• Title/Summary/Keyword: Electrical corrosion

Search Result 470, Processing Time 0.025 seconds

The Comparison Analysis of Field Test Cases on Technical Specifications of Electrolytic Corrosion in Urban Railway (국내 도시철도 전식방지 기술기준에 따른 시험사례 비교분석)

  • Kim, Jae-Moon;Jung, Ho-Sung;Kim, Yang-Su
    • The Transactions of the Korean Institute of Electrical Engineers P
    • /
    • v.59 no.3
    • /
    • pp.305-310
    • /
    • 2010
  • DC electricity feeder system operating in the urban railway is typically a feedback circuit consisted of the contact wire and electric railway vehicle via rail. But stray current is flowed on a structure that is not part of the intended electrical circuit with respect to a given structure. This paper presents comparison analysis of field test cases based on criteria of electrolytic corrosion protection of buried metallic structures adjacent to DC traction systems. As a result of it, we confirmed that measurement methods are different from each other about the same tests. Therefore measurement methods to prevent electrolytic corrosion need to establish electrical facilities standards to be applied domestic.

Sliding Wear and Corrosion Resistance of Copper-based Overhead Catenary for Traction Systems

  • Kwok, C.T.;Wong, P.K.;Man, H.C.;Cheng, F.T.
    • International Journal of Railway
    • /
    • v.3 no.1
    • /
    • pp.19-27
    • /
    • 2010
  • In the present study, the electrical sliding wear and corrosion resistance of pure copper (Cu) and six age-hardened copper alloys (CuCr, CuZr, CuCrZr, CuNiSiCr, CuBe and CuBeNi) were investigated by a pin-on-disc tribometer and electrochemical measurement. Various copper-based alloys in the form of cylindrical pin were forced to slide against a counterface stainless steel disc in air under unlubricated condition at a sliding velocity of 31 km/h under normal load up to 20 N with and without electric current. The worn surface of and wear debris from the specimens were studied by scanning electron microscopy. Both mechanical wear and electrical arc erosion were the wear mechanisms for the alloys worn at 50 A. Owing to its good electrical conductivity, high wear and corrosion resistance, CuCrZr is a promising candidate as the overhead catenary material for electric traction systems.

  • PDF

Interpretation of Corrosion Mechanism on Anode side Separator for MCFC (용융탄산염 연료전지에서 양극측 분리판의 부식기구 해석)

  • Park, Hyeong-Ho;Lee, Min-Ho;Lee, Kyu-Taek
    • Korean Journal of Materials Research
    • /
    • v.8 no.6
    • /
    • pp.571-576
    • /
    • 1998
  • This study was carried out for investigating the corrosion behaviors, corrosion mechanisms, and behaviors of elements on a separator for a molten carbonate fuel cell under both the electrolyte and anode side environment. A 310S austenitic stainless steel was used as the separator material. Corrosion proceeded via three steps; the formation step of corrosion product in which rapid corrosion takes place until stable corrosion product is formed after the beginning of corrosion, the protection step against corrosion until breakaway occurs after the formation step of stable corrosion product and the advancing step of corrosion after the breakaway. From the standpoint of the behavior of the elements in the specimen, Fe and Cr, Ni were enriched in the region of corrosion product, in the region of corrosion protection, and at the Cr-deplete zone, respectively. With respect to corrosion mechanism, ionization of electrolyte at the anode side was the main corrosion mechanism, and the final corrosion products were $LiFeO_2$ and $LiCrO_2$ at the anode side.

  • PDF

Coating Performance of SiO2 / Epoxy Composites as a Corrosion Protector

  • Rzaij, Dina R.;Ahmed, Nagham Y.;Alhaboubi, Naseer
    • Corrosion Science and Technology
    • /
    • v.21 no.2
    • /
    • pp.111-120
    • /
    • 2022
  • To solve the corrosion problem of industrial equipment and other constructions containing metals, corrosion protection can be performed by using coating which provides a barrier between the metal and its environment. Coatings play a significant role in protecting irons and steels in harsh marine and acid environments. This study was conducted to identify an anti-corrosive epoxy coating for carbon steel composite with 0.1, 0.3, and 0.5 wt% concentrations of nanoparticles of SiO2 using the dip-coating method. The electrochemical behavior was analyzed with open circuit potential (OCP) technics and polarization curves (Tafle) in 3.5 wt% NaCl and 5 vol% H2SO4 media. The structure, composition, and morphology were characterized using different analytical techniques such as X-ray Diffraction (XRD), Fourier Transform Infrared spectrum (FT-IR), and Scanning Electron Microscopy (SEM). Results revealed that epoxynano SiO2 coating demonstrated a lower corrosion rate of 2.51 × 10-4 mm/year and the efficiency of corrosion protection was as high as 99.77%. The electrochemical measurement showed that the nano-SiO2 / epoxy coating enhanced the anti-corrosive performance in both NaCl and H2SO4 media.

The Effect of the Anti-corrosion by$CHF_3$ Treatment after Plasma Etching of Al Alloy Films (Al 합금막의 식각후 $CHF_3$ 처리에 의한 부식억제 효과)

  • 김창일;권광호;윤용선;백규하;남기수;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.11 no.7
    • /
    • pp.517-521
    • /
    • 1998
  • After etching Al-Cu alloy films using $SiCl_4/Cl_2/He/CHF_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS(X-ray pheotoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, $CHF_3$ plasma treatment subsequent to the etch has been carried put. A passivation layer is formed by fluorine-related compounds on the etched Al-Cu surface after $CHF_3$ treatment, and the layer suppresses effectively the corrosion on the surface as the $CHF_3$treatment in the pressure of 300m Torr.

  • PDF

A study of the fluorine treatment for the anti-corrosion after plasma etching of AlCu films (AlCu 배선의 부식방지를 위한 fluorine 가스 처리연구)

  • 김창일;서용진;권광호;김태형;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1998.06a
    • /
    • pp.383-386
    • /
    • 1998
  • After etching Al-Cu alloy films using SiC1$_4$/Cl$_2$/He/CHF$_3$ plasma, a corrosion phenomenon on the metal surface has been studied with XPS (X-ray photoelectron spectroscopy) and SEM (Scanning electron microscopy). In Al-Cu alloy system, the corrosion occurs rapidly on the etched surface by residual chlorine atoms. To prevent the corrosion, CHF$_3$ plasma treatment subsequent to the etched has been carried out. A passivation layer is formed by fluorine-related compounds on the etched Al-Cu surface after CHF$_3$ and SF$_{6}$ treatment, and the layer supresses effectively the corrosion on the surface as the CHF$_3$ and SF$_{6}$ treatment pressure increases. The corrosion could be suppressed successfully with CHF$_3$ and SF6 treatment in the pressure of 300mTorr.orr.

  • PDF

The Analysis of Electrical Conduction and Corrosion Phenomena in HVDC Cooling System and the Optimized Design of the Heat Sink of the Semiconductor Devices (HVDC 냉각시스템의 전기전도현상 및 부식현상 기술 분석과 스위칭 소자의 방열판 최적 설계 검토)

  • Kim, Chan-Ki;Park, Chang-Hwan;Kim, Jang-Mok
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.22 no.6
    • /
    • pp.484-495
    • /
    • 2017
  • In HVDC thyristor valves, more than 95% of heat loss occurs in snubber resistors and valve reactors. In order to dissipate the heat from the valves and to suppress the electrolytic current, water with a high heat capacity and a low conductivity of less than 0.2 uS/cm must be used as a refrigerant of the heat sink. The cooling parts must also be arranged to reduce the electrolytic current, whereas the pipe that supplies water to the thyristor heat sink must have the same electric potential as the valve. Corrosion is mainly caused by electrochemical reactions and the influence of water quality and leakage current. This paper identifies the refrigerants involved in the ionization, electrical conductivity, and corrosion in HVDC thyristor valves. A method for preventing corrosion is then introduced. The design of the heat sink with an excellent heat radiation is also analyzed in detail.

Development of Metallic Bipolar Plate for Automotive PEMFC (자동차 구동용 PEMFC 금속계 분리판 개발)

  • Jeon, Yoo-Taek;Chung, Kyeong-Woo;Na, Sang-Mook
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2005.06a
    • /
    • pp.321-325
    • /
    • 2005
  • Bipolar plate is the main part with MEA in automotive PEMFC. It must have a good electrical conductivity and excellent corrosion resistance, be cost effective. Therefore, stainless steels have been studied by many researchers because of its corrosion resistance and cost benefits. But their properties are not sufficient for the application to bipolar plate for automotive PEMFC. In this work, we have performed stamping using various commercial stainless steels to select candidate material for biploar plate and to derive design parameters for stamping simulation. The results showed that a small curvature at the corner of flow field is more favorable due to easier a plastic deformation. Stamping process was simulated by changing surface condition, and the size and angle of channel. The optimum shape and spring back phenomena were evaluated. Surface coating was applied to increase the corrosion resistance and electrical conductivity of stainless steel. The electrical interfacial resistance was 10 to $15m{\Omega}cm^2$ under clamping force of 150psi. But corrosion resistance of coating on the stainless steel was not good due to the unstableness of microstructure.

  • PDF

A Study on Corrosion Resistance and Electrical Surface Conductivity of an Electrodeposited Ni-W Thin Film (전해도금에 의한 Ni-W 합금의 내식성 및 표면 전도도 특성 연구)

  • Park, Je-Sik;Jeong, Goo-Jin;Kim, Young-Jun;Kim, Ki-Jae;Lee, Churl-Kyoung
    • Journal of the Korean institute of surface engineering
    • /
    • v.44 no.2
    • /
    • pp.68-73
    • /
    • 2011
  • A Ni-W thin-film was synthesized by electrodeposition, and its corrosion resistance and electrical surface conductivity were investigated. Amount of tungsten in the Ni-W thin-film increased linearly with current density during the electrodeposition, and crack-free and low-crystalline Ni-21 at.%W coating layer was obtained. Corrosion resistances of the Ni-W thin-films were examined with an anodic polarization method and a storage test in a strong sulfuric acid solution. As a result, the Ni-21 at.%W thin-film exhibited the greatest corrosion resistance, and maintained the electrical surface conductivity even after the severe corrosion test, which could be applicable as a surface treatment for advanced metallic bipolar plates in fuel cell or redox flow battery systems.

A Study on the Development of a Control and Monitoring System for Impressed Current Corrosion Protection (선박용 차세대 외부전원방식 제어 및 감시 시스템 UNIT 개발)

  • Kim, Y.B.;Kim, B.Y.;Suh, J.H.;Kim, J.W.
    • Journal of Power System Engineering
    • /
    • v.10 no.2
    • /
    • pp.104-110
    • /
    • 2006
  • Corrosion has been around for all of recorded history. Cathodic protection is the electrical solution to the corrosion problem. Corrosion is not exactly a new topic. It has been around since the beginning of time. Corrosion is simply the loss of material resulting from current leaving a metal, following through a medium, and returning to the metal at a different point. Corrosion takes many forms and has various names, such as oxidation, rust, chemical, and bacteria action. Regardless of the agent, all corrosion is the result of electrical current flow. Various methods are used to treat corrosion or to try to prevent ti. Some of these include chemical treatment. coatings, and electrical current. Especially, proper impressed current can stop corrosive action on the protected surface. In this article, we introduce the Impressed Current Cathodic Protection (ICCP) Control and monitoring system developed by ourselves. The ICCP system is composed of a power supply, anode, reference electrode and controller. The main issue is to control the current flow on the desired value such that it is possible to force a metal to be more negative(cathodic) than the natural state. From the this process, we can achieve the cathodic protection. Of course, in the developed system, the necessary functions are possessed, such as remote control, monitoring of system fault detection etc. Some experimental results show the system performance and usefulness.

  • PDF