• Title/Summary/Keyword: Electrochemical conversion

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Artificial muscles: Non-Stoichiometry Nature, Sensing and Actuating Properties and Tactile Sensibility

  • Otero T.F.;Lopez-Cascales J.J.;Vazquez-Arenas G.
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.5B no.2
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    • pp.118-122
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    • 2005
  • Electro-chemo-mechanical devices or artificial muscles based on conducting polymers (CP) are presented as bilayers, CP/adhesive polymer, or as triple layers, CP/adhesive polymer/CP. Those soft and wet materials, working in aqueous solutions of a salt, mimic the composition of most organs from animals. Under electrochemical control, so working as new electrical machines, they produce continuous, reverse and elegant bending movements, mimicking those produce by animal muscles. By means of the current a perfect controls of the movement rate is attained giving soft and continuous movements. Muscles able to sense the chemical and mechanical conditions of work or muscle having tactile sense, as will be presented here, are being developed. All of them are founded on the non-stoichiometric nature of the soft and wet materials.

Applications of metamaterials: Cloaking, Photonics, and Energy Harvesting

  • Kim, Kyoungsik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.77.2-77.2
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    • 2015
  • Recently, metamaterials attracted much attention because of the potential applications for superlens, cloaking and high precision sensors. We developed several dielectric metamaterials for enhancing antireflection or light trapping capability in solar energy harvesting devices. Colloidal lithography and electrochemical anodization process were employed to fabricate self-assembed nano- and microscale dielectric metamaterials in a simple and cost-effective manner. We improved broadband light absorption in c-Si, a-Si, and organic semiconductor layer by employing polystyrene (PS) islands integrated Si conical-frustum arrays, resonant PS nanosphere arrays, and diffusive alumina nanowire arrays, respectively. We also demonstrated thin metal coated alumina nanowire array which is utilized as an efficient light-to-heat conversion layer of solar steam generating devices. The scalable design and adaptable fabrication route to our light management nanostructures will be promising in applications of solar energy harvesting system. On the other hands, broadband invisible cloaks, which continuously work while elastically deforming, are developed using smart metamaterials made of photonic and elastic crystals. A self-adjustable, nearly lossless, and broadband (10-12GHz) smart meatamaterials have great potentials for applications in antenna system and military stealth technology.

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Formation of $I_2$ by a Photocatalytic Reaction of Rose Bengal (Rose Bengal의 광촉매 반응에 의한 $I_2$의 생성)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.9 no.1
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    • pp.72-77
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    • 1996
  • In the process of solar energy conversion into electrical energy using the photoelectrochemical cell containing the sensitizer, rose bengal and supersensitizer. $I^-$, the photocurrent is stabilized and durable. But the long time span of irradiation causes the decrease of photocurrent monotonically. Spectroscopic and electrochemical analyses of rose bengal solution containing $I^-$ revealed that the decrease of concentration of rose bengal was attributed to the reaction of rose bengal in the dark with $I_2$ formed as a result of the possible photocatalytic reaction of rose bengal with $I^-$.

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Fabrication of TCO-less Dye-sensitized Solar Cells by Using Low Cost Ti Layer Deposited Glass Substrate (저가의 Ti 박막이 증착된 유리 기판을 사용한 TCO-less 염료감응형 태양전지의 응용)

  • Jung, Haeng-Yun;Ki, Hyun-Chul;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.11
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    • pp.725-729
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    • 2014
  • In this study, a transparent conductive oxide (TCO)-less dye-sensitized solar cells (DSSCs) was fabricated by using titanium (Ti) electrode to replace the Fluorine-doped tin oxide (FTO) for the reduction of manufacturing cost. Ti film was formed by electron beam evaporation method and the results showed the sheet resistance of Ti electrodes with a thikness of 500 nm similar to FTO. In case of power conversion efficiency (PCE), a DSSC with Ti electrodes showed a lower value than that with FTO by 0.38%. For the investigation of the difference, the DSSCs were measured and analyzed by using electrochemical impedance analyzer (EIS).

Ordered CdS nanorods- organic hybrid solar cells

  • Kang, Yoon-Mook;Kim, Dong-Hwan
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.32-36
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    • 2005
  • We studied the optoelectronic properties of hybrid solar cells formed by mixing cadmium sulfide [CdS] nanorods with a conjugated polymer, poly-2-methoxy, 5-[2'-ethy[hexyloxy]-1,4-p-phenylenevinylene[MEH-PPV]. CdS nanorods were grown vertically on Ti substrates by electrochemical deposition through a porous alumina template. Absorption spectrum of the composite layer was the same as the superposition of the absorption spectrum of each individual layer. The photoluminescence signal from MEH-PPV film was reduced as a result of the mixing. The energy conversion efficiency of MEH-PPV improved from $0.0012\%$ to about $0.60\%$ when combined with the vertically aligned CdS nanorods.

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Nanostructured Photoelectrode Materials for Improving Light-Harvesting Properties in DSSCs

  • Jeong, Hyeon-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.7.2-7.2
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO). In this presentation, we introduce monodisperesed TiO2 nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Inverse opal-based scattering layers containing highly crystalline anatase nanoparticles are also introduced and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength.

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Water Oxidation Mechanism for 3d Transition Metal Oxide Catalysts under Neutral Condition

  • Seo, Hongmin;Cho, Kang Hee;Ha, Heonjin;Park, Sunghak;Hong, Jung Sug;Jin, Kyoungsuk;Nam, Ki Tae
    • Journal of the Korean Ceramic Society
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    • v.54 no.1
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    • pp.1-8
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    • 2017
  • Electrochemical water splitting to produce hydrogen energy is regarded as a promising energy conversion process for its environmentally friendly nature. To improve cell efficiency, the development of efficient water oxidation catalysts is essentially demanded. For several decades, 3d transition metal oxides have been intensively investigated for their high activity, good durability and low-cost. This review covers i) recent progress on 3d transition metal oxide electrocatalysts and ii) the reaction mechanism of oxygen evolving catalysis, specifically focused on the proposed pathways for the O-O bond formation step.

Methanol Concentration Sensor by Using Pt dot Catalyst Electrode (Pt dot 촉매전극을 활용하여 제작한 메탄올 센서)

  • Yang, Jin-Seok;Park, Jung-Ho;Park, Moon-Ho
    • Proceedings of the IEEK Conference
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    • 2008.06a
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    • pp.505-506
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    • 2008
  • The direct methanol fuel cell (DMFC) is a promising power source for portable applications due to many advantages such as simple construction, compact design, high energy density, and relatively high energy-conversion efficiency. In this work, an electrochemical methanol sensor for monitoring the methanol concentration in direct methanol fuel cells was fabricated using a thin composite nafion membrane as the electrolyte. We have analyzed the I-V characteristic of the fabricated methanol sensor as a function of methanol concentration, catalyst electrode and platinum(Pt) dot.

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Why Fuel Cell ? - Its Vision and Prospects (연료전지 - 그 비전과 전망)

  • Kim, Gun-Tag;Chung, Jin-Yop
    • 유체기계공업학회:학술대회논문집
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    • 2001.11a
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    • pp.367-372
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    • 2001
  • A fuel cell is an electrochemical energy conversion device tint converts hydrogen and oxygen into electricity and heat for hot water and heating room A fuel cell provides a DC voltage tint can be used to power motors, lights or any number if electrical appliances. There are several different types if fuel cells, each using a different chemistry. Some types if fuel cells show promise for use in DC (distributed generation) because fuel cell is very clean and efficient energy device. CETI (Clean Energy Technologies, Inc.) is developing PEMFC and DMFC for residential power generation, portable and battery. It is anticipated tint RPG is advantageous over current power generation by utility In terms if economics assuming the lifetime of major components is at least five years.

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Topological Optimization of Heat Dissipating Structure with Forced Convection (강제 대류를 통한 열소산 구조물의 위상최적화)

  • Yoon, Gil-Ho
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.408-409
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    • 2008
  • This paper presents a new development for topology optimization of heat-dissipating structure with forced convection. To cool down electric devices or machines, two types of convection models have been widely used: Natural convection model with a large Archimedes number and Forced convection with a small Archimedes number. Nowadays, many engineering application areas such as electrochemical conversion device or fuel cell devices adopt the forced convection to transfer generated heat. Therefore, to our knowledge, it becomes an important issue to design flow channels inside which generated heat transfer. Thus, this paper studies optimal topological designs considering fluid-heat interaction. To consider the effect of the advection in the heat transfer problem, the incompressible Navier-stokes equation is solved. This paper numerically studies the coupling phenomena and presents optimal channel design considering forced convection.

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