• 한국표면공학회지
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• 제29권1호
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• pp.60-72
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• 1996

A photoetching process is widely used for small and high precision parts in machinery, electronic and semi-conductor industries. One of the high precision parts, grid is very important part of digitron which use electron display, and it is fabricated by only photoetching process because of high precision. In this study, to develop high precision digitron grid, characteristics of etching solution were investigated with electrochemical test, that was potentiodynamic test and immersion test in the ferric chloride solution and added some additives. Based on the electrochemical etching test, grid was fabricated by continuous photoetching process at various etching condition. From the result of measured line width and etching depth under-cut and etching factor were calculated. For the fabrication of 25$\mu\textrm{m}$ line width, optimal etching condition was etching temperature 40~$45^{\circ}C$, spray pressure 1.5kg/$\textrm{cm}^2$ and etching time 3~4min.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 1999년도 춘계학술대회 논문집
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• pp.263-268
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• 1999

With HAZ of A 106 Gr B steel weldment, fatigue test in air, electrochemical polarization test and corrosion fatigue test in 3.5wt.% NaCl solution were performed changing load ratio. Obtained results are as follows. 1) K$\sub$op/ was independent of K$\sub$max/ and load ratio in fatigue crack growth. 2) In variation of load ratio, the scatter band of crack growth curve was reduced by half considering crack closure 3) In the result of electrochemical polarization test, current density was increased abruptly when potential was larger than corrosion potential. 4) Fatigue crack growth rate in corrosive environment was markly higher than the rate in air because of corrosion characteristics of the material and anodization of inner surface crack.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.49-54
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• 2000

Cr-Mo-V steel is widely used as a material for the turbine structural component in fossil power plants. It is well known that this material shows the various material degradation phenomenons such as temper embrittlement, carbide coarsening. and softening etc. or ins to the severe operation conditions as high temperature and high pressure. These deteriorative factors cause tile change of mechanical properties as reduction of fracture toughness. Therefor it is necessary to evaluate tile extent of degradation damage for Cr-Mo-V steel in life assessment of turbine structural components. In this paper. the electrochemical potentiokinetic reactivation(EPR) test in $50wt%-Ca(NO_3)_2$ solution is performed to develop the newly technique for degradation damage evaluation of Cr-Mo-V steel. The results obtained from the EPR test are compared with those in small punch(SP) tests recommended by semi-nondestructive testing method using miniaturized specimen. The evaluation parameters used in EPR test are tile reactivation current density$(I_R)$ and charge$(Q_{RC})$ reactivation rate$(I_R/I_{Crit},\;Q_R/Q_{Crit})$. The results suggest that $I_R/I_{Crit}$ in these parameters shows a good correlation with SP test results.

• 전기화학회지
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• 제9권3호
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• pp.107-112
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• 2006

실리콘 분말에 polyaniline(PAn)을 중합하고 탄화하여 Si-C재료를 개발하고 물리적 특성 및 전기화학적 특성을 분석하였다. 평균입도는 PAn의 중합으로 증가하였으며 탄화로 일부 감소하였다. XRD분석으로 결정질의 실리콘과 비결정성의 탄소 재료가 공존함을 확인 하였다. Si-PAn 전구체로 부터 개발한 Si-C 재료를 이용한 Si-C|Li cell은 Si|Li cell에 비하여 우수한 특성을 나타내었으며, 탄소 전구체인 PAn의 HCl 탈도핑에 의해 전기화학적 특성을 개선할 수 있었다. 전해액 중 FEC 첨가한 경우 초기 방전 용량이 증가하였다. GISOC시험으로 구한 가역 비용량 범위는 Si-C(Si:PAn=50:50wt. ratio)|Li 전지의 경우 약 414mAh/g를 나타내었으며, 가역 범위에 대한 초기 충방전의 intercalation 효율(IIE)는 75.7%였으며, 표면 비가역 비용량은 35.4mAh/g을 나타내었다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1281-1284
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• 2005

In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. Generally, the stainless steel electrode corrodes, passivates or dissolves in the electrochemical cell according to the electrode potential. Therefore, the electrode must maintain stable potential. The stable electrode potentials of tool and workpiece were determined with the potentiodynamic polarization test and verified experimentally from the point of machining stability and machined surface quality.

• Journal of Advanced Marine Engineering and Technology
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• 제14권1호
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• pp.83-89
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• 1990

Electrochemical methods have been proposed as non-destructive, rapid and quantitative means for determining the degree of sensitization associated with Chromium depleted zones surrounding precipitates of Cr carbide and formation of secondary phase in stainless steel. In this study, the specimen of AISI 304 stainless steel and its welded sections, which welded by TIG, MIG, $CO_2$ and ARC, were tested corrosion resistance by electrochemical methods in 0.5N HCl and 1N $H_2SO_4$ with or without 0.01N KSCN. The results were confirmed that electrochemical methods could be used as a test method of corrosion resistance evaluation for the welded AISI 304 stainless steel.

• 한국정밀공학회지
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• 제23권4호
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• pp.146-152
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• 2006

In micro electrochemical machining (ECM), electrodes should be prevented from unfavorable oxide and Passive layer formation on the machined surface or overall corrosion of the entire surface. Generally, metal electrodes corrode, passivate or dissolve in the electrochemical cell according to the electrode potential. Therefore, each electrode must maintain its stable potential. Tn this paper, the stable electrode potentials of tool and workpiece were determined using the potentiodynamic polarization test and verified experimentally considering machining stability and surface quality. Stable workpiece electrode potentials of two different passive materials of 304 stainless steel and nickel were determined in the 0.1 M sulfuric acid. Experimental results show good machined surface and fast machining rate using the determined electrode potentials.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2002년도 추계학술대회 논문집
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• pp.151-154
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• 2002

In this paper a mathematical model, the results of computer simulation and exprimental investigations of electrochemical machining with a too-electrode are presented. The experimental investigations were carried out in order to evaluate the influence of working voltage, initial interelectrode gap size, and metal remove rate. Accuracy of computer simulation evaluated by differences between results of experimental test and computer simulation depends on electrochemical machining coefficient, total overpotential of electrode process, current density, electrical conductivity of electrolyte, and etc. Metal removal rate would be predicted by the simulation of ECM process.

• Corrosion Science and Technology
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• 제14권5호
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• pp.218-225
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• 2015

The electrochemical behaviors of various metals with and without diamond-like-carbon (DLC) coating in 3.5 wt% NaCl solution were investigated. The effect of hydrodynamic conditions was focused by employing a rotating disc electrode (RDE). The experimental results showed that each bare metal had a more positive corrosion potential and a higher corrosion rate due to enhanced oxygen transport at the higher rotating speed of the RDE. DLC coating caused a substantial increase in the corrosion resistance of all metals studied. However, localized corrosion was still found in the DLC-coated metal at sites where deposition defects existed. Surface morphology examination was performed after the electrochemical test to confirm the roles of hydrodynamic conditions and DLC coating.

• Journal of Electrochemical Science and Technology
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• 제12권3호
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• pp.365-376
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• 2021

Two arylamino substituted mercaptoimidazole derivatives namely 4,5-dimethyl-1-(phenylamino)-1H-imidazole-2(3H)-thione (I1) and 4,5- dimethyl-1-((p-chlorophenyl)amino)- 1H-imidazole-2(3H)-thione (I2) were synthesized and investigated as corrosion inhibitors for carbon steel in 0.5 M HCl solution by means of electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, ATR-FTIR spectroscopy and SEM. The results showed that the investigated mercaptoimidazole derivatives act as mixed type inhibitors and inhibition efficiency follows the I2>I1 order. Adsorption of inhibitors on metal surface was found to obey the Langmuir adsorption isotherm. Thermodynamic parameters revealed that adsorption of the inhibitors has both physisorption and chemisorption adsorption mechanism. Electrochemical test results were supported by quantum chemical parameters obtained from DFT calculations.