• 한국전기전자재료학회논문지
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• 제25권10호
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• pp.824-829
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• 2012

Zn wires have been electrically exploded in methanol or distilled water using the pulsed power technologies. The nanopowders produced by the explosions have been observed by using SEM and TEM, and analyzed its phase by using EDS and XRD. The nanopowders produced in distilled water showed ZnO phase only. On the other hands, the nanopowder produced in methanol showed mixed phases with Zn and ZnO. The HR-TEM images of the nanopowders produced in methanol showed that the some particles have been coated with carbon like materials. It is considered that the carbon coatings could be depended on the positions of the particles during the plasma state formed by explosion.

• 한국분말재료학회지
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• 제10권3호
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• pp.161-163
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• 2003

The feasibility of obtaining highly dispersed aluminum oxide powders by the electrical explosion of aluminum conductors in an inert gas atmosphere and the subsequent oxidation of aluminum particles by water prior to their contact with air is demonstrated. For a specific surface area of the initial aluminum powder of 6.5$m^2$/g, the corresponding specific surface area of the resultant aluminum oxide nanopowder was as large as 300$m^2$/g.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 The 8th Asian Symposium on Precision Forging ASPF
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• pp.189-192
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• 2003

The Electro-thermal Explosion Coating (EEC) technique is a new surface treatment technology emerged in recent years. It uses an electrical discharge (with very high voltage from 5 to 30 kV or more) to produce a pulse current with large density inside the material to be deposited, the metal wire undergo the heating, melting, vaporization, ionization and explosion processes in a very short time (from tens ns to several hundreds ${\mu}s$), and the melted droplets shoot at the substrate with a very high velocity (3000 - 4500 m/s), so that the coating materials can be deposited on the surface of the substrate. Coatings with nano-size grains or ultra- fine grains can be formed because of rapid solidification (cooling rate up to $10^6-10^9\;k/s$). Surface of the substrate (about $1-5{\mu}m$ in depth) can be melted rapidly and coatings with very high bonding strength can be obtained.

• 한국재료학회지
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• 제12권12호
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• pp.941-946
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• 2002

Both Cu and Cu-oxide nanopowders have great potential as conductive paste, solid lubricant, effective catalysts and super conducting materials because of their unique properties compared with those of commercial micro-sized ones. In this study, Cu and Cu-oxide nanopowders were prepared by Pulsed Wire Evaporation (PWE) method which has been very useful for producing nanometer-sized metal, alloy and ceramic powders. In this process, the metal wire is explosively converted into ultrafine particles under high electric pulse current (between $10^4$ and $10^{ 6}$ $A/mm^2$) within a micro second time. To prevent full oxidations of Cu powder, the surface of powder has been slightly passivated with thin CuO layer. X-ray diffraction analysis has shown that pure Cu nanopowders were obtained at $N_2$ atmosphere. As the oxygen partial pressure increased in $N_2$ atmosphere, the gradual phase transformation occurred from Cu to $Cu_2$O and finally CuO nanopowders. The spherical Cu nanopowders had a uniform size distribution of about 100nm in diameter. The Cu-oxide nanopowders were less than 70nm with sphere-like shape and their mean particle size was 54nm. Smaller size of Cu-oxide nanopowders compared with that of the Cu nanopowders results from the secondary explosion of Cu nanopowders at oxygen atmosphere. Thin passivated oxygen layer on the Cu surface has been proved by XPS and HRPD.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2005년도 추계학술강연 및 발표대회강연 및 발표논문 초록집
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• pp.97-98
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• 2005

• 한국분말재료학회지
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• 제19권6호
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• pp.435-441
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• 2012

A new manufacturing process of Fe-Cr-Al powder porous metal was attempted. First, ultra-fine fecralloy powders were produced by using the submerged electric wire explosion process. Evenly distributed colloid (0.05~0.5% powders) was dispersed on PU (Polyurethane) foam through the electrospray process. And then degreasing and sintering processes were conduced. In order to examine the effect of sintering temperature in process, pre-samples were sintered for two hours at temperatures of $1350^{\circ}C$, $1400^{\circ}C$, $1450^{\circ}C$, and $1500^{\circ}C$, respectively, in $H_2$ atmospheres. A 24-hour TGA (thermo gravimetric analysis) test was conducted at $1000^{\circ}C$ in a 79% $N_2$+21% $O_2$ to investigate the high temperature oxidation behavior of powder porous metal. The results of the high temperature oxidation tests showed that oxidation resistance increased with increasing sintering temperature (2.57% oxidation weight gain at $1500^{\circ}C$ sintered specimen). The high temperature oxidation mechanism of newly manufactured Fe-Cr-Al powder porous metal was also discussed.

• 한국분말재료학회지
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• 제21권1호
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• pp.55-61
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• 2014

Fe-Cr-Al powder porous metal was manufactured by using new electro-spray process. First, ultra-fine fecralloy powders were produced by using the submerged electric wire explosion process. Evenly distributed colloid (0.05~0.5% powders) was dispersed on Polyurethane foam through the electro-spray process. And then degreasing and sintering processes were conduced. In order to examine the effect of cell size ($200{\mu}m$, $450{\mu}m$, $500{\mu}m$) in process, pre-samples were sintered for two hours at temperature of $1450^{\circ}C$, in $H_2$ atmospheres. A 24-hour thermo gravimetric analysis test was conducted at $1000^{\circ}C$ in a 79% $N_2$ + 21% $O_2$ to investigate the high temperature oxidation behavior of powder porous metal. The results of the high temperature oxidation tests showed that oxidation resistance increased with increasing cell size. In the $200{\mu}m$ porous metal with a thinner strut and larger specific surface area, the depletion of the stabilizing elements such as Al and Cr occurred more quickly during the high-temperature oxidation compared with the 450, $500{\mu}m$ porous metals.

• 한국분말재료학회지
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• 제11권4호
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• pp.308-313
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• 2004

An experimental study on the combustion of superfine aluminum powders (average particle diameter, a$_{s}$: ∼0.1 ${\mu}{\textrm}{m}$) in air is reported. The formation of aluminum nitride during the combustion of aluminum in air and the influence of the combustion scenario on the structures and compositions of the final products are in the focus of this study. The experiments were conducted in an air (pressure: 1 atm). Superfine aluminum powders were produced by the wire electrical explosion method. Such superfine aluminum powder is stable in air but once ignited it can burn in a self-sustaining way due to its low bulk: density (∼0.1 g/㎤) and a low thermal conductivity. During combustion, the temperature and radiation were measured and the actual burning process was recorded by a video camera. Scanning electron microscopy (SEM), X-ray diffraction (XRD) and chemical analysis were performed on the both initial powders and final products. It was found that the powders, ignited by local heating, burned in a two-stage self-propagating regime. The products of the first stage consisted of unreacted aluminum (-70 mass %) and amorphous oxides with traces of AlN. After the second stage the AlN content exceeded 50 mass % and the residual Al content decreased to ∼10 mass %. A qualitative discussion is given on the kinetic limitation for AlN oxidation due to rapid condensation and encapsulation of gaseous AlN.N.

• Carbon letters
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• 제21권
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• pp.68-73
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• 2017

We have demonstrated the production of thin films containing multilayer graphene-coated copper nanoparticles (MGCNs) by a commercial electrodeposition method. The MGCNs were produced by electrical wire explosion, an easily applied technique for creating hybrid metal nanoparticles. The nanoparticles had average diameters of 10-120 nm and quasi-spherical morphologies. We made a complex-electrodeposited copper thin film (CETF) with a thickness of $4.8{\mu}m$ by adding 300 ppm MGCNs to the electrolyte solution and performing electrodeposition. We measured the electric properties and performed corrosion testing of the CETF. Raman spectroscopy was used to measure the bonding characteristics and estimate the number of layers in the graphene films. The resistivity of the bare-electrodeposited copper thin film (BETF) was $2.092{\times}10^{-6}{\Omega}{\cdot}cm$, and the resistivity of the CETF after the addition of 300 ppm MGCNs was decreased by 2% to ${\sim}2.049{\times}10^{-6}{\Omega}{\cdot}cm$. The corrosion resistance of the BETF was $9.306{\Omega}$, while that of the CETF was increased to 20.04 Ω. Therefore, the CETF with MGCNs can be used in interconnection circuits for printed circuit boards or semiconductor devices on the basis of its low resistivity and high corrosion resistance.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2010년도 춘계학술발표대회
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• pp.52.1-52.1
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• 2010

나노금속분말은 기존의 마이크론 입자와 다른 특이한 기계적, 전기적, 자기적 특성을 나타낸다. 나노금속분말 제조에서 가장 중요한 것은 오염되지 않은 고순도의 분말을 균일하고, 고분산된 입자를 제조하는 것으로 전기선폭발법(Electric Explosion of Wire, EEW)은 이러한 요구조건을 만족시킨다. 최근에는 전기선폭발법을 유체 내에 적용하여 분말을 제조하는 공정이 개발되었다. 이로 인해 고순도의 구형의 금속 나노입자를 얻을 수 있다. 본 연구에서는 물, 알코올, 에틸렌글라이콜 등 다양한 유체내에서 다양한 순금속 분말과 TiNi, SUS 등 나노합금분말을 제조하였다. 제조된 금속입자의 특성과 금속입자가 분산된 유체의 특성은 FE-SEM, HR-TEM, XRD, Turbiscan등으로 분석하였다.