridyl complexes (N3 and N719), and the black ruthenium dye have achieved power conversion efficiencies up to 11.2% and 10.4%, respectively. However, the Ru-dyes are facing the problem of manufacturing costs and environmental issues. In order to obtain even cheaper photosensitizers for DSSC, metal-free organic photosensitizers are strongly desired. Metal-free organic dyes offer superior molar extinction coefficients, low cost, and a diversity of molecular structures, compared to conventional Ru-dyes. Recently, novel photosensitizers such as coumarin, merocyanine, cyanine, indoline, hemicyanine, triphenylamine, dialkylaniline, bis(dimethylfluorenyl)-aminophenyl, phenothiazine, tetrahydroquinoline, and carbazole based dyes have achieved solar-to-electrical power conversion efficiencies up to 5-9%. On the other hand, organic dye molecules have large ${\pi}$-conjugated planner structures which would bring out strong molecular stacking in their solid-state and poor solubility in their media. It was well known that the molecular stacking of organic dyes could reduce the electron transfer pathway in opto-electronic devices, significantly. In this paper, we have studied on synthesis and characterization of dendritic organic dyes with different number of electron acceptor/anchoring moieties in the end of dendrimer. The photovoltaic performances and the incident photon-to-current (IPCE) of these dyes were measured to evaluate the effects of the dendritic strucuture on the open-circuit voltage and the short-circuit current.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.117.2-117.2
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• 2011

Since Gratzel and co-workers developed a new type of solar cell based on the nanocrystalline TiO2 electrode, dye-sensitized solar cells (DSSCs) have attracted considerable attention on account of their high solar energy-to-conversion efficiencies (11%), their easy manufacturing process with low cost production compared to conventional p-n junction solar cells. The mechanism of DSSC is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline TiO2. The oxidized dye is reduced by the hole injection process from either the hole counter or electrolyte. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO gap, of dye molecule in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. To date, high performance and good stability of DSSC based on Ru-dyes as a photosensitizer had been widely addressed in the literatures. DSSC with Ru-bipyridyl complexes (N3 and N719), and the black ruthenium dye have achieved power conversion efficiencies up to 11.2% and 10.4%, respectively. However, the Ru-dyes are facing the problem of manufacturing costs and environmental issues. In order to obtain even cheaper photosensitizers for DSSC, metal-free organic photosensitizers are strongly desired. Metal-free organic dyes offer superior molar extinction coefficients, low cost, and a diversity of molecular structures, compared to conventional Ru-dyes. Recently, novel photosensitizers such as coumarin, merocyanine, cyanine, indoline, hemicyanine, triphenylamine, dialkylaniline, bis(dimethylfluorenyl)-aminophenyl, phenothiazine, tetrahydroquinoline, and carbazole based dyes have achieved solar-to-electrical power conversion efficiencies up to 5-9%. On the other hand, organic dye molecules have large ${\pi}$-conjugated planner structures which would bring out strong molecular stacking in their solid-state and poor solubility in their media. It was well known that the molecular stacking of organic dyes could reduce the electron transfer pathway in opto-electronic devices, significantly. In this paper, we have studied on synthesis and characterization of dendritic organic dyes with different number of electron acceptor/anchoring moieties in the end of dendrimer. The photovoltaic performances and the incident photon-to-current (IPCE) of these dyes were measured to evaluate the effects of the dendritic strucuture on the open-circuit voltage and the short-circuit current.