• Title/Summary/Keyword: Electro-chemical discharge

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Study on Reactive Non-thermal Plasma Process combined with Metal Oxide Catalyst for Removal of Dilute Trichloroethylene

  • Han Sang-Bo;Oda Tetsuji;Park Jae-Youn;Park Sang-Hyun;Koh Hee-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.292-300
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    • 2006
  • In order to improve energy efficiency in the dilute trichloroethylene removal using the nonthermal plasma process, the barrier discharge treatment combined with manganese dioxide was experimentally studied. Reaction kinetics in this process was studied on the basis of final byproducts distribution. Decomposition efficiency was improved to about $99\;\%$ at the specific energy of 40 J/L with passing through manganese dioxide. C=C ${\pi}$ bond cleavage of TCE substances gave DCAC, which has the single bond of C-C through oxidation reaction during the barrier discharge plasma treatment. Those DCAC were broken easily in the subsequent catalytic reaction due to the weak bonding energy about $3{\sim}4\;eV$ compared with the double bonding energy in TCE molecules. Oxidation byproducts of DCAC and TCAA from TCE decomposition are generated from the barrier discharge plasma treatment and catalytic surface chemical reaction, respectively. Complete oxidation of TCE into COx is required to about 400 J/L, but $CO_2$ selectivity remains about $60\;\%$.

Improvement of Geometric Accuracy using Powder Mixed Electro-chemical Discharge Machining Process (전해액 내 혼합된 미세 전도성 입자를 이용한 전해 방전 가공의 형상 정밀도 향상)

  • Han M.S.;Min B.K.;Lee S.J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.366-369
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    • 2005
  • Electrochemical discharge machining (ECDM) has been found to be potential fur the micro-machining of non-conductive materials such as ceramics or glass. However this machining process has its own inherent problem that the reproducibility is too low to get the available geometric accuracy fur micromachining applications. One main challenge in reaching this goal is the control of the hydrogen built around the tool-electrode in which happen the discharges. This paper proposes the methods to improve the geometric accuracy using powder-mixed ECDM process. The experimental results show the effects of powder producing improved geometric accuracy by averaging and decreasing the concentration of spark energy.

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Electrochemical Properties of Porous Co(OH)2 Nano-flake Thin Film Prepared by Electro-deposition for Supercapacitor (전착법을 이용한 슈퍼커패시터용 다공성 Co(OH)2 나노플레이크 박막의 제조 및 전기화학적 특성)

  • Lee, Hyeon Jeong;Jin, En Mei;Jeong, Sang Mun
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.157-162
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    • 2016
  • Porous $Co(OH)_2$ nano-flake thin films were prepared by a potential-controlled electro-deposition technique at various deposition voltage (-0.75, -1.0, -1.2, and -1.4 V) on Ti-mesh substrates for supercapacitor application. The potential of electrode was controlled to regulate the film thickness and the amount of $Co(OH)_2$ nano-flake on the titanium substrate. The film thickness was shown to reach the maximum value of $34{\mu}m$ at -1.4 V of electrode potential, where 17.2 g of $Co(OH)_2$ was deposited on the substrate. The specific discharge capacitances were measured to be 226, 370, 720, and $1008mF\;cm^{-2}$ in the 1st cycle corresponding to the films which were formed at -0.75, -1.0, -1.2, and -1.4 V of electrode potentials, respectively. Then the discharge capacities were decreased to be 206, 349, 586 and $866mF/cm^{-2}$, where the persistency rates were 91, 94, 81, and 86%, respectively.

Pentacene Thin Film Transistors Fabricated by High-aspect Ratio Metal Shadow Mask

  • Jin, Sung-Hun;Jung, Keum-Dong;Shin, Hyung-Chul;Park, Byung-Gook;Lee, Jong-Duk;Yi, Sang-Min;Chu, Chong-Nam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.881-884
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    • 2004
  • The robust and large-area applicable metal shadow masks with a high aspect ratio more than 20 are fabricated by a combination of micro-electro-discharge machining (${\mu}$-EDM) and electro chemical etching (ECE). After defining S/D contacts using a 100 ${\mu}m$ thick stainless steel shadow mask, the top-contact pentacene TFTs with channel length of 5 ${\mu}m$ showed routinely the results of mobility of 0.498 ${\pm}$ 0.05 $cm^2$/Vsec, current on/off ratio of 1.6 ${times}$ $10^5$, and threshold voltage of 0 V. The straightly defined atomic force microscopy (AFM) images of channel area demonstrated that shadow effects caused by the S/D electrode deposition were negligible. The fabricated pentacene TFTs have an average channel length of 5 ${\pm}$ 0.25 ${\mu}m$.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터의 개발)

  • Oh, Kil-Hun;Kim, Han-Joo;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Characteristics of LiMn2O4 Cathode Material Prepared by Precipitation-Evaporation Method for Li-ion Secondary Battery (침전-증발법에 의해 제조된 리튬이온 2차 전지용 LiMn2O4 양극재료의 특성)

  • Kim, Guk-Tae;Yoon, Duck-Ki;Shim, Young-Jae
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.712-717
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    • 2002
  • New wet chemical method so called precipitation-evaporation method was suggested for preparing spinel structure lithium manganese oxide ($LiMn_2$$O_4$) for Li ion secondary battery. Using precipitation-evaporation method, $LiMn_2$$O_4$ cathode materials suitable for Li ion secondary batteries can be synthesized. Single spinel phase $LiMn_2$$O_4$ powder was synthesized at lower temperature compared to that of prepared by solid-state method. $LiMn_2$$O_4$ powder prepared by precipitation-evaporation method showed uniform, small size and well defined crystallinity particles. Li ion secondary battery using $LiMn_2$$O_4$ as cathode materials prepared by precipitation-evaporation method and calcined at $800^{\circ}C$ showed discharge capacity of 106.03mAh/g and discharge capacity of 95.60mAh/g at 10th cycle. Although Li ion secondary battery showed somewhat smaller initial capacity but good cyclic ability. It is suggested that electro-chemical properties can be improved by controlling particle characteristics by particle morphology modification during calcination and optimizing Li ion secondary battery assembly conditions.

A Study on Micro Ultrasonic machining for Brittle Material Using Ultrasonic vibration (초음파 진동을 이용한 취성재료 가공기술에 관한 연구)

  • 이석우;최헌종;이봉구
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.969-972
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    • 1997
  • Ultrasonic machining technology has been developed over recent years for he manufacture of cost-effective and quality-assured precision parts for several industrial application such as optics, semiconductors, aerospace, and automobile application. The past decade has seen a tremendous in the use of ceramic in structural application. The excellent thermal, chemical and wear resistance of these material can be realized because of recent improvement in the overall strength and uniformity of advanced ceramics. Ultrasonic machining, in which abrasive particles in slurry with water are presented to the work surface in the presence of an ultrasonic-vibrating tool, is process which should be of considerable interest, as its potential is not limited by he electrical or chemical characteristics of the work material, making it suitable for application to ceramics. In order to improve the currently used ultrasonic machining using ultrasonic energy, technical accumulation is needed steadily through development of exciting device of ultrasonic machine composed of piezoelectric vibrator and horn. This paper intends to further the understanding of the basic mechanism of ultrasonic machining for brittle material and ultrasonic machining of ceramics based in the fracture-mechanic concept has been analyzed.

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Wastewater Treatment Process Study for Used Diaper Recycling (사용 후 기저귀 재활용을 위한 폐수처리방안 연구)

  • Kim, Kyung Shin;Lee, Ho Sun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.2
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    • pp.24-33
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    • 2015
  • This study aims to suggest wastewater treatment options for diaper recycling by identifying characteristic analysis of wastewater from diaper recycling process and efficiency evaluation of wastewater treatment units. The wastewater characteristic analysis showed that the concentration of organic pollutants and ionic materials were very high comparing to seawater. Through the investigation of similar wastewater treatment, six treatment units were identified to reduce pollutants. It is found UF(ultra-filtration), DAF(dissolved air flotation), fenton oxidation, electro-coagulation and chemical-coagulation are effective in reducing organic pollutants while membrane system and ion exchanger are effective in reducing ionic materials. Even though the target of water quality should be secured in terms of managing organic pollutants level, the application of treatment unit for reducing ionic material needs lots of considerations. This result suggests that reuse of pulping wastewater after controlling organic pollutants is better than direct discharge of pulping wastewater. To select the appropriate wastewater treatment unit, an economic analysis about operation condition, wastewater flow, cost, efficiency should be considered.