• Title/Summary/Keyword: Electrochemical Material

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Application of Electrochemical Etch-stop in TMAH/IPA/pyrazine Solution to Pressure Sensors (TMAH/IPA/pyrazine용액에 있어서 전기화학적 식각정지법의 압력센서에의 응용)

  • 박진성;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.423-426
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    • 1998
  • Piezoresistive pressure sensors have fabricated using electrochemical etch-stop technique. Si diaphragm having thickness of n-epi. layer was fabricated and used to detect pressure range from 0 to 1 kg/$\textrm{cm}^2$. Piezoresistors were diffused 3${\times}$10$\^$18/ cm$\^$-3/ and placed at diaphragm edge for maximum pressure detection. The characteristics of electrochemical etch-stop in TMAH/lPA/pyrazine solution were also discussed. I-V curves of n and p-type Si in TMAH/lPA/pyrazine solution were obtained. Etching rate is highest at optimum etching condition, TMAH 25wt.%/IPA 17vo1.%/pyrazine 0.1/100m1, thus the elapsed time of etch-stop was reduced.

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Corrosion Resistance Properties of Rice Husk Ash Blended Concrete

  • Ganesan, K.;Rajagopal, K.;Thangavel, K.
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.12-17
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    • 2007
  • Portland cement incorporating supplementary cementing material develops excellent mechanical properties and long term durability characteristics. India is a leading rice producing country and rice husk is considered as waste in the rice milling industries. In this present work, the rice husk ash (RHA) was added to concrete as cement replacement from 0 to 30%. Corrosion performance of reinforcing steel embedded in RHA blended concretes was studied using linear polarization, AC impedance and gravimetric methods. The corrosion rate of steel bars embedded in RHA concretes were compared with control concrete. The results clearly indicate that the corrosion rate of reinforcing steel embedded in concrete is significantly reduced with the incorporation of RHA. A good correlation among gravimetric method and electrochemical methods was observed. Electrochemical impedance study showed 98 percentage reduction in corrosion rate to the RHA blended concrete with 15% replacement than control concrete.

Fundamental Approach to Capacity Prediction of Si-Alloys as Anode Material for Li-ion Batteries

  • Kim, Jong Su;Umirov, Nurzhan;Kim, Hyang-Yeon;Kim, Sung-Soo
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.51-59
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    • 2018
  • Various Si-Fe-Al ternary alloys were prepared with the same amount of Si by the melt spinning technique. The feasibility of the capacity prediction approach based on the estimation of the active amount of Si using the phase diagram was practically examined and reported. These predictions were verified by the electrochemical test of fabricated coin cells and other characterization methods. The capacity prediction approach using the phase diagram might be a fundamental and efficient method to accelerate the practical application of Si-based alloys as the anode material for Li-ion batteries. The details on the prediction procedure were discussed.

Micromachining of Si substrate Using Electrochemical Etch-Stop in Aqueous TMAH/IPA/pyrazine Solution (TMAH/IPA/Pyrazine 수용액에서 전기화학적 식각정지법을 이용한 Si 기판의 미세가공)

  • 박진성;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.397-400
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    • 1997
  • This paper presentes the characteristics of Si anisotropic etching and electrochemical etch-stop in aqueous TMAH/IPA/pyrazine solution. (100) Si etching rate of 0.747 $\mu\textrm{m}$/min which faster 86% than TMAH 25 wt.%/IPA 17 vol.% solution was obtained using best etching condition at TMAH 25 wt.%/IPA 17 vol.%/pyrazine 0.1 g and the etching rate of (100) Si was decreased with more additive quantity of pyrazine. I-V curve of p-type Si in TMAH/IPA/pyrazine was obtained. OCP(Open Circuit Potential) and PP(Passivation Potential) were -2 V and -0.9 V, respectively. Si diaphragms were obtained by electrochemical etch-stop in aqueous TMAH/IPA/pyrazine solution.

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The Electrochemical Characteristics of $LiCoO_2$Cathode Materials as a function of Polyaniline contents (Polyaniline을 첨가한 $LiCoO_2$정극활물질의 전기화학적 특성)

  • 임동규;임석범;김영호;김은옥;류광선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.667-670
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    • 2000
  • The electrochemical characterization was conducted by the addition of chemically synthesized polyaniline on LiCoO$_2$electrode. From the results of XRD and SEM, the phase transition and microstructure were not found. Initial electrochemical characteristics of LiCoO$_2$electrode for lithium secondary battery were evaluated through the charge/discharge within the range of 4.3 V to 3.0 V versus Li/Li$^{+}$. Discharge capacity of LiCoO$_2$electrode without addition of Polyaniline were 160.21 mAh/g. But after addition of polyaniline, lower discharge capacities 25.7 mAh/g was found.d.

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A Study on thinning of SDB SOI by electrochemical etch-stop (전기화학적 식각정지에 의한 SDB SOI의 박막화에 관한 연구)

  • 김일명;이승준;강경두;정수태;주병권;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.362-365
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    • 1999
  • This paper describes on thinning SDB SOI substrates by SDB technology and electrochemical etch-stop. The surface of the fabricated SDB SOI substrates is more uniform than that grinding or polishing by mechanical method, and this process is possible to accurate SOI thickness control. During Electrochemical etch-stop, leakage current versus voltage curves were measured for analysis of the open current potential (OCP) point and the passivation potential (PP) poin and determinated to anodic substrates were analyzed by using AFM and SEM, respectivelv.

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Electrochemical Properties of Polypyrrole Nanotubules Enzyme Electrode Immobilized with Glucose Oxidase (포도당 산화효소가 고정화된 Popyrrole Nanotubules 효소전극의 전기화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.909-912
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    • 2000
  • We synthesized polypyrrole (PPy) nanotubules by oxidative polymerization of the pyrrole monomer within the pores of a polycarbonate template. The electrochemical behavior was investigated using cyclic voltammetry. The redox potential was about -0.5 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for PPy film. It is considered as the backbone grows according to the pore wall. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. By electrochemical doping of glucose oxidase (GOx) on PPy nanotubules, an enzyme electrode has been fabricated. The kinetic parameter of biochemical reaction with glucose was evaluated. The formal Michaelis constant and maximum current calculated by computer were about 11.4 mmol $dm^3$ and 170.85 A respectively. Obviously, an affinity for the substrate and current response of the PPy nanotubules enzyme electrode are rather good, comparing with that of PPy film.

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Study on Morphology Investigation and Electron-Transfer Property of Self-Assembled Viologen Monolayers (자기조립된 Viologen 단분자막의 모폴로지 관찰과 전하이동 특성 연구)

  • Lee, Dong-Yun;Park, Sang-Hyun;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.395-396
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    • 2005
  • We fabricated self-assembled monolayers(SAMs) onto quartz crystal microbalance(QCM) using viologen, which has been widely used as electron acceptor and electron transfer mediator. We determined the time dependence to resonant frequency shift during self-assembly process and observed the morphology of self-assembled mono layers by STM and investigated the electrochemical behavior of SAMs by cyclic voltammetry. Electrochemical deposition of viologen was investigated using electrochemical quartz crystal microbalance(EQCM). The redox reactions of viologen were highly reversible and the EQCM has been employed to monitor the electrochemically induced adsorption of SAMs during the redox reactions.

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