• Title/Summary/Keyword: Electric fraction

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Evaluation of Grooving Corrosion and Electrochemical Properties of H2S Containing Oil/Gas Transportation Pipes Manufactured by Electric Resistance Welding

  • Rahman, Maksudur;Murugan, Siva Prasad;Ji, Changwook;Cho, Yong Jin;Cheon, Joo-Yong;Park, Yeong-Do
    • Corrosion Science and Technology
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    • v.17 no.3
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    • pp.109-115
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    • 2018
  • Electrical Resistance Welding (ERW) on a longitudinal seam-welded pipe has been extensively used in oil and gas pipelines. It is well known that the weld zone commonly suffers from grooving corrosion in ERW pipes. In this paper, the grooving corrosion performances of API X65 grade non-sour service (steel-A) and API X70 grade sour gas resistant (steel-B) steel electrical resistance welding pipelines were evaluated. The microstructure of the bondline is composed of coarse polygonal ferrite grains and several elongated pearlites. The elongated pattern is mainly concentrated in the center of the welded area. The grooving corrosion test and electrochemical polarization test were conducted to study the corrosion behavior of the given materials. A V-shaped corrosion groove was found at the center of the fusion zone in both the steel-A and steel-B ERW pipes, as the corrosion rate of the bondlines is higher than that of the base metal. Furthermore, the higher volume fraction of pearlite at the bondline was responsible for the higher corrosion rate at the bondline of both types of steel.

Neutron Personal Dose Equivalent Evaluation Using Panasonic UD-809P Type TLD Albedo Dosimeters (Panasonic UD-809P 알비도 열형광선량계를 이용한 중성자 개인선량당량 평가)

  • Shin, Sang-Woon;Son, Joong-Kwon;Jin, Hua
    • Journal of Radiation Protection and Research
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    • v.24 no.3
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    • pp.143-154
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    • 1999
  • Panasonic UD-809P type albedo neutron TL dosimeters mounted on a water phantom were used to measure neutron personal dose equivalent in a Korean nuclear power plant. From the measured TL readings, personal dose equivalents from thermal, epithermal and fast neutrons were evaluated by using a method adopted in a neutron dose calculation algorithm for Panasonic UD-809P type albedo neutron TL dosimeters, which was suggested in a Panasonic TLD System User's Manual. The results showed that personal dose equivalent from fast neutrons could not be adequately evaluated in a field with high thermal neutron fraction to be encountered in a nuclear power plant. This seems to be related to the incomplete incidence of albedo thermal neutrons to the TL dosimeters. In order to evaluate appropriately the personal dose equivalent from fast neutrons in the field condition, new method fer the neutron dose calculation algorithm was suggested. In this new method, neutrons are grouped into thermal neutrons and fast neutrons. For each neutron component, equations for TL response, sensitivity factor, calibration factor and personal dose equivalent were derived.

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Thermodynamic Study on the Micellar Properties of DBS/Brij 30 Mixed Surfactant Systems (DBS/Brij 30 혼합계면활성제의 미셀화에 대한 열역학적 연구)

  • Lee, Byeong-Hwan;Park, In-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.190-195
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    • 2006
  • The critical micelle concentrations (CMC) and the counter ion binding constants (B) in a micellar state of the mixed surfactant systems of sodium dodecylbenzenesulfonate (DBS) with polyoxyethylene(4) lauryl ether (Brij 30) in water were determined as a function of 1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method from 288 K to 308 K. Various thermodynamic parameters (Smo, Hmo, and Gmo) for the micellization of DBS/Brij 30 mixtures were calculated and analyzed from the temperature dependence of CMC values. The measured values of Gomare all negative but the values of Smo are positive in the whole measured temperature region. On the other hand, the values of Hmo are positive or negative, depending on the measured temperature and 1.

Gas Impermeability Enhancement of EFDM/Crosslinked IIR Blends (Crosslinked IIR의 블렌드비에 따른 EPDM의 내기체투과특성 향상)

  • Kim, Hyun-Jun;Jung, Il-Hyun;Hong, In-Kwon;Park, Jae-Woo
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.193-200
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    • 1998
  • It is well known that EPDM(ethylene propylene diene monomer) rubber has inherently excellent resistance to the weathering, ozone, heat, cold and moisture, whereas crosslinked IIR (isobutylene isoprene divlnyl benzene terpolymer) shows proper resistance to the water and gas permeation. Various characteristics of EPDM blend with crosslinked IIR such as curing characteristics, mechanical properties, dispersion of minor component and gas impermeability were explored. The optimum curing time $(t_{90})$ examined with peroxide was decreased by adding small amount of crosslinked IIR to the EPDM rubber. Mechanical properties of blends such as tensile strength, hardness and elongation at break were enhanced by increasing EPDM content. These results might be explained with the affinity of carbon black to the EPDM rubber. On the other hand, the physical properties were not changed significantly after aging, and the increase of crosslinked IIR fraction caused the decrease of compression set to small rate. EPDM rubber shows different behavior with crosslinked IIR in oxygen permeability. By adding 30wt.% crosslinked IIR to the EPDM rubber, the resistance to the oxygen permeation was improved up to three times than that of pure EPDM rubber. Conclusively, EPDM blend containing 30wt.% crosslinked IIR might be commercially applied to the o-ring and electric parts because of its proper resistance to the weathering, ozone and oxygen permeability.

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A Study on Nozzle Flow and Spray Characteristics of Piezo Injector for Next Generation High Response Injection (차세대 고응답 분사용 피에조 인젝터의 노즐유동 및 분무특성에 관한 연구)

  • Lee Jin-Wook;Min Kyoung-Doug
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.6 s.249
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    • pp.553-559
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    • 2006
  • Most diesel injector, which is currently used in high-pressure common rail fuel injection system of diesel engine, is driven by the solenoid coil energy for its needle movement. The main disadvantage of this solenoid-driven injector is a high power consumption, high power loss through solenoid coil and relatively fixed needle response's problem. In this study, a prototype piezo-driven injector, as a new injector mechanism driven by piezoelectric energy based on the concept of inverse piezo-electric effect, has been designed and fabricated to know the effect of piezo-driven injection processes on the diesel spray structure and internal nozzle flow. Firstly we investigated the spray characteristics in a constant volume chamber pressurized by nitrogen gas using the back diffusion light illumination method for high-speed temporal photography and also analyzed the inside nozzle flow by a fully transient simulation with cavitation model using VOF(volume of fraction) method. The numerical calculation has been performed to simulate the cavitating flow of 3-dimensional real size single hole nozzle along the injection duration. Results were compared between a conventional solenoid-driven injector and piezo-driven injector, both equipped with the same micro-sac multi-hole injection nozzle. The experimental results show that the piezo-driven injector has short injection delay and a faster spray development and produces higher injection velocity than the solenoid-driven injector. And the predicted simulation results with the degree of cavitation's generation inside nozzle for faster needle response In a piezo-driven injector were reflected to spray development in agreement with the experimental spray images.

Studies on Pollution Characteristics and Sources of Precipitation in Jeiu Island

  • Kang, Chang-Hee;Kim, Won-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E4
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    • pp.191-201
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    • 2002
  • The pH, electric conductivity. and the major ionic components were analyzed for the precipitation samples collected at 1100 Site of Mt. Halla and Jeju city. The quality of analytical data was verified by the comparison of ion balances, conductivities and acid fractions, all of which correlation coefficients were over 0.952. The ionic strengths lower than 10$^{-4}$ M were found in 57 and 28% at 1100 Site and Jeju city respectively. The precipitation in Jeju city was influenced more by the oceanic effect than those in 1100 Site. The acidification of precipitation was caused mostly by S $O_4$$^{2-}$and N $O_3$$^{[-10]}$ in both areas, and the organic acids have contributed to the acidity with only 7~8%. The neutralization factors by N $H_3$ were about 44 and 47% at the 1100 site and the Jeju city, respectively, whereas those by CaC $O_3$were 21 and 24%, and the free acidity were about 38 and 28% at two sites. From the investigation of seawater and soil enrichment factors, the S $O_4$$^{2-}$, N $O_3$$^{[-10]}$ and N $E_4$$^{+}$ were immigrated by other sources rather than from the seawater or soil origins. but not in the case of $Mg^{2+}$, C $l^{[-10]}$ , N $a^{+}$, and $K^{+}$. Factor analysis has shown that the precipitation at the 1100 site had been influenced mostly by anthropogenic sources, followed by soil and sea-water sources. On the other hand, the precipitation at the Jeju city was mainly influenced by oceanic sources, followed by anthropogenic and soil sources.urces.

Improvement of Learning Behavior of Mice by an Antiacetylcholinesterase and Neuroprotective Agent NX42, a Laminariales-Alga Extract (Acetylcholinesterase 억제 및 신경세포 보호 활성을 갖는 다시마목 해조 추출물 NX42의 마우스 학습능력 향상 효과)

  • Lee, Bong-Ho;Stein, Steven M.
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.974-978
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    • 2004
  • Brown-alga-derived natural agent NX42, mainly composed of algal polysaccharides and phlorotannins, showed mild but dose-dependent inhibition of acetylcholinesterase with $IC_{50}=600-700\;{\mu}g/mL$. Phlorotannin-rich fraction of NX42 showed substantial increase of the activity by more than one order of magnitude ($IC_{50}=54\;{\mu}g/mL$) and significant protection of SK-N-SH cells from oxidative stress by $H_2O_2$. Learning trials of mice for 5 consecutive days revealed electric-shock treatment during learning period significantly retarded learning process, whereas NX42-treated mice showed significant resistance against leaning deficiency possibly mainly due to anticholinesterase and neuroprotective activities of phlorotannin.

Comparative Study on the Mixed Micellizations of Anionic Surfactant (DBS) with Nonionic Surfactnats (Brij 30 and Brij 35) (음이온성 계면활성제(DBS)와 비이온성 계면활성제(Brij 30과 Brij 35)와의 혼합미셀화에 대한 비교연구)

  • Park, In-Jung;Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.491-498
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    • 2009
  • The critical micelle concentration (CMC) and the counter ion binding constant (B) for the mixed micellizations of DBS (sodium dodecylbenzenesulfonate) with Brij 30 (polyoxyethylene(4) lauryl ether) and Brij 35 (polyoxyethylene (23) lauryl ehter) at 25 ${^{\circ}C}$ in pure water and in aqueous solutions of n-butanol were determined as a function of $\alpha$1 (the overall mole fraction of DBS) by the use of electric conductivity method. Various thermodynamic parameters (Xi, $\gamma$i, Ci, aiM, $\beta$, and ${\Delta}H_{mix}$) were calculated and compared for each mixed surfactant system by means of the equations derived from the nonideal mixed micellar model. There sults show that the molecules of DBS interact more strongly with Brij 35 than Brij 30 and that the DBS/Brij35 mixed system has greater negative deviation from the ideal mixed micellar model than the DBS/Brij 30mixed system.

Effect of n-Butanol on the Mixed Micellization of DPC with CDEAB (DPC와 CDEAB의 혼합마이셀화에 미치는 n-부탄올의 효과)

  • Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.48 no.3
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    • pp.236-242
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    • 2004
  • The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the Dodecylpyridinium chloride (DPC) with the Cetyldimethylethylammonium bromide (CDEAB) at 25$^{\circ}C$ in aqueous solutions of n-butanol were determined as a function of ${\alpha}_1$ (the overall mole fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters (($X_i,\;{\gamma}_i,\;C_i,\;a^M_i,\;{\beta},\;and {\Delta}H_{mix})$were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the mixed micellization of the DPC/CDEAB mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters (CMC, B 및 $;{\Delta}G_o\;^m$).

Statistics on Radiation Field Waveforms Associated with Multiple Intracloud Lightning Discharges

  • Lee, Bok-Hee;Lee, Dong-Moon;Ahn, Chang-Hwan;Kim, Young-Bong
    • Journal of KIEE
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    • v.11 no.1
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    • pp.32-40
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    • 2001
  • This paper presents the detailed statistics on radiation field signatures associated with multiple-intracloud lightning discharges. A transient signal recording system was used to measure the electric and magnetic fields produced by lightning flashes. The measurements were made in th summers of 1995 through 1999, and the location of the observation station was in Inchon on the coast of the Yellow Sea in Korea(37$^{\circ}$25'N, 126$^{\circ}$ 39'E). Most of lightning flashes typically contains between two and five strokes. The individual intracloud stork radiation fields were the bipolar pulse. On the average, the ratio of the peak of the second stroke to the first stroke peak was 75.1$\pm$40.1% for the negative, and a fraction of the subsequent stroke peaks were higher than the first stroke peak. The greater the number of the subsequent stroke order, less time separations between strokes were produced. The mean of the depth of the dip was 81.2$\pm$27.9% for the positive polarity and 75.9$\pm$24.4% for the negative. The depth of the dip increased for the positive bipolar pulses and decreased for the negative as the number of the stroke order increased.

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