• Title/Summary/Keyword: Electrode performance.

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Improvement of Cathode Reaction of Vanadium Redox Flow Battery by Reforming Graphite Felt Electrode Using Cobalt Oxide (바나듐 레독스 흐름전지 양극 반응 향상을 위한 코발트 산화물 전극 개질법 연구)

  • Park, Jeongmok;Ko, Minseong
    • Journal of the Korean institute of surface engineering
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    • v.52 no.3
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    • pp.180-185
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    • 2019
  • The demands to improve the performance of the vanadium redox flow battery have attracted an intense research on modifying the carbon-based electrode. In this study, the surface of graphite felt was reformed, using cobalt oxide. The cobalt oxide was implanted into graphite felt during hydrothermal and two step heat treatments. The cobalt was deposited by hydrothermal method and the two step heat treatments made lots of holes on the graphite felt surface which is called as porous surface. The porous surface acts as an electrochemically active site for the cathodic reaction of vanadium redox flow battery. The reformed electrode shows the electrochemically improved performance compared with the pristine electrode.

Enzyme-Free Glucose Sensing with Polyaniline-Decorated Flexible CNT Fiber Electrode (Polyaniline을 이용한 CNT fiber 유연 전극 기반의 비효소적 글루코스 검출)

  • Song, Min-Jung
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.1-6
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    • 2022
  • As the demand for wearable devices increases, many studies have been studied on the development of flexible electrode materials recently. In particular, the development of high-performance flexible electrode materials is very important for wearable sensors for healthcare because it is necessary to continuously monitor and accurately detect body information such as body temperature, heart rate, blood glucose, and oxygen concentration in real time. In this study, we fabricated the nonenzymatic glucose sensor based on polyaniline/carbon nanotube fiber (PANI/CNT fiber) electrode. PANI layer was synthesized on the flexible CNT fiber electrode through electrochemical polymerization process in order to improve the performance of a flexible CNT fiber based electrode material. Surface morphology of the PANI/CNT fiber electrode was observed by scanning electron microscopy. And its electrochemical characteristics were investigated by chronoamperometry, cyclic voltammetry, electrochemical impedance spectroscopy. Compared to bare CNT fiber electrode, this PANI/CNT fiber electrode exhibited small electron transfer resistance, low peak separation potential and large surface area, resulting in enhanced sensing properties for glucose such as wide linear range (0.024~0.39 and 1.56~50 mM), high sensitivity (52.91 and 2.24 ㎂/mM·cm2), low detection limit (2 μM) and good selectivity. Therefore, it is expected that it will be possible to develop high performance CNT fiber based flexible electrode materials using various nanomaterials.

A Study on the Gap Voltage and Machining Stability in Diesinking Electrical Discharge Machining (형조 방전가공에서 극간 전압과 가공 안정성에 관한 연구)

  • 김광열;이상민;이건기
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.3
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    • pp.429-436
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    • 2003
  • The electrical discharge machining(EDM) with Si electrode instead of Gr or Cu electrode. made enormous effects on the surface. machining time, anti-caustic workpiece surface and so on In this paper. we experimented on the inter-role distance during discharge the electrical phenomenon of inter-pole, the distribution of discharge point. the distribution of off load time. etc., using Si electrode Cu electrode and Gr electrode under the same machining condition. As a result of a large quantity generated exclusive powders. the performance of the EDM using Si electrode. compared with EDM using others. is improved. We show that the quantities of those make far pole-gap discharge and discharge scatter under stable machining status possible.

Electrical Propeties of Supercapacitor using Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 Supercapacitor의 전기적 특성)

  • 강광우;김명산;김종욱;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.764-769
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapactior cell of CP composite electrode with 1M LiClO$_4$/PC brings out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 15Wt% SP270(PAnS15) and PT composite electrode adding 50%wt% SP270(PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/$\textrm{cm}^2$, respectively.

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Study of the Application of Gel Electrolyte in the Reference Electrode of $Cu/CuSO_4$

  • Lin, Cunguo;Xu, Likun;Liu, Yang
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.179-181
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    • 2008
  • With nano-$SiO_2$ and sulphate acid, a kind of colloid electrolyte is synthesized by sol-gel method. It is placed outside the reference electrode as a layer of gel electrolyte so as to decrease the leaching of $Cu^{2+}$ and increase the life of the reference electrode. The performance of the gel electrode in simulating soil solution is measured as follows: the potential of the electrodes ranging from 60 mV to 80 mV (vs. SCE) with potential variation no more than $\pm10mV$, enough resistance to polarization. The $Cu^{2+}$ effusion rate of the reference electrode without gel electrolyte is 3 times that with colloid electrolyte, which means that gel electrolyte can extend the life of the reference electrode significantly.

Electrochemical Properties of Conducting Polymer for Supercapacitor (Supercapacitor용 도전성 고분자의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.332-334
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

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Electrical Properties of Supercapacitor with Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 supercapaccitor의 전기적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.487-490
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Electrochemical capacitor(supercapacitor) cell of CP composite electrode with 1M LiClO$_4$PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding l5wt%SP270(PAnS15) and PT composite electrode adding 50wt%SP270 (PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/cm$^2$. Supercapacitor cell with PTS50(+)/PAnS15(-) showed good capacitance and stability with cycling.

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Spraying Performance Evaluation of Spraying Nozzle Using Electrostatic Effect (정전효과를 이용한 분무노즐의 분무성능 평가)

  • 조성인;이동훈
    • Journal of Biosystems Engineering
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    • v.21 no.4
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    • pp.456-466
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    • 1996
  • Electrostatic spraying is needed for today's sustainable farming. An electrostatic spraying nozzle was developed and its spraying performance was evaluated. High voltages of 15㎸, 20㎸, and 25㎸ were supplied for the electrostatic electrode. Artificial and real apple targets were used for the spraying experiments. Insulated material was used around the electrode to protect the loss of electrostatic effect. Three angles (0, 45, 90 degree) of spraying direction were used for the spraying test. The performance of electrostatic spraying was improved from 204.5% upto 429.2% on the apple targets.

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Performance Investigation of Cylindrical-Type ER Valves With Different Electrode Length (전극길이 변화에 따른 실린더 형태 ER밸브의 성능고찰)

  • Jeon, Young-Sik
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.7 no.6
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    • pp.1-11
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    • 1998
  • This paper presents performance analyses of three types of the cylindrical-type ER(electro-rheo-logical) valves, which have different electrode length and width but same electrode area. Following the composition of silicone oil-based ER fluid, the field-dependent yield stresses are obtained from experimental investigation on the Bingham property of the ER fluid. The ER valve which is dependent on the applied electric field is devised and its theoretical model is derived. On the basis of the pressure-drop analysis, three types of the ER valves are designed and manufactured. After experimentally evaluation field-dependent pressure drops, PI controller is formulated to achieve tracking control on desired pressure drop. The controller is then experimentally implemented and tracking control performance is presented in order to demonstrate superior controllability of the ER valve. In addition, the response characteristic of the ER valve with respect to the excitation frequency of the electric fiedls is provided to show the feasibility of practical application.

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Performance of Pt/$WO_3$ and Pt-$WO_3$/C electrode systems for direct methanol fuel cell (직접메탄올 연료전지용 백금/삼산화텅스텐 및 백금-삼산화텅스턴/탄소 전극계의 성능 평가)

  • Lee, C.H.;Lee, C.W.;Jung, D.W.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1358-1360
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    • 1997
  • In this paper, the performance of Pt/$WO_3$ and Pt-$WO_3$ electrodes was studied for the direct methanol fuel cell. The characteristics of Pt/$WO_3$ electrode which was prepared by using electrodeposition method was tested with half-cell experiment. The characteristics of Pt-$WO_3$/C electrode which was Prepared by using freeze-drying method was tested with a single cell experiment. The performance of DMFC single cell which was prepared by Pt-$WO_3/C$ and Pt/C showed a current density of $32mA/cm^2$ at $110^{\circ}C$ & 0.3V(0.5mg Pt/$cm^2$).

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