• 제목/요약/키워드: Electrochemical evaluation method

검색결과 116건 처리시간 0.025초

열화평가에 전기화학적 방법의 응용에 관한 연구 (A study on the application of electrochemical method for degradation evaluation)

  • 권재도;문윤배;김상태
    • 대한기계학회논문집A
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    • 제22권1호
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    • pp.44-51
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    • 1998
  • In order to develop the evaluation methods of degradation for the Ni-Cr-Mo-V steel, which is in use for turbine rotor in nuclear power plant, the degraded materials were prepared by simulated degradation methods. The result of impact test and fatigue crack growth test shows that the FATT(Fracture Appearance Transition Temperature) and fatigue crack growth rate increased with the increase of degradation. And the result of new electrochemical polarization test method was suggested for the evaluating FATT, fatigue crack growth exponent and coefficient C values based on the results of relationship between corrosion current density(Icorr) & FATT, and the m & C and Icorr.

전기화학적 방법에 의한 AISI 304 스테인리스강 용접부의 내식성 평가 (A Corrosion Resistance Evaluation of Welded AISI 304 Stainless Steel by Electrochemical Methods.)

  • 백신영;김관휴
    • Journal of Advanced Marine Engineering and Technology
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    • 제14권1호
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    • pp.83-89
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    • 1990
  • Electrochemical methods have been proposed as non-destructive, rapid and quantitative means for determining the degree of sensitization associated with Chromium depleted zones surrounding precipitates of Cr carbide and formation of secondary phase in stainless steel. In this study, the specimen of AISI 304 stainless steel and its welded sections, which welded by TIG, MIG, $CO_2$ and ARC, were tested corrosion resistance by electrochemical methods in 0.5N HCl and 1N $H_2SO_4$ with or without 0.01N KSCN. The results were confirmed that electrochemical methods could be used as a test method of corrosion resistance evaluation for the welded AISI 304 stainless steel.

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비금속 자원 재활용을 위한 전해부상 장치를 이용한 고농도 유기질 폐수의 재활용에 관한 연구 (A Study on Recycle of Concreted Organic Waste water by Electroflotation Apparatus for Resource Recycle of Non-Metal)

  • 김기준;남상성
    • 한국응용과학기술학회지
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    • 제29권4호
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    • pp.653-658
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    • 2012
  • 고농도 유기질 폐수처리를 위해 전기화학적 방법의 사용에 있어 관심이 고조되고 있다. 전기화학적 방법의 기술은 음식물폐수 및 공업적 폐수 문제를 해결하는데 이상적 처리 방법이다. 다른 화학적 처리 방법과는 다르게 전기화학적 처리장치는 2차 폐수의 부피를 증가시키지 않고 용수와 유기질 비료로 재활용한다. 전기화학적 방법은 전해부상장치를 무기화학적 약품과 병행하여 더욱 효과적으로 음식물 폐수를 처리한다. 이 연구는 2차 처리로 초음파와 오존처리로 탈색, COD와 BOD가 격감함으로 용수 및 유기질 비료로 활용하도록 실험하였다.

12%Cr강 인성열화도의 전기화학적 평가법에 대한 연구(II) (A Study on Electrochemical Evaluation Method of Toughness Degradation for 12%Cr Steel (II))

  • 김창희;서현욱;윤기봉;박기성;김승태
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.268-273
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    • 2001
  • Fossil power plants operated in high temperature condition are composed of components such as turbine, boiler, and piping system. Among these components, turbine blades made with 12%Cr steel operate at a temperature above $500^{\circ}C$. Due to the long term service, turbine blades experience material degradation manifested by change in mechanical and microstructural properties. The need to make life assessment and to evaluate material degradation of turbine blade is strongly required but in reality, there is a lack of knowledge in defining failure mechanism and fundamental data for this component. Therefore, in making life assessment of turbine blade, evaluation of material degradation must be a priority. For this purpose, evaluation of toughness degradation is very important. The major cause of toughness degradation in 12Cr turbine blade is reported to be critical corrosion pitting induced by segregation of impurity elements(P etc.), coarsening of carbide, and corrosion, but the of materials for in-service application. In this study, the purpose of research is focused on evaluating toughness degradation with respect to operation time for 12%Cr steel turbine blade under high temperature steam environment and quantitatively detecting the degradation properties which is the cause of toughness degradation by means of non-destructive method, electrochemical polarization.

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고주파 아크 금속용사공법을 이용한 용사금속의 방식성능 평가 (Evaluation of the Corrosion Protective Property in Steel applying Spray Metal by using High-frequency Arc Metal Spray Method)

  • 최홍복;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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    • pp.94-95
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    • 2014
  • The purpose of this study is to evaluate the corrosion protective property of Al-Mg high-freqeuncy arc metal spray method in comparison to Zn-Sn and Zn-Al alloys by electrochemical method and CASS test. As a result, it appeared that Al-Mg alloy had very higher corrosion protective property through the electrochemical characteristic and the CASS test comparing with the other alloys.

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Corrosion Evaluation of Epoxy-Coated Bars by Electrochemical Impedance Spectroscopy

  • Choi, Oan-Chul;Park, Young-Su;Ryu, Hyung-Yun
    • International Journal of Concrete Structures and Materials
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    • 제2권2호
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    • pp.99-105
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    • 2008
  • Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가 (An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe by each Welding Materials)

  • 김진경;원창욱;문경만
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2006년 창립20주년기념 정기학술대회 및 국제워크샵
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    • pp.185-188
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    • 2006
  • The sea water pipe of engine room in all kinds of ships is being surrounded with severe corrosive environment. Therefore it's leakage part due to corrosion is inevitably prevented by various welding method. In this case corrosion property of welded zone may be considerably different by each welding materials. In this study corrosion resistance of the welded zone of sea water pipe with some welding materials such as shielded metal arc welding materials, inert gas arc welding materials was investigated with electrochemical method.

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전기화학적 분극특성을 이용한 2.25Cr-lMo 강의 열화도 평가 (The Evaluation of 2-25Cr-lMo Steels Degradation by the Electrochemical Polarization Method)

  • 김지수;현양기;이재도;오세규
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2001년도 춘계학술대회 논문집
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    • pp.314-319
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    • 2001
  • Most parts of facilities in domestic petroleum plants and power plants are needed to be abandoned, repaired or replaced, because in Korea they were built in the 1960s and, they have been used under severe conditions and exposed corrosive environments. 2.25Cr- lMo steels have excellent high-temperature mechanical properties. Therefore, the material have been widely used as heat exchanger tubes, boiler headers and its tubes in such industries. But, those microstructural evolutions in high temperature such as precipitation and carbide coarsening give a reason to degrade the material. Especially, in case of this material, carbides induced embrittlement(CIE) is the primary reason for degrading mechanical properties at over 50$0^{\circ}C$. In this paper, we introduce a electrochemical polarization method for detecting CIE quantitatively.

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