• Bulletin of the Korean Chemical Society
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• 제22권2호
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• pp.189-193
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• 2001

The irreversible capacities caused by the reduction of solvent on the surface of a negative electrode (KMFC:Kawasaki Mesophase Fine Carbon) were examined during the initial cycle in ethylene carbonate (EC)-diethyl carbonate (DEC) electrolyte solut ions at various concentrations of LiPF6. Chronopotentiograms, linear sweep voltammograms, and impedance spectra clearly showed differences in irreversible capacity and that those differences are related to the concentration of electrolyte during the initial charge. These differences were caused by the amount of solvent decomposition as a function of the concentration of LiPF6 electrolytic salt. The data are discussed with reference to the concentration of electrolytic salt and the properties of passivation film formed by solvent decomposition.

• 한국기계가공학회지
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• 제7권4호
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• pp.121-127
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• 2008

Automatic grease lubricator is an equipment that provides adequate amount of fresh grease constantly to the shaft and bearings of machines. It minimizes the friction heat and reduces the friction loss of machines to the least. This paper is developing an automatic grease lubricator using a mode of the gas generation type from galvanic electricity. The ultimate goal of this equipment is to lubricate an adequate amount of grease with galvanic corrosion. In an electrolyte, combining anode(Mo) with cathode(Zn) is pressing out hydrogen gas of an galvanic element with galvanic reaction. The characteristics of this method is continuous flowing small hydrogen gas and controling the usage of the amount of the generation of hydrogen gas. The exterior body of grease lubricator was analyzed by Digital Mock-up of CATIA V5 and finite element analysis. The maximum stress is distributed over the outlet part where the grease lubricator suddenly narrowly contracts. The outlet part is analyzed with different constructed angle due to the different loading and setting angles. Using the analyzed design, RP trial products were producted and tested.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.547-548
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• 2006

This study focuses on a determination of amount of Pt in the Pt/C for catalysts of polymer electrolyte membrane fuel cells (PEMFC). PEMFC offer low weight and high power density and being considered fur automotive and stationary power applications. The PEMFC behavior is quite complex is influenced by several factors, including catalysts and structure of electrode and membrane type. Catalyst of electrode is important factor for PEMFC. One of the obstacles preventing polymer electrolyte membrane fuel cells from commercialization is the high cost of noble metals to be used as catalyst, such as platinum. To effectively use these metals, they have to be will dispersed to small particles on conductive carbon supports. The optimal amount of Pt in Pt/C was investigated by using polarization curves in single cell with $H_2/O_2$ operation.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.592-598
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• 2011

Electrode of solid oxide fuel cell must have sufficient porosity to allow gas transport to the interface with electrolyte effectively but high porosity has a negative impact on structural stability in electrode support. Thus, the upper limit of porosity is based on consideration of mechanical strength of electrode. In this study, the effect of microstructure of Ni-YSZ anode supported SOFC on the mechanical and electrical property was investigated. LSCF composite cathode and 8YSZ electrolyte were used. The porosity of the anode was modified by the amount of graphite powder and added graphite contents were 24, 18, 12 vol%, respectively. The higher the porosity, the better the electrical performance, $P_{max}$. While the flexural strength decreased with increasing the amount of graphite. But the rate of increase in electrical performance and the rate of decrease in mechanical strength were not directly proportional to amount of graphite. The optimum graphite content incorporating both electrical and mechanical performance was 18 vol%.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.96-98
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• 2006

Proper water management is vital to achieve high performance and durability of PEFC (Polymer Electrolyte Fuel Cell). The effects of the residual water from PEFC after purge in shut-down processes on GDL/MEAs were investigated with freeze/thaw cycles Freeze/thaw cycle tests were conducted with single cells which were designed from transparent acryl plates. Single cells which contain several amount of residual water were cycles from $80^{\circ}C$ to $-28^{\circ}C$. The resistance changes of the single cells which have various amount of residual water were evaluated by ac-impedance analysis with 24 times of freeze/thaw cycles. Also, after the freeze/thaw cycles, the property changes were characterized by visual methods such as SEM, EPMA. Though it was difficult to observe noticeable property changes in the visual characterizations, the resistance of cells dramatically increased with the amount of remained water.

• 자원리싸이클링
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• 제17권5호
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• pp.60-65
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• 2008

고순도 동 제조를 위해 황산동 전해액중에 존재하는 은(Ag)을 제거하기 위한 기초연구를 실시하였다. 이온교환수지법, 활성탄 흡착법, 구리분말 및 세선을 이용한 치환법, CuS침전법 등을 이용하여 Ag제거에 대한 실험을 실시하였으며, 은(Ag)제거 반응에 영향을 미칠 수 있는 반응온도, 반응시간, 첨가량 등에 대해 고찰하였다. 이들 방법중 CuS 침전법과 Lewatit TP214를 이용한 이온교환수지 방법이 효과적이었는데 특히 Lewatit TP214를 사용한 경우 초기 동전해액중, Ag 농도가 10ppm서 0.1ppm 이하 수준까지 제거가 가능하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.89.1-89.1
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• 2011

The influence of potential and humidity on the electrochemical carbon corrosion in high temperature polymer electrolyte membrane fuel cells(HT-PEMFCs) is investigated by measuring $CO_2$ emission at different potentials for 30 min using on-line mass spectrometry. These results are compared with low tempterature polymer electrolyte membrane fuel cells(LT-PEMFCs) operated at lower temperature and higher humidity condition. Although the HT-PEMFC is operated at non humidified condition, the emitted $CO_2$ in the condition of HT-PEMFC is more than LT-PEMFC at the same potential in carbon corrosion test. Thus, carbon corrosion shows a stronger positive correlation with the cell temperature. In addition, the presence of a little amount of water activate electrochemical carbon corrosion considerably in HT-PEMFC. With increased carbon corrosion, changes in fuel cell electrochemical characteristics become more noticeable and thereby indicate that such corrosion considerably affects fuel cell durability.

• Transactions on Electrical and Electronic Materials
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• 제16권3호
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• pp.135-138
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• 2015

A manganese dioxide (MnO₂) layer and zinc (Zn) layer are used as the cathode and the anode to develop filmtype manganese battery, in which a stack of a MnO₂ layer, gel electrolyte, and Zn layer are sandwiched between two plastic layers. This paper describes the chemical equation of swelling control upon the film-type manganese battery. We examined the reduction of hydrogen formation, by using calcium hydroxide Ca(OH)₂ as an additive in the electrolyte of film-type manganese battery. The phenomena or an effect of reduced hydrogen gas was proven by cyclic voltammogram, X-ray photoelectron spectra (XPS), and volume of hydrogen formation. The amount of H₂ gas generation in the presence of Ca²⁺ ion was reduced from 4.81 to 4.15 cc/g-zinc (14%), and the corrosion of zinc electrode in the electrolyte was strongly inhibited as time passed.

• 한국수소및신에너지학회논문집
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• 제17권2호
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• pp.141-148
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• 2006

This study was carried out to analyze the microstructure characteristics of electrolyte membrane through XRD, SEM and AC impedance measurement for using in high temperature steam electrolysis(HTE). It was investigated that thermal stability and electric characteristics by sintering condition using dry and wet process, and confirmed growth of particle and density change by sintering temperature. The sintering temperature and behavior had an effect on the relative density of the ceramic and the average grain size. The more amount of dispersant in organic compound increase, the more the density increased. But the binder was shown opposite phenomenon. It was analyzed that electrolyte resistance and electrical characteristics using AC impedance. The electrical properties of YSZ grain boundary changed with the sintering temperature.

• 한국세라믹학회지
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• 제46권6호
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• pp.648-652
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• 2009

Ceramic fiber separator is the promising material for thermal battery system because it reduces the production cost and offers the potential to a new application compared to a pellet type electrolyte. The electrolyte separator for thermal battery should be easily handled and loaded a large amount of the molten lithium salt. Ceramic fibers were used as an electrolyte separator and the lithium based molten salts were infiltrated into the ceramic filters. Leakage of molten salt (several lithium salts) leads to short-circuit during the thermal battery operation. In this study, a uniform and fine SiOC mat with fibers ranging from 1 to 3 ${\mu}m$ was obtained by electrospinning of polycarbosilane and pyrolysis. The optimum spinning conditions for obtaining fine diameters of SiOC fiber were controlled by the solution composition and concentration, applied voltage and spinning rate, release rate by porosity. The pore structures of the ceramic filter and the melting properties of the lithium salts affected to the electrolyte loading and leakage. The importance of the fiber size and porosity and their control was discussed and the mechanical properties were also discussed.