• 제목/요약/키워드: Electrode treatment

검색결과 693건 처리시간 0.036초

Fetal Bovine Serum을 포함한 세포 배양액에 담근 Indium Tin Oxide 전극 계면의 전기화학적 특성 (Electrochemical Properties of Indium Tin Oxide Electrodes Immersed in a Cell Culture Medium with Fetal Bovine Serum)

  • 최원석;조성보
    • 대한의용생체공학회:의공학회지
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    • 제34권1호
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    • pp.34-39
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    • 2013
  • For the biocompatibility test of implantable devices or for the sensitivity evaluation of biomedical sensors, it is required to understand the mechanism of the protein adsorption and the interaction between the adsorbed proteins and cells. In this study, the adsorption of proteins in a cell culture medium with fetal bovine serum onto an indium tin-oxide electrode was characterized by using linear sweep voltammetry and impedance spectroscopy. We immersed the fabricated ITO electrodes in the culture medium for 30, 60, or 90 min, and then measured the electrochemical properties of electrodes with 10 mM $Fe(CN){_6}^{3-/4-}$ and 0.1 M KCl electrolyte. With an increase of contacting time, the anodic peak current was decreased and the charge transfer resistance was increased. However, both parameters were recovered to the values before contact with the medium after the treatment of Trypsin/Ethylenediaminetetraacetic acid hydrolyzing proteins.

주사바늘 전극형 오존발생기 특성 연구 (Observation and Characteristics of Ozonizer using Injection Needle Electrode)

  • 박현미;권영학;박원주
    • 조명전기설비학회논문지
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    • 제29권12호
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    • pp.77-82
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    • 2015
  • Ozone is a powerful disinfectant and oxidizing agent, and it is used in a wide range of applications, such as waste water treatment, food processing, etc.. There is also a great potential of using ozone in new emerging medical applications, such as ozone dentistry and ozone oxygen therapy. For these purposes, simple, small, compact and efficient sources of ozone are needed. In this study, in order to increase the current-voltage range of the discharge and to avoid the overheating of the gas in the ozonizer we suggested ozonizer of injection needle and plate electrode type(INP Type) with the gas through the needle. A ozonizer of INP type have been investigated by focusing on ozone concentration and yield according to flow rates and Gap of two electrodes. The results of studies of ozone production for DC corona discharge in oxygen at atmospheric pressure about the ozonizer of INP type. The ozone concentration and the generation yield increased as the gap of two electrodes and gas flow were decreased. Also, when the gap of two electrodes and gas flow with no change, the ozone concentration and generation yield each have variation of direct proportion and inverse proportion with discharge voltage.

Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals [(Ni (II), Pb (II), Cd (II)] by Electrocoagulation Method

  • Khosa, Muhammad Kaleem;Jamal, Muhammad Asghar;Hussain, Amira;Muneer, Majid;Zia, Khalid Mahmood;Hafeez, Samia
    • 대한화학회지
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    • 제57권3호
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    • pp.316-321
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    • 2013
  • Electrocoagulation (EC) technique is applied for the treatment of wastewater containing heavy metals ions such as nickle (Ni), lead (Pb) and cadmium (Cd) by using sacrificial anodes corrode to release active coagulant flocs usually aluminium or iron cations into the solution. During electrolytic reactions hydrogen gas evolve at the cathode. All the experiments were carried out in Batch mode. The tank was filled with synthetic wastewater containing heavy metals and efficiency of electro-coagulation in combination with aluminum and iron electrodes were investigated for removal of such metals. Several parameters, such as contact time, pH, electro-coagulant concentration, and current density were optimized to achieve maximum removal efficiency (%). The concentrations of heavy metals were determined by using Atomic Absorption Spectroscopy (AAS). It is found that the electro-coagulation process has potential to be utilized for the cost-effective removal of heavy metals from wastewater specially using iron electrodes in terms of high removal efficiencies and operating cost.

Treatment of Rice Mill Wastewater Using Continuous Electrocoagulation Technique: Optimization and Modelling

  • Karichappan, Thirugnanasambandham;Venkatachalam, Sivakumar;Jeganathan, Prakash Maran;Sengodan, Kandasamy
    • 대한화학회지
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    • 제57권6호
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    • pp.761-768
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    • 2013
  • Removal of COD and TSS from rice mill wastewater was investigated using continuous electrocoagulation method (CEC). The electrical energy consumption (EEC) of the process was also examined in order to evaluate the economic viability. The Box-Behnken statistical experiment design (BBD) and response surface methodology (RSM) were used to investigate the effects of major operating variables. Initial pH, current density, electrode distance and flow rate were selected as independent variables in BBD while COD removal, TSS removal and EEC were considered as the response functions. The predicted values of responses obtained using the response function was in good agreement with the experimental data. Optimum operating conditions were found to be pH of 7, current density of 15 mA $cm^{-2}$, electrode distance of 5 cm and flow rate of 70 ml/min. Under these conditions, greater than 89% removal of COD and TSS were obtained with EEC value of 7 KWh.

무정형 탄소의 입도분포에 따른 리튬이온이차전지의 탄소부극 특성 (The Effect of Particle Size Distribution of the Nongraphitic Carbon on the Performance of Negative Carbon Electrode in Lithium Ion Secondary Battery)

  • 김현중;이철태
    • 공업화학
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    • 제9권5호
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    • pp.781-785
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    • 1998
  • 무정형탄소인 petroleum cokes를 대상으로 attrition mill을 이용하여 6~48시간 동안 분쇄한 후 이를 $700^{\circ}C$에서 1시간 동안 열처리한 후 재료특성과 전기화학적 특성을 조사하였다. 분쇄에 의한 효과에 의하여 입도분포와 BET 비표면적의 변화가 발생하였으며 내부의 층간거리도 변화시킬 수 있었다. 이들의 재료특성 변화에 의한 cyclic voltammogram과 충 방전 특성과의 관계를 조사한 결과, 분쇄시간 12~24시간에서 분쇄된 후의 경우가 $6{\sim}8{\mu}m$의 평균입도를 가지며 비교적 큰 층간거리와 표면적을 가질 때 전기화학적 특성이 비교적 우수하였다.

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Effects of surface modification of $Nafion^{(R)}$ Membrane on the Fuel Cell Performance

  • Prasanna, M.;Cho, E.A.;Ha, H.Y.;Hong, S.A.;Oh, I.H.
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2004년도 추계 학술발표회 논문집
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    • pp.133-138
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    • 2004
  • Proton exchange membrane fuel cell (PEMFC) is considered as a clean and efficient energy conversion det ice for mobile and stationary applications. Anions all the components of the PEMFC, the interface between the electrolyte ,and electrode catalyst plays an important role in determining tile cell performance since the electrochemical reactions take place at the interface in contact with tile reactant gases. Therefore, to increase the interface area and obtain a high-performance PEMFC, surface of the electrolyte membrane was roughened by Ar$^{+}$ beam bombardment. The results imply that by modifying surface of the electrolyte membrane, platinum loading can be reduced significantly without performance loss. To optimize the surface treatment condition, effects of ion dose density on characteristics of the membrane/electrode interface were examined by measuring the cell performance, impedance spectroscopy, and cyclic voltammograms. Surface of the modified membranes were characterized using scanning electron microscopy and FT-IR.R.

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Analysis of Failed Spinal Cord Stimulation Trials in the Treatment of Intractable Chronic Pain

  • Jang, Hyun-Dong;Kim, Min-Su;Chang, Chul-Hoon;Kim, Sang-Woo;Kim, Oh-Lyong;Kim, Seong-Ho
    • Journal of Korean Neurosurgical Society
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    • 제43권2호
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    • pp.85-89
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    • 2008
  • Objective: The purpose of this study is to identify the factors affecting the failure of trials (<50% pain reduction in pain for trial period) to improve success rate of spinal cord stimulation (SCS) trial. Methods: A retrospective review of the failed trials (44 patients, 36.1 %) among the patients (n=122) who underwent SCS trial between January 1990 and December 1998 was conducted. We reviewed the causes of failed trial stimulation, age, sex, etiology of pain, type of electrode, and third party support. Results: Of the 44 patients, 65.9% showed unacceptable pain relief in spite of sufficient paresthesia on the pain area with trial stimulation. Four of six patients felt insufficient paresthesia with stimulation had the lesions of the spinal cord. Seventy five percent of the patients experienced unpleasant or painful sensation during stimulation had allodynia dominant pain. Third-party involvement, sex, age and electrode type had no influence on the outcome. Conclusion: We conclude that SCS trial is less effective for patients with neuropathic pain of cord lesions, postherpetic neuropathy or post-amputation state. Further, patients with allodynia dominant pain can feel unpleasant or painful during trial stimulation.

Structural Investigations of $RuO_2$ and Pt ad Films fir the Applications of memory Devices

  • S. M. Jung;Park, Y. S.;D. G. Lim;Park, Y.;J. Yi
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1998년도 PROCEEDINGS OF THE 14TH KACG TECHNICAL MEETING AND THE 5TH KOREA-JAPAN EMGS (ELECTRONIC MATERIALS GROWTH SYMPOSIUM)
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    • pp.57-60
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    • 1998
  • Lean zirconate titanate (PZT) is an attractive material for the memory device applications. We have investigated Pt and{{{{ { RuO}_{2 } }}}} as a botton electrode for a device application of PZT thin film. The bottom electrodes were prepared by using an RF magnetron sputtering method. The substrate temperature influenced the resistivity of Pt and {{{{ { RuO}_{2 } }}}} a s well as the film crystal structure. XRD examination shows that a preferred(111) orientations for the substrate temperature of 30$0^{\circ}C$. From the XRD and AFM results, we recommend the substrate temperature of 30$0^{\circ}C$ for the bottom electrode growth. We investigated and anneal temperature effect because Perovskite PZT structure is recommended for the memory device applications and the structural transformation is occurred only after and elevated heat treatment. As post anneal temperature was increased from RT to $700^{\circ}C$, the resistivity of Rt and {{{{ { RuO}_{2 } }}}} w as decreased. Surface morphology was observed by AFM as a function of post anneal temperature.

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삼인산 나트륨과 아질산 나트륨에 의한 탄소강 부식방지 특성 연구 (Study on The Corrosion Inhibition Characteristics of Carbon Steel by Sodium Phosphate And Sodium Nitrite)

  • 문전수;이재근
    • Corrosion Science and Technology
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    • 제9권3호
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    • pp.137-141
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    • 2010
  • Sodium nitrite is widely used as one of the popular corrosion inhibitors for the protection of ferrous metal in closed cooling water system, such as a diesel engine and a chiller. The optimum treatment conditions are studied through laboratory tests using linear polarization resistance (LPR) technique. Corrosion rate of the carbon steel electrode could be maintained less than $2.5{\times}10^{-3}$ mmpy in the test condition of 500 ppm as ${NO_2}^-$, 200 ppm as $Cl^-$, $70^{\circ}C$ and pH 6.8. The pH control is confirmed not to be an important factor in the protection of carbon steel by sodium nitrite inhibitor. The addition of tolyltriazole was needed for the protection of the copper alloy in the sodium nitrite treatment system.

선택적 표면처리와 딥코팅 방법을 이용한 고해상도 금속 패턴 형성연구 (Patterning of high resolution metal electrodes using selective surface treatment and dip casting for printed electronics)

  • 김영훈;엄유현;박성규;오민석;강정원;한정인
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1340_1341
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    • 2009
  • In this report, high-resolution metal electrode patterning is demonstrated by using selective surface treatment and dip casting for low-cost printed electronic applications. On hydrophobic octadecyltrichlorosilane treated $SiO_2$ surface, deep UV irradiation was performed through a patterned quartz photomask to selectively control the surface energy of the $SiO_2$ layer. The deep UV irradiated region becomes hydrophilic and by dipping into Ag nano-ink, Ag patterns were formed on the surface. Using this patterning technique, line patterns and dot arrays having less than $10{\mu}m$ pitch were fabricated.

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