• Title/Summary/Keyword: Electrokinetic

Search Result 262, Processing Time 0.018 seconds

A study on Surfactants for Electrokinetic Soil Remediation (동전기적 토양복원에 적합한 계면활성제의 선정)

  • 이현호;박지연;김상준;이유진;양지원
    • Journal of Soil and Groundwater Environment
    • /
    • v.8 no.1
    • /
    • pp.1-8
    • /
    • 2003
  • Three different surfactants, APG, Brij30, and SDS, were tested to study the characteristics of sorption on soil surfaces, washing ability, biodegradability, and electrokinetic removal. Kaolinite and phenanthrene were selected as a model soil and a representative HOC, respectively. Phenanthrene was sorbed on kaolinite up to 2,200 mg/kg dry soil. The APG, Brij30, and SDS were sorbed on soil to 40, 7, and 4g/kg soil, respectively. The washing ability of phenanthrene was in order of Brij30>SDS>APG. The biodegradability tested with sludge was in order of APG>Brij30>SDS. In the electrokinetic test, the highest removal efficiency was obtained with APG that exhibited the highest electroosmotic flow. To increase the removal efficiency of HOC in the electrokinetic remediation, the most important factor was the selection of surfactant which maximized the electroosmotic flow.

The Variation of Density and Settlement for Contaminated Sediments During Electrokinetic Sedimentation and Remediation Processes (오염퇴적토에 대한 동전기적 침전 및 정화 공정에서의 시료 밀도 및 침하 변화 특성)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
    • /
    • v.22 no.9
    • /
    • pp.5-14
    • /
    • 2006
  • Generally, the sediments contain significant water, clay, colloidal fraction and contaminants, and can result in soft strata with high initial void, and its potential hazards in subsurface environments exist. Electrokinetic technique has been used in sedimentation for volume reduction of slurry tailing wastes and in remediation for extraction of contaminants from contaminated soils. In this research, the coupled effects of sedimentation and remediation of contaminated sediments are focused using electrokinetic sedimentation and remediation techniques from experimental aspects. A series of laboratory experiments including variable conditions such as initial solid content of the specimen, concentration level of the contaminant, and magnitude of applied voltage are performed with the contaminated sediment specimens mixed with ethylene glycol. Commercially available high specification Kaolin was used to simulate slurried sediment. From the test results, the settlement of specimen increases with increasing of applied voltage and decreasing of solid content and contamination level. The density of specimen increases due to settlement of specimen in the process of electrokinetic sedimentation and decreases due to extraction of organic contaminant in the process of electrokinetic remediation.

Electrokinetic deposition of individual carbon nanotube onto an electrode gap

  • Han Chang-Soo;Seo Hee-Won;Lee Hyung-Woo;Kim Soo-Hyun;Kwak Yoon-Keun
    • International Journal of Precision Engineering and Manufacturing
    • /
    • v.7 no.1
    • /
    • pp.42-46
    • /
    • 2006
  • This paper presents a method for deposition an individual carbon nanotube (CNT). The alignment of a single CNT is very useful to perform studies related to applications in FET (Field Emitted Transistor), SET (Single Electron Transistor) and to make chemical sensor as well as bio sensors. In this study, we developed the deposition method of a CNT individualized in a solution. Using the electrokinetic method, we found the optimum conditions to assemble the nanotube and discussed about plausible explanation for the assembling mechanism. These results will be available to use for making the CNT sensor device.

Effect of Acid Buffering Capacity and Soil Component Remediation of Soil Contaminated with Phenanthrene using Electrokinetic-Fenton Process (산 완충능력과 토양 성분이 동전기-펜톤 공정에 의한 phenanthrene 오염토양 정화에 미치는 영향)

  • Kim, Jung Hwan;Na, So Jeong;Park, Joo Yang;Byun, Young Deog
    • Journal of Soil and Groundwater Environment
    • /
    • v.18 no.1
    • /
    • pp.129-136
    • /
    • 2013
  • This research was conducted to investigate effects of acid buffering capacity and soil component in treatment of phenanthrene using electrokinetic-Fenton process. In Hadong clay of high acid buffering and low iron oxide content, it was difficult to oxidize phenanthrene due to shortage of iron catalyst and scavenger effect of carbonate minerals. The desorbed phenanthrene conductive to Fenton oxidation was transported toward cathode by electroosmotic flow. However, in Youngdong illitic clay, oxidation of phenanthrene near anode readily occurred compared to Hadong clay due to high iron content and low acid buffering capacity.

Electrokinetic streaming potential detection in a triangular-shaped microchannel (역삼각형 모양을 갖는 마이크로 채널에서의 전기역학적 흐름전위 검출)

  • Jo, Seong-Sik;Park, Je-Kyun
    • Journal of Sensor Science and Technology
    • /
    • v.16 no.2
    • /
    • pp.115-119
    • /
    • 2007
  • We report electrokinetic streaming potential detection in a microchannel. Streaming potential, one of the representative electrokinetic phenomena, becomes noticeable either when the channel size reduces or when the concentration of electrolyte reduces. We suggest a triangular-shaped microchannel to enhance streaming potential. The triangular-shaped microchannel shows better performance than the straight one in terms of streaming potential. Couple of possible methods to enhance streaming potential is also discussed. Moreover, this type of channel and phenomenon can be applied to biological sensor application and energy transduction.

Effect of Electrolyte Concentration on Surfactant-Enhanced Electrokinetic Removal of Phenanthrene

  • 이유진;박지연;김상준;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2004.04a
    • /
    • pp.346-349
    • /
    • 2004
  • Surfactant-enhanced electrokinetic (EK) process was investigated to remove polycyclic aromatic hydrocarbons (PAHs) from low-permeable soils. Phenanthrene and kaolinite were selected as a representative PAH and a model soil, respectively. A nonionic surfactant Tergitol 15-S-12 was applied to improve the solubility of phenanthrene and sodium chloride was used as an electrolyte at the various concentrations from 0.001 to 0.1M. The addition of electrolyte affected both the removal efficiency and operation cost. When electrolyte was introduced, the electrical potential gradient became low and thus power consumption was reduced. However, as electrolyte concentration increased, the electroosmotic flow also decreased, so the removal efficiency of contaminant decreased. Therefore, the removal efficiency and power consumption should be considered simultaneously to determine the iptimum surfactant concentration, so a relatively lower concentration of electrolyte than certain value is desired.

  • PDF

Increase in Color Depth and Analysis of the Interfacial Electrokinetic Potential of Poly(Ethylene Terephthalate) Fabric by Plasma Treatment (폴리에스테르 직물의 저온플라즈마 처리에 따른 계면동전위와 심색성 향상에 관한 연구)

  • Jeon, Sang-Min;Lee, Ki-Poong;Gu, Kang
    • Textile Coloration and Finishing
    • /
    • v.15 no.4
    • /
    • pp.1-7
    • /
    • 2003
  • We investigated the effect of color depth on polyester fabrics by plasma treatment. In this study, although it have many paper about effects of plasma treatment, we observed interfacial electrokinetic potential of polyester fabrics by plasma treatment and also we investigated relationship between deep coloring agent and plasma treatment to get the effect of color depth on polyester fabrics. The results obtained are as follows, 1. Plasma treatment did not enhanced the effect of color depth of polyester fabrics by plasma treatment independently. 2. In the case of using the deep coloring agent with plasma treatment on polyester fabrics, lightness was more decreased than using the deep coloring agent itself. 3. Plasma treatment could not affect surface shape and tensile strength of treated polyester fabrics.

Studies on the Electrochemical Properties of Indigo Dye (인디고 염료의 전기화학적 특성 연구)

  • Lee Song Ju;Jang Hong Gi;Heo Buk Gu;Park Dong Won
    • Textile Coloration and Finishing
    • /
    • v.17 no.4 s.83
    • /
    • pp.1-6
    • /
    • 2005
  • We studied the degree of variety of indigo for the electrochemical redox reaction in addition of reducing agent and the electrokinetic parameters. The electrokinetic parameters such asthe number of electron and the exchange rate constant were obtained by cyclic voltammetry. With increasing scan rate, the reduction currents of indigo were increased and the reduction potentials were shifted to the negative direction. As the results, the reduction processes of the indigo were proceeding to totally irreversible and diffusion controlled reaction. Also, exchange rate constant ($k^0$) and diffusion coefficient ($D_0$) of indigo were decreased by increasing concentration of reducing agent. We found that the less concentration, the more easily diffused and electron transferred and the product was more stable.

Cd으로 오염된 토양의 EK 정화시 Humic acid가 미치는 영향

  • 구한모;김정환;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2001.09a
    • /
    • pp.131-134
    • /
    • 2001
  • This research was carried out to evaluate the effects of humic acid on contaminated kaoline with cadmium when electrokinetic remediation. Electrokinetic remediation test was performed depending on humic acid concentrations(0.005, 0.01, 0.05, 0.083, 0.1, 0.5, 5.0mg/g) in contaminated kaoline with cadmium and time(4, 8, 12days). In the absence of humic acid, Cd at the anode showed the highest concentration while Cd concentrations were lower as the concentration of humic acid increased. The removal of Cd to the anode reservoir was increased with increasing humic acid concentration by electroosmosis or ion migration.

  • PDF

Electrokinetic-Fenton 기법에 의한 phenanthrene으로 오염된 토양의 처리

  • 김정환;김강호;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2001.09a
    • /
    • pp.51-54
    • /
    • 2001
  • This research was carried out to evaluate feasibility of using an Electrokinetic-Fenton(EK-Fenton) technique to treat hydrophobic organic pollutant(phenanthrene) from soils. Experiment examined the effect by introducing a continuous flow of a 3.5% hydrogen peroxide solution at the anode. An electric gradient of 1V/cm was applied to enhance the saturated flow in the soil cell for a period of 11 days. After 11 days or 1 pore volume, overall concentration of residual phenanthrene in the soil cell was 11% and residual phenanathrene concentration in the soil was found to increase with toward the cathode. This results indicated that Fenton-like reaction catalyzed by mineral surface was effective in oxidizing phenanthrene. This results also showed that hydrogen peroxide was effectively transported into the soil by electroosmotic flow as well as by diffusion.

  • PDF